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Acid heap leaching process for cupric oxide ore

A technology of copper oxide ore and new process is applied in the fields of energy saving, new technology of high-efficiency copper extraction, and environmental protection, which can solve the problems of low leaching rate, interference of ore sludge, and low recovery rate of sulfuration flotation, so as to reduce environmental pollution and improve economy. benefit, the effect of improving the level of comprehensive utilization

Inactive Publication Date: 2009-05-20
有研资源环境技术研究院(北京)有限公司
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Problems solved by technology

For copper oxide ore with large mud content and easy mudification, the recovery rate of traditional sulfidation flotation is low, and it is difficult to solve the problem of mud interference; stirring leaching method has the advantages of short leaching cycle and high copper leaching rate, but has the disadvantages of high production cost, Defects such as difficult solid-liquid separation; conventional heap leaching methods have disadvantages such as poor permeability, low leaching rate and long leaching cycle

Method used

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  • Acid heap leaching process for cupric oxide ore
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Embodiment 1

[0027] A domestic copper mine is a copper oxide deposit, and copper oxide minerals mainly exist in the form of malachite and azurite. In addition to copper minerals, the ore also contains a large amount of iron, which mainly exists in the form of limonite. The gangue minerals are mainly clay minerals, quartz and gypsum. Most of the gangue minerals are in the form of silt, with a soft and brittle structure. In the pores and gaps of the gangue minerals, there are often sporadic distributions of malachite and bluestone in a dispersed state. copper ore. Mineral composition in the ore: malachite and azurite 28%, limonite 35%, quartz 10%, iron stained clay mineral 20%, kaolin 5%, gypsum 2%.

[0028] Because there are many clay-like muddy minerals in the ore and the content of iron minerals is large, no matter whether the flotation process or the gravity separation process is used, the separation effect of copper is poor, and it is difficult to obtain good technical indicators.

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Abstract

The invention provides a new technique of acid heap leaching of copper oxide ore. The copper oxide ore is crushed and screened, then materials on a screen are carried out conventional acid heap leaching operation and the materials under the screen carry out concentration, size mixing and granulation and then are piled and leached; and leachate rich in copper ions is treated by the procedures of extraction, electrodeposition and the like so as to obtain cathode copper sold on the market. After the materials under the screen are concentrated, a binding agent needs to be added for size mixing; after size mixing, ore pulp and prepared acid-proof gravel with the granularity of 5mm to 25mm are mixed for granulation; in the granulation and heap leaching process, the pile height is 3 to 5m, in the heap leaching process, the concentration of dilute sulphuric acid is 0.1 to 2mol / L, the spraying strength is 0.2 to 0.5L / (min.m<2>) and the leaching period is 1 to 2 months. The technique can fully utilize copper oxide ore resource which is hard to be utilized in the past time, contains a large amount of clay mineral and is easy to argillization, improves the level of comprehensive utilization of mines, saves cost and increases profit. The invention is particularly suitable for being applied to the development of copper ore resources, mainly the copper oxide ore, which are hard to treat in all regions of China, in particular to remote regions of the western highlands.

Description

technical field [0001] The invention relates to a new process of heap leaching of copper oxide ore by acid method, especially the use of crushed stone carrier to granulate, improve the permeability of ore, and accelerate the leaching rate of copper oxide ore. New technology for efficient copper extraction. Background technique [0002] Copper oxide ore is an important copper mineral, and its deposits are mostly formed by geological epigenesis. The material composition and structure of various copper oxide ores are different, but they all have common characteristics such as strong hydrophilicity, large mud content, strong solubility, and flotation. [0003] The main methods of processing copper oxide ore are: flotation and leaching. For copper oxide ore with large mud content and easy mudification, the recovery rate of traditional sulfidation flotation is low, and it is difficult to solve the problem of mud interference; stirring leaching method has the advantages of short ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/08C22B1/14C22B15/00C25C1/12
CPCY02P10/20
Inventor 舒荣波温建康武彪
Owner 有研资源环境技术研究院(北京)有限公司
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