Reinforcement treatment of bisphenol waste water

An enhanced treatment, bisphenol technology, applied in water/sewage treatment, chemical instruments and methods, light water/sewage treatment, etc., can solve the problems of long treatment time, transfer to another state, low degradation efficiency, etc. To achieve the effect of no secondary pollution

Inactive Publication Date: 2006-05-31
WUHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Bisphenols are the main chemical raw materials for the production of polycarbonate, epoxy resin, phenolic resin, polyacrylate and tooth sealant, etc., and have a wide range of applications in chemical industry, light industry, electronics, electromechanical, instrumentation, construction industry and food industry They can enter the environment through various channels during production and use. However, this is a typical type of environmental endocrine disruptors. After entering the human body and animals, they can cause dysfunction, such as reproductive disorders, developmental abnormalities, and certain immune disorders. Diseases of the system and nervous system have attracted great attention from academia and the public in recent years. Therefore, it is of great practical significance to human beings to deal with such substances reasonably and safely. At present, the traditional methods for dealing with such substances are: chemical Oxidation method, electrochemical oxidation method, physical adsorption method, biodegradation and other methods, and these methods have certain problems in terms of processing time, efficiency and cost. For example, biological methods mainly use the metabolism of microorganisms, so the processing time is long , and the degradation efficiency is not high, the treatment cost of chemical oxidation and electrochemical oxidation is relatively high, and the physical adsorption method can only transfer pollutants from one state to another state, but cannot fundamentally solve the treatment problem of such substances. Therefore, an efficient, simple, economical and safe treatment method is needed, and the photochemical method developed in recent years provides a good solution for the treatment of toxic and harmful refractory persistent organic substances in the environment.

Method used

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  • Reinforcement treatment of bisphenol waste water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] Example 1: Add β-cyclodextrin to a simulated water sample containing 100 mg / L of bisphenol A (bisphenol A, BPA), the content of which is 500 mg / L, and the pH of the photoreaction solution is around 7.0. In 30 minutes, the photodegradation rate of bisphenol A after molecular recognition can be increased by 60%, and the reaction rate constant can be increased by 11.0 times.

Embodiment 2

[0012] Example 2: Add β-cyclodextrin to a simulated water sample containing 100 mg / L of bisphenol E (bisphenol E, BPE), the addition amount is 530 mg / L, the pH of the photoreaction solution is about 7.0, and the light is irradiated under ultraviolet light After 60 minutes, the photodegradation rate of bisphenol E after molecular recognition can be increased by 55%, and the reaction rate constant can be increased by 5.4 times.

Embodiment 3

[0013] Example 3: Add β-cyclodextrin to a simulated water sample containing 100 mg / L of bisphenol F (BPF), the addition amount is 570 mg / L, the pH of the photoreaction solution is around 7.0, and the light is irradiated under ultraviolet light In 60 minutes, the photodegradation efficiency of bisphenol F after molecular recognition can be increased by 40%, and the reaction rate constant can be increased by 2.3 times.

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Abstract

A fortified treatment of bisphenol waste water is carried out by adding ª‰-cyclodextrin into waste-water containing bisphenol substances in proportion of 5:1í½10:1, forming stable clathrate compound, and light degrading at normal temperature and pressure with ultraviolet light as light source. It can improve bisphenol substance light degradation efficiency by 40-60% and reaction speed ratio 2.3-11.0 times. It is cheap, simple and has no secondary pollution.

Description

technical field [0001] The invention relates to a selective strengthening treatment method for wastewater containing bisphenols. Background technique [0002] Bisphenols are the main chemical raw materials for the production of polycarbonate, epoxy resin, phenolic resin, polyacrylate and tooth sealant, etc., and have a wide range of applications in chemical industry, light industry, electronics, electromechanical, instrumentation, construction industry and food industry They can enter the environment through various channels during production and use. However, this is a typical type of environmental endocrine disruptors. After entering the human body and animals, they can cause dysfunction, such as reproductive disorders, developmental abnormalities, and certain immune disorders. Diseases of the system and nervous system have attracted great attention from academia and the public in recent years. Therefore, it is of great practical significance to human beings to deal with s...

Claims

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Application Information

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IPC IPC(8): C02F1/58C02F1/32
Inventor 王光辉吴峰张旭邓南圣
Owner WUHAN UNIV
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