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Method for preparing carbon nano-tube/nano-nickel composite film

A technology of carbon nanotubes and composite films, applied in electrolytic coatings, electrophoretic plating, coatings, etc., can solve the problems of rough coating surface, limited carbon nanotube reinforcement, unevenness, etc.

Inactive Publication Date: 2008-09-03
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation of carbon nanotubes / nano-nickel composite thin film materials by composite plating has made great progress, but there are still some problems. The difficulty of research is mainly due to the fact that carbon nanotubes are easily agglomerated in aqueous solution, resulting in rough surface of the coating. and inhomogeneity, limiting the reinforcing effect of carbon nanotubes in composites

Method used

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  • Method for preparing carbon nano-tube/nano-nickel composite film
  • Method for preparing carbon nano-tube/nano-nickel composite film
  • Method for preparing carbon nano-tube/nano-nickel composite film

Examples

Experimental program
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Effect test

Embodiment 1

[0029] 1. Substrate pretreatment: (1) Surface polishing: Polish the aluminum foil (thickness 100 μm) with 2#, 4#, 6#, 8# metallographic sandpaper in sequence until the surface is uniform and bright. (2) Degreasing and degreasing: Put the polished aluminum foil into a beaker filled with distilled water, and after ultrasonic cleaning for 5 minutes, put it in acetone for 3 to 5 minutes to remove surface oil, take it out and wash it with twice distilled water, and place Dry in an oven at 120°C for use.

[0030] 2. Preparation of electrophoretic suspension: Weigh about 0.01g of carbon nanotubes into a 150ml beaker, measure 50ml of acetylacetone, cover with a film, and use ultrasonic vibration for 1 hour before use.

[0031] 3. Electrophoretic deposition: before deposition, stir the suspension and ultrasonically for 25 minutes, insert a cylindrical stainless steel electrode (as the anode) into the middle of the suspension, and insert the pretreated and dried aluminum foil (as the ca...

Embodiment 2

[0036] 1. Substrate pretreatment: (1) Surface polishing: Polish the titanium foil (thickness 100 μm) with 2#, 4#, 6#, 8# metallographic sandpaper in sequence until the surface is uniform and bright. (2) Degreasing and degreasing: Put the polished aluminum foil into a beaker filled with distilled water, and after ultrasonic cleaning for 5 minutes, put it in acetone for 3 to 5 minutes to remove surface oil, take it out and wash it with twice distilled water, and place Dry in an oven at 120°C for use.

[0037] 2. Preparation of electrophoretic suspension: prepare electrophoretic liquid according to Example 1.

[0038] 3. Electrophoretic deposition: before deposition, stir the suspension and sonicate for 25 minutes, insert a cylindrical stainless steel electrode (as an anode) into the middle of the suspension, insert a pretreated and dried stainless steel foil (as a cathode) into the suspension, and place In the middle, adjust the DC power supply voltage to 60V, adjust the curren...

Embodiment 3

[0043] 1. Substrate pretreatment: (1) Surface polishing: Polish the stainless steel foil (thickness 100-200μm) with 2#, 4#, 6#, 8# metallographic sandpaper in sequence until the surface is uniform and bright. (2) Degreasing and degreasing: Put the polished titanium foil into a beaker filled with distilled water, after ultrasonic cleaning for 5 minutes, put it in acetone for 3 to 5 minutes, remove the surface oil, take it out and wash it with twice distilled water, Dry in an oven at 120°C for later use.

[0044] 2. Preparation of electrophoretic suspension: Weigh about 0.02g of carbon nanotubes into a 150ml beaker, measure 50ml of acetylacetone, cover with a film, and use ultrasonic vibration for 1 hour before use.

[0045] 3. Electrophoretic deposition: before deposition, stir the suspension and sonicate for 25 minutes, insert a cylindrical stainless steel electrode (as an anode) into the middle of the suspension, insert a pretreated and dried stainless steel foil (as a cathod...

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Abstract

A preparation method for carbon nanotube / nanonickel composite film material, relating to a method for preparing carbon nanotube / nanonickel composite film material on surface of metal foil, providing a method for preparing carbon nanotube film in acetylacetone by electrophoretic deposition, then electronically depositing nanoparticle of nickel on the carbon nanotube film by electrophoretic deposition, so as to prepare carbon nanotube / nanonickel composite film material with good catalytic and corrosion resisting property on surface of metal foil; depositing the metal foil processed by surface polishing and acetone oil removal in acetylacetone suspension having carbon nanotube by electrophoresis, undergoing electrophoretic deposition by direct current supply, then undergoing electrodeposit in nickel plating solution with constant current, after that, obtaining the carbon nanotube / nanonickel composite film material by drying process.

Description

technical field [0001] The invention relates to a composite thin film material, in particular to a method for preparing a carbon nanotube / nano-nickel composite thin film material on the surface of a metal foil. Background technique [0002] The most typical application of nanomaterials is carbon nanotubes. Carbon nanotubes are seamless nanotube-like substances curled from single-layer or multi-layer graphite. Each layer of nanotubes is composed of a carbon atom that is completely bonded to the surrounding three carbon atoms through sp2 hybridization. The cylindrical surface composed of planes, due to its nearly perfect bonding structure, hinders the intervention of impurities and defects, making it have super strong mechanical properties and high chemical stability, and its chemical activity is lower than that of graphite. Carbon nanotubes are currently the thinnest fiber material due to their high length-to-diameter ratio (the diameter is within tens of nanometers, and the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D13/02C25D13/20C23G5/024
Inventor 王周成祁正兵廖齐华
Owner XIAMEN UNIV
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