Apparatus and method for hydrogen generation from gaseous hydride

Abstract

An apparatus and method including storage and dispensing vessels to safely store and dispense gaseous hydrides, where the storage and dispensing vessels contain a solid-phase physical sorbent medium having a physically sorptive affinity for gaseous hydrides, and wherein the gaseous hydride is decomposed in the apparatus to generate hydrogen gas. The gaseous hydrides include, but are not limited to, silane, germane, stibine and diborane. The gaseous hydrides decompose spontaneously and / or decomposition is enhanced using surface modified adsorbents. The hydrogen generated by the apparatus may be used in a fuel cell or other hydrogen gas consuming unit.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This is a continuation under 35 USC 120 of U.S. patent application Ser. No. 10 / 575,556 filed Apr. 10, 2006 in the names of J. Donald Carruthers, et al. for “Hydrogen Generation,” issuing Aug. 24, 2010 as U.S. Pat. No. 7,780,747, which in turn is a U.S. national phase of International Patent Application PCT / US04 / 33915 filed Oct. 14, 2004 and claiming the benefit of priority of U.S. Provisional Patent Application No. 60 / 510,983 filed Oct. 14, 2003 in the names of J. Donald Carruthers, et al. The disclosures of U.S. patent application Ser. No. 10 / 575,556, International Patent Application PCT / US04 / 33915 and U.S. Provisional Patent Application No. 60 / 510,983 are hereby incorporated herein by reference in their respective entireties, for all purposes.FIELD OF THE INVENTION[0002]The instant invention relates generally and specifically to solving the problem of insufficient hydrogen storage capacity in a vessel or tank, while simultaneously permi...

AI Technical Summary

Problems solved by technology

As the world's population expands, so does the use of carbon-based fuels with a concomitant increase in the amount of carbon dioxide released into the atmosphere.

Furthermore, the extraction and movement of fossil fuels around the globe exacerbates global pollution and is a causative factor in the strategic military struggles between nations.

However, further decreases in carbon released into the atmosphere are necessary to stave off future catastrophes caused by a runaway greenhouse effect.

Hydrogen is the “ultimate fuel.” While the world's oil reserves are depletable, the supply of hydrogen remains virtually unlimited.

Furthermore, hydrogen, although presently more expensive than petroleum, is an inherently low cost fuel.

To date, the greatest challenge is undoubtedly the need for a cost-effective, on-board hydrogen storage system that will meet the DOE minimum vehicle range of 300 miles within the weight and volume constraints of the vehicle.

DOE emphasizes that this is the greatest challenge, since no hydrogen storage technology available today can meet the DOE cost and performance targets even in light of the well-developed hydrogen production and fuel cell technologies (Farrauto, R., ACS Division of Fuel Chemistry, 226th ACS National Meeting, New York, September 2003, paper No. 87, “Catalysts for the Hydrogen Economy”).

This is unacceptable knowing that almost 23 moles of hydrogen gas must be oxidized to release as much energy as the combustion of 1 mole of octane.

Storage of hydrogen as a liquid also has disadvantages because liquid hydrogen must be kept extremely cold (below −253° C.) and is highly volatile if spilled.

Moreover, liquid hydrogen is energetically expensive to liquefy and maintain in the liquefied state.

Whether stored as a liquid or gas, hydrogen storage is highly dangerous due to the flammability of the gas.

Conventional adsorption methods and materials have been shown to be completely inadequate.

These technologies, while promising, introduce other challenges, such as poor gravimetric energy density of the fuel (McEnaney, B., “Go Further with H2,” Chem. in Britain, 39(1), 24 (2003)), and the fact that the solid hydrides must be heated to relatively high temperatures in order to release hydrogen.

However, these devices require increasing amounts of portable electric power.

Currently available battery packs are heavy and unwieldy and function for only a few hours at a time before requiring recharge.

One downside to the use of methanol is that the catalytic treatment process uses some of the produced hydrogen fuel to convert methanol to hydrogen fuel, which is highly inefficient.

However, because it is unfavorable to transport heavy, high pressure compressed hydrogen gas cylinders, methanol is still the re-generator of choice.

Conventional high pressure gas cylinders are susceptible to leakage from damaged or malfunctioning regulator assemblies, as well as to rupture or other unwanted bulk release of gas from the cylinder if internal decomposition of the gas leads to rapid increasing interior gas pressure in the cylinder.

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