Flocculation pretreatment method for penicillin fermentation waste water
A penicillin fermentation and pretreatment technology, which is applied in the direction of flocculation/sedimentation water/sewage treatment, water/sewage multi-stage treatment, neutralization water/sewage treatment, etc., can solve problems such as complex process, achieve reduction of biological inhibitory substances, Improved degradability and stable effect
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Embodiment 1
[0027] Penicillin fermented liquid is not filtered and extracted from the raffinate phase after high-temperature distillation. The temperature of the still residue is 74°C, the pH is 2.5, and the measured COD is 54580mg / L, SS is 23385mg / L, SO 4 2- The content is 6200mg / L, and the treatment process is as follows: firstly, Ca(OH)2 is added to the residual liquid, and the pH value of the residual liquid is adjusted to 10, and Ca(OH) 2 While adjusting the electrical properties and pH of the raffinate itself, the SO2 in the raffinate 4 2- React to generate slightly soluble calcium sulfate precipitate; then add 280 mg / L cationic polyacrylamide with a concentration of 0.15%, and after mixing and flocculating for 3 minutes, insoluble substances such as suspended solids, colloids, and precipitates in the still raffinate will form dehydration. Good flocs; then pass the reacted still residue into a belt filter press for solid-liquid separation, so that the COD of the supernatant obtain...
Embodiment 2
[0029] The still raffinate after the high-temperature distillation of the raffinate phase of the penicillin fermentation liquid extraction process without filtration, the temperature of the still raffinate is 72°C, the pH is 2.5, the measured COD is 52600mg / L, and the SS is 20150mg / L. The treatment process is as follows: first Add polymeric silicic acid to the residual liquid of the kettle, the amount of polymeric silicic acid added is 8.5g / L, after fully stirring and mixing, react, then add 450mg / L of cationic polyacrylamide with a concentration of 0.2%, and mix and flocculate for 3min, then react The final residual liquid is passed into a decanter centrifuge for solid-liquid separation. The COD in the supernatant obtained in this way is reduced to 22310 mg / L, the SS content is reduced to 660 mg / L, and the water content of the mud cake is 70%. The removal rates of COD and SS were 56.1% and 96.7%, respectively.
[0030] Wherein the preparation method of polymeric silicic acid ...
Embodiment 3
[0032]The still raffinate after the high-temperature distillation of the raffinate phase of the penicillin fermentation liquid extraction process without filtration, the temperature of the still raffinate is 74°C, the pH is 2.5, the measured COD is 55012mg / L, and the SS is 23310mg / L. The treatment process is as follows: first Add 500 mg / L of 5% tannin to the residual liquid, then add 400 mg / L of cationic polyacrylamide with a concentration of 0.2%, mix and flocculate for 4 minutes, and then pass the residual liquid after the reaction into a decanter centrifuge Machine for solid-liquid separation, the COD of the supernatant obtained in this way is reduced to 23710mg / L, the SS content is reduced to 210mg / L, and the water content of the mud cake is 80%. The removal rates of COD and SS were 56.9% and 99.1%, respectively.
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