Method for raising titanium dioxide film self-cleaning glass photocatalytic activity
A technology of photocatalytic activity and titanium dioxide, which is applied in the fields of glass, self-cleaning and air purification, ceramics or other building materials surface antifouling, which can solve the problems of no self-cleaning, low catalytic activity, increased coating time and cost, etc. Achieve the effect of improving photocatalytic activity, reducing coating cost and reducing coating time
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Embodiment 1
[0007] Example 1: Accurately measure a certain amount of butyl titanate (17.02ml) and diethanolamine (4.08ml) and dissolve in absolute ethanol (67.28ml), and stir for 2h; then add water and absolute ethanol The mixture (0.9ml of water and 10ml of absolute ethanol) was stirred for 30min to obtain a stable, uniform, clear and transparent yellow-orange sol. TiO 2 The composition of the sol is: Ti(OC 4 h 9 ) 4 :EtOH:H 2 O:NH(C 2 h 5 Oh) 2 =1:26.5:1:1 (molar ratio). TiO 2 The film is prepared from the above-mentioned sol precursor by dipping and pulling with a clean glass slide as the substrate, and the pulling speed is 2mms -1 , after drying the wet film at 100°C for 10min, put it in a muffle furnace at 500°C, keep it warm for 1h, take it out and let it cool down to room temperature naturally, then you can get TiO 2 film. Repeat the above operations to obtain films with different thicknesses. The film was then subjected to surface acid treatment, the acid used was 1MH ...
Embodiment 2
[0008] Embodiment 2: except that substrate adopts quartz glass, other conditions are exactly the same as embodiment 1, when on the quartz glass surface TiO 2 When the thickness of the film is 0.50um, TiO before and after sulfuric acid solution treatment 2 The reaction rate constants of the films are 0.0263 and 0.0355, respectively.
Embodiment 3
[0009] Embodiment 3: In order to increase TiO 2 The porosity, specific surface area and surface hydroxyl content of the film surface, in the above TiO 2 Add an appropriate amount of organic high polymer polyethylene glycol (PEG) (molecular weight is 2000) as template agent in the solution, other conditions are exactly the same as embodiment 1, then prepare TiO 2 film. TiO 2 The composition of the sol is shown in Table 1.
[0010]
sample
Ti(OC 4 h 9 ) 4
/ ml
NH(C 2 h 5 O) H) 2
/ ml
h 2 o
/ ml
C 2 h 5 Oh
/ ml
PEG
/ g
T 05 D. 1 h 1 E.
17.02
4.08
0.9
77.28
0
T 05 D. 1 h 1 EP 025
17.02
4.08
0.9
77.28
0.25
2000PEG
T 05 D. 1 h 1 EP 05
17.02
4.08
0.9
77.28
0.5
2000PEG
T 05 D. 1 h 1 EP 10
17.0...
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