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Environment friendly free-cutting leadless copper alloy material and processing technology

A processing technology and copper alloy technology, which are applied in the field of environmentally friendly free-cutting copper alloy materials and processing technology, can solve the problems of high price, adverse effects of antimony on human health, limited bismuth resources, etc., so as to reduce the processing cost and save the intermediate annealing process. Effect

Active Publication Date: 2009-03-18
中铝洛阳铜加工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, alloys have added bismuth and antimony instead of lead to form free-cutting copper alloys to achieve environmental protection and lead-free purposes. However, bismuth resources are limited and expensive. The control of antimony by NSF61 in the United States is also relatively strict, and the standard for the dissolution value of antimony is 0.6 μg / L, second only to the control of cadmium. At the same time, antimony has adverse effects on human health. It can be seen that the application of antimony has limitations, so the development of alternative environmentally friendly free-cutting lead-free copper alloys is of great significance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Making product specifications by stretching process A 10mm lead-free lead-free copper alloy rod, which is environmentally friendly and easy to cut, in which:

[0027] Ingredients: 34% of Zn, 1.6% of P, 0.8% of Al, 0.5% of Fe, 0.5% of B, 0.3% of Ti, 0.3% of an element in the RE system, 0.01% of Pb , 0.1% Sb, 0.3% unavoidable impurities, and the rest is Cu for batching, and after batching, it is melted and cast into a billet.

[0028] Stretching: Stretch the finished billet with a stretching machine, and the elongation coefficient is 1.05.

[0029] Annealing: The annealing furnace is used to anneal the stress-relief finished products on the cut-to-length bars, and the annealing temperature is 300°C.

Embodiment 2

[0031] Making product specifications by stretching process A 10mm lead-free lead-free copper alloy rod, which is environmentally friendly and easy to cut, in which:

[0032] Ingredients: 43% of Zn, 0.6% of Si, 0.1% of Al, 0.1% of Fe, 0.3% of B, 0.25% of Ti, 0.2% of two elements in RE system, 0.008% of Pb , 0.08% Sb, 0.2% unavoidable impurities, and the rest is Cu for batching, and after batching, it is melted and cast into a billet.

[0033] Stretching: Stretch the finished billet with a stretching machine, and the elongation coefficient is 1.83.

[0034] Annealing: use an annealing furnace to anneal stress-relieving finished products on the cut-to-length bars, and the annealing temperature is 350°C.

Embodiment 3

[0036] Product specifications made by stretching process: A 10mm lead-free lead-free copper alloy rod, which is environmentally friendly and easy to cut, in which:

[0037] Ingredients: 44% of Zn, 2.0% of Mg, 0.5% of Al, 0.2% of Fe, 0.4% of B, 0.2% of Ti, 0.1% of an element in the RE system, 0.01% of Pb , 0.1% Sb, 0.1% unavoidable impurities, and the rest is Cu for batching, and after batching, it is melted and cast into a billet.

[0038] Stretching: Stretch the finished billet with a stretching machine, and the elongation coefficient is 2.6.

[0039] Annealing: The annealing furnace is used to anneal the stress-relief finished products on the cut-to-length bars, and the annealing temperature is 400°C.

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PUM

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Abstract

The invention relates to an environment-friendly free cutting copper alloy material. The compositions of the environment-friendly free cutting copper alloy material are 30 to 45 percent of zinc, 0.05 to 2.0 percent of aluminum, less than or equal to 1.0 percent of iron, less than or equal to 0.5 percent of boron, less than or equal to 0.5 percent of titanium, less than or equal to 0.3 percent of one element or more than one element in a rare earth element RE system, less than or equal to 0.01 percent of plumbum, less than or equal to 0.1 percent of stibium, less than or equal to 0.3 percent of unavoidable impurities and the balance being copper; and 0.05 to 1.6 percent of phosphor or 0.05 to 3.0 percent of silicon or 0.1 to 3.0 percent of magnesium or 0.05 to 3.0 percent of silicon and 0.05 to 0.5 percent of tin or 0.05 to 3.0 percent of silicon, 0.05 to 0.5 percent of tin and 0.05 to 0.5 percent of manganese are added into the compositions for mixture, and the mixture is cast into blanks after mixture. The lengthening and drawing coefficient is controlled to between 1.05 and 2.6, and the annealing temperature is controlled to between 300 and 400 DEG C. The copper alloy has the cutting performance of leaded brass, simplifies the processing technique, saves the step of intermediate annealing, and reduces the processing cost.

Description

technical field [0001] The invention belongs to the technical field of copper alloy materials, and in particular relates to an environment-friendly easy-cutting copper alloy material and a processing technology. Background technique [0002] Lead brass has excellent properties such as easy cutting, mechanics, and physics, and is a widely used copper alloy. The utilization rate of brass water pipes in developed countries is as high as 90%. [0003] Free-cutting lead brass is a two-phase brass, and lead is dispersed in the grain and grain boundary as fine particles. When copper is used as drinking water pipe fittings such as faucets and pipe joints, lead will be leached into the water under the action of substances in the water, because lead is a harmful element that can cause serious harm to the environment and human body, so its application is increasingly strict limit. [0004] In order to reduce the harmful effect of lead, researchers have systematically studied the corr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/04C22F1/08
Inventor 娄花芬赵万花任玉波孙飞涛丁顺德符学智冷建伟秦书平
Owner 中铝洛阳铜加工有限公司
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