The invention relates to the steel-making field, and concretely provides an atmospheric corrosion resistant structural steel liquid, which contains the following components by adopting the total weight of the steel liquid as the baseline: 0.01 percent to 0.09 percent of C, 0.15 percent to 0.35 percent of Si, 0.30 percent to 0.60 percent of Mn, 0.30 percent to 0.40 percent of Cu, 0.20 percent to 0.30 percent of Ni, 2.0 percent to 3.5 percent of Cr, 0.06 percent to 0.12 percent of V, 0.005 percent to 0.030 percent of Ti, 0.008 percent to 0.014 percent of M, less than or equal to 0.030 percent of P, and less than or equal to 0.020 percent of S. The invention provides atmospheric corrosion resistant structural steel, and a production method thereof. By adopting the steel liquid provided by the invention for continuous casting, the central quality of a casting blank can be improved, and the occurrence of center burst and center line shrinkage is avoided, so that the quality of a high atmospheric corrosion resistant structural steel casting blank with high strength can be improved, and the yield of the casting blank can be greatly improved; and in addition, the finally obtained atmospheric corrosion resistant structural steel has good atmospheric corrosion resistance and a higher strength performance.