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Dirty-proof inhibition composition for reclaimed water circulation sewage and preparation method and application

A technology for scale and corrosion inhibition and composition, applied in the field of scale and corrosion inhibition composition of reclaimed water turbidity ring system and its preparation field, can solve the problems affecting the heat exchange efficiency of circulating water system, system scaling, corrosion and the like, and achieves The effect of excellent scale and corrosion inhibition performance, energy saving of backwater utilization and low economic cost

Inactive Publication Date: 2008-02-06
北京能泰高科环保技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the oil pollution of the circulating water system of the continuous casting machine in the steelmaking plant is a problem that has plagued the water system of the steelmaking enterprise for many years. The oil pollution comes from the dripping of various oil agents in the continuous casting equipment, the oil penetrates into the circulating water, and the dust in the bonding water and calcium scale, forming oil sludge particles suspended in circulating water, or changing with temperature and concentration, decomposing or forming oil scale and adhering to equipment; because circulating water contains oil and rich oxidation, under sufficient light or temperature, a large amount of oil will surely grow in the system Bacteria and algae, and after adding the fungicide, the killed bacteria and algae will form biological slime adhesion or deposition, which will affect the heat exchange efficiency of the circulating water system. The slime and sundries will block the cooling water nozzle and bring System fouling and corrosion problems

Method used

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  • Dirty-proof inhibition composition for reclaimed water circulation sewage and preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A scale and corrosion inhibitor composition (TWZL-002) for reclaimed water turbid ring system, containing the following components (kg): organic phosphonate 25, acrylic acid-sodium sulfonate terpolymer or hydroxypropyl acrylate Copolymer 30, zinc sulfate salt 10, water 35.

[0048] The preparation method of this composition is:

[0049] 1. Material preparation: according to the above formula ratio, use a metering pump to successively weigh organic phosphonate, acrylic acid-sodium sulfonate terpolymer or hydroxypropyl acrylate copolymer, zinc sulfate salt, and water.

[0050] 2. Production: Turn on the vacuum pump, and the organic phosphonate, acrylic acid-sodium sulfonate terpolymer or hydroxypropyl acrylate copolymer and water will be pumped into the reaction kettle. When the reaction temperature is 40-50°C, the stirring speed is Under the condition of 80 rev / min, stir for 20 minutes; thereafter, add zinc sulfate salt to make it completely dissolved, continue stirring...

Embodiment 2

[0052] Corrosion inhibition experiment of carbon steel by scale and corrosion inhibitor (TWZL-002) of the present invention.

[0053] 2.1 Purpose of the experiment.

[0054] The method of rotating coupon corrosion test is to evaluate the corrosion inhibition performance of water treatment agent by calculating the corrosion rate and corrosion inhibition rate by using the loss mass of the test piece under the given conditions in the laboratory. The corrosion characteristics of the continuous casting secondary spray cooling water system are tested by using the rotating coupon corrosion measurement method, and the corrosion inhibition performance of the product of the present invention is comprehensively evaluated by indicators such as the appearance color change of the carbon steel after the test, and the corrosion rate measured by the weight loss method. .

[0055] 2.2 Experimental conditions.

[0056] Experimental water quality: the experimental water is provided by the secon...

Embodiment 3

[0082] The comparative experiment of the corrosion inhibition performance of the composition of the present invention and other corrosion inhibitors.

[0083] 3.1 Purpose of the experiment.

[0084] Carry out the carbon steel corrosion inhibition test for different corrosion inhibitors, still utilize the rotating coupon corrosion measurement method, adopt the same soft water system, and judge the corrosion inhibition performance of the present invention by comparison.

[0085] 3.2 Experimental conditions and experimental procedures.

[0086] Same as 2.2 and 2.3.

[0087] 3.3 Experimental conclusion.

[0088] The following table is the test results of the present invention and other similar corrosion inhibitors on carbon steel surface.

[0089] Table 4 Comparison of carbon steel corrosion rates under different corrosion inhibitors.

[0090] Product number

Scale and corrosion inhibitor TWZL-002

Existing scale and corrosion inhibitors for comparison

D...

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Abstract

The invention relates to a corrosion and deposit inhibiting combination for intermediate water sewage system, a fabrication and application method to be concerned, the corrosion and deposit inhibiting combination comprises an organic phosphonate, carboxylic acid multipolymer, zince sulfate and water; the corrosion and deposite inhibiting combination of the invention is fabricated by carboxylic acid multipolymer and other compounds, which can effectively prevent the formation of calcium carbonate in cool circulating water, and also has a favorable performance on preventing the formation of calcium phosphate scale, as the result shows, the corrosion and deposit inhibiting combination has an outstanding corrosion inhibiting effect, the corrosion velocity of carbon steel is only 0.05mm / a which is far smaller than 0.125mm / a equivalent to the national standard, the invention is applicable to a wide arrange of water quality fluctuation, and can provide with an outstanding corrosion and deposit inhibiting performance, the medicament consumption is small, only 40 to 60mg / l of the corrosion and deposit inhibiting combination in the invention can be used for capability of meeting the requirement on corrosion and deposit inhibiting, an industrial water consumption and an economic expense are tremendously saved, the economic benefit and the social benefit are favorable.

Description

technical field [0001] The invention relates to the technical field of industrial water treatment, in particular to a scale and corrosion inhibition technology used in circulating cooling water systems in the fields of electric power and thermal power to prevent scaling and corrosion of pipelines and equipment, especially for medium Scale and corrosion inhibitor composition for water turbid ring system, preparation method and application thereof. The antiscaling and corrosion inhibiting composition of the invention is energy-saving and suitable for circulating cooling water systems with wide fluctuations in water quality. Background technique [0002] The scarcity and pollution of water resources pose a threat to social stability and economic development, and become one of the most prominent problems facing the stability and development of most countries in the world. Conserving water and improving the utilization rate of water resources have become a top priority. To save ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14
Inventor 刘彦华刘雪冬王永梅宋焕明安海珍杜雪梅王鑫
Owner 北京能泰高科环保技术有限公司
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