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Epoxy resin dough moulding compound and preparation method thereof

A technology of bulk molding compound and epoxy resin, which is applied in the field of epoxy resin bulk molding compound and its preparation, can solve the problems of low production efficiency, difficult operation, complicated process, etc., and achieve high production efficiency, long application period, The effect of simple process

Active Publication Date: 2010-10-27
北京玻钢院复合材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there are few formulations using epoxy resins as raw materials for molding compounds, all of which use latent curing systems. Most of them need to be matured before they can be used, and the process is relatively complicated; as the Chinese patent application with publication number CN101096443A discloses a kind of epoxy resin The preparation method of the sheet molding compound is to prepare the epoxy resin paste, add chopped fiber and mix evenly, then make a sheet with a scraper, and then thicken it in an oven for 24-96 hours to mature, and control the thickening temperature to 28 -40℃, get epoxy resin sheet molding compound
The curing process is an indispensable process in the preparation of the existing epoxy resin molding compound. It consumes energy, is difficult to operate and has low production efficiency.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0035] Prepare the epoxy resin paste and the curing agent mixture respectively, and select the chopped fibers used; where:

[0036] The epoxy resin paste uses 80 parts of liquid bisphenol A epoxy resin of the type WSR618, 5 parts of dimethyl phthalate, 4 parts of silicon dioxide, 3 parts of montan wax, and 0.5 parts of coupling agent KH550. In the high-speed mixer, the high-speed mixer is standby after stirring at a speed of 800 rpm for 0.5 hour; the high-speed mixer is selected from the model produced by the German IKA company to be: RW 20 DZM mixer.

[0037]For the preparation of the curing agent mixture, first select 10 parts of isophorone diamine, add 4 parts of ordinary dicyandiamide to it and stir evenly, then add 1 part of N, N-dimethyldiphenylurea and continue to stir and mix evenly Backup.

[0038] Chopped fiber selects 1 / 4 inch chopped glass fiber for use.

[0039] The preparation method of epoxy resin bulk molding compound of the present invention: take 35 parts o...

example 2

[0042] Prepare the epoxy resin paste and the curing agent mixture respectively, and select the chopped fibers used; where:

[0043] 110 parts of epoxy resins are selected for use in the epoxy resin paste, and this epoxy resin contains 60 parts of liquid bisphenol A type epoxy resins that model is WSR618 and 50 parts of bisphenol F epoxy resins that model is ADK4901; Plasticizer Choose 7 parts of polyvinyl butyral, 5 parts of calcium carbonate as filler, 4 parts of silicone grease as release agent, and 1 part of KH560 as coupling agent.

[0044] The amine curing agent contained in the curing agent mixture is selected from 6 parts of ethylenediamine, the latent curing agent is selected from 7 parts of electronic grade dicyandiamide, and the accelerator is selected from 2 parts of N, N-dimethyl diphenyl urea;

[0045] Chopped fiber selects 1 / 2 inch chopped carbon fiber for use.

[0046] When in use, take 35 parts of epoxy resin paste, 5 parts of curing agent mixture, and put cho...

example 3

[0049] Prepare the epoxy resin paste and the curing agent mixture respectively, and select the chopped fibers used; where:

[0050] The epoxy resin paste contains 120 parts of epoxy resin, including 60 parts of liquid bisphenol A epoxy resin with a model number of WSR618 and 60 parts of glycidyl ester epoxy resin with a model number of TDE-85. 10 parts of diethyl diformate, 8 parts of aluminum hydroxide as filler, 6 parts of zinc stearate as release agent, and 2 parts of KH560 silane coupling agent as coupling agent.

[0051] The curing agent mixture contains 7 parts of diethylenetriamine as the amine curing agent, 7 parts of electronic grade dicyandiamide as the latent curing agent, and 3 parts of N, N-diethyldiphenylurea as the accelerator.

[0052] Chopped fiber is selected as 1 / 8 inch chopped aramid fiber.

[0053] When in use, take 35 parts of epoxy resin paste, 5 parts of curing agent, and 70 parts of chopped aramid fiber, put them into a kneader, mix for 30 minutes, an...

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Abstract

The invention discloses an epoxy resin dough moulding compound and a preparation method thereof. The epoxy resin dough moulding compound is prepared by evenly kneading 35-40 parts by mass of epoxy resin paste, 4-5 parts by mass of curing agent mixture and 65-70 parts by mass of chopped fiber, wherein the epoxy resin paste comprises the following components in parts by mass: 80-120 parts of epoxy resin, 5-10 parts of plasticizer, 4-8 parts of filler, 3-6 parts of mould release agent and 0.5-2 part(s) of coupling agent; the curing agent mixture comprises the following components in parts by mass: 4-7 parts of latent curing agent, 1-3 part(s) of accelerator and 6-10 parts of amine curing agent, and the length of the chopper fiber is one eighth to one half inch. Compared with the traditional method, the preparation method eliminates the curing process, and the dough moulding compound is prepared by adding modifying components and different curing systems into the epoxy resin. The method has the advantages of simple operation, high production efficiency, long working life and easy formation. Since the baking oven and other heating equipment are not needed, the method can reduce the energy consumption. Moreover, the method is applicable to fields of structural materials and composite materials with high requirements for insulation and electrical properties, and can be easily promoted and implemented.

Description

technical field [0001] The invention relates to an epoxy resin bulk molding compound and a preparation method thereof. Background technique [0002] Molding compound technology is a mature composite material technology. It is used by mixing resin and fiber evenly, and has the characteristics of uniform and stable quality, fast molding speed and high production efficiency. Common molding compounds mainly use polyester resin as the resin matrix, which has the characteristics of low cost and low curing temperature. Using epoxy resin as the resin matrix of molding compounds has unique advantages in some special technical fields. Long storage period, high glass transition temperature, good mechanical properties and electrical properties and other fields. [0003] At present, there are few formulations using epoxy resins as raw materials for molding compounds, all of which use latent curing systems. Most of them need to be matured before they can be used, and the process is relat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L63/02C08K13/04C08K7/14C08K7/06C08K7/10C08K5/12C08K5/17C08L77/10
Inventor 孙超明陈淳刘红影柴红梅陈敬菊
Owner 北京玻钢院复合材料有限公司
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