Manufacturing method of etched substrate and light-sensitive resin composition
A technology of photosensitive resin and photosensitive resin layer, which is applied in the field of photosensitive resin composition, and can solve problems such as time-consuming and labor-consuming
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[0047] [Preparation of Alkaline Soluble Resin (A)]
[0048] (A) component is prepared by making some acid groups derived from (a1) component react with the epoxy group derived from (a2) component, and introducing an unsaturated group into (a1) component. Specifically, for example, it can prepare by making the inert organic solvent solution of (a1) component, and (a2) component react at about 20-120 degreeC for about 1-5 hours. The inert organic solvent is not particularly limited, and examples thereof include alcohols, esters, and aliphatic or aromatic hydrocarbons. The ratio of the component (a1) to the component (a2) may vary depending on the type of monomer used to synthesize the component (a1), but the ratio of the component (a2) to the component (a1) is preferably 15 mol % or more. Favorable etching resistance can be provided to the resin pattern obtained by hardening the photosensitive resin composition containing (A) component as the ratio of (a2) component with respec...
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[0081] The present invention will be described more specifically with reference to the following examples. However, these Examples are only examples of the present invention and cannot limit the scope of the present invention.
[0082]
[0083] According to Table 1-Table 4, the photosensitive resin composition of Examples 1-17 and Comparative Examples 1-3 was prepared. Each component described in Table 1 is as follows. Moreover, the 45 mass % DPGME (dipropylene glycol monomethyl ether) solution of the alkali-soluble resin (A) was prepared and used for preparation of the photosensitive resin composition. However, 100 parts by mass of the alkali-soluble resin (A-1 or A-2) in Tables 1 to 4 means that the solid content of the alkali-soluble resin is 100 parts by mass.
[0084] Alkaline soluble resin (A)
[0085] A-1: Cycloma-ACA Z250 (manufactured by Daicel Chemical Industry Co., Ltd., mass average molecular weight 20000, acid value 101.7mgKOH / g, acrylic resin containing acid...
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