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Polycarboxylate superplasticizer capable of effectively resisting influence of flocculating agent and preparation method of polycarboxylate superplasticizer

A technology of flocculant and polycarboxylic acid, which is applied in the field of water reducing agent, can solve the problems of concrete slump loss, low concrete strength, and reduce concrete fluidity, so as to achieve low viscosity, facilitate pumping, and improve wrapping property entanglement effect

Active Publication Date: 2022-05-13
SICHUAN TONGZHOU CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Aiming at the above-mentioned deficiencies in the prior art, the present invention provides a polycarboxylate water reducer that can effectively resist the influence of flocculants and its preparation method. The polycarboxylate water reducer can effectively solve the existing problems of existing water reducers. When the residual amount of flocculant in the machine-made sand is high, the viscosity of the concrete material will increase, which will reduce the fluidity of the concrete and accelerate the loss of the slump of the concrete, and the amount of the water reducing agent needs to be increased a lot or doubled, and the concrete strength will be lowered, etc. question

Method used

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  • Polycarboxylate superplasticizer capable of effectively resisting influence of flocculating agent and preparation method of polycarboxylate superplasticizer
  • Polycarboxylate superplasticizer capable of effectively resisting influence of flocculating agent and preparation method of polycarboxylate superplasticizer

Examples

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Effect test

Embodiment 1

[0030] A kind of polycarboxylate water reducing agent that effectively resists the influence of flocculant, its preparation method comprises the following steps:

[0031] (1) Add 335 parts of diethylene glycol monovinyl polyoxyethylene ether macromonomer, 3.2 parts of 32% sodium hydroxide solution and 280 parts of deionized water into the reaction kettle, stir until it dissolves until there is no obvious lump solution in shape or sheet;

[0032] (2) Measure the temperature in the reactor, control the initial temperature to 21° C., and throw in 3.4 parts of hydrogen peroxide and 0.009 part of rhodium (II) acetate dimer at one time;

[0033] (3) After 5 minutes, start to drop the solution A consisting of 0.7 parts of 2-hydroxy-2-sulfinic acid-disodium salt, 1.6 parts of 2-mercaptoethanol and 136 parts of deionized water, and the dropping time is 1.25 hours ;

[0034] (4) After another 2 minutes, start to drop the mixture prepared by adding 16 parts of acrylic acid, 32 parts of...

Embodiment 2

[0037] A kind of polycarboxylate water reducing agent that effectively resists the influence of flocculant, its preparation method comprises the following steps:

[0038] (1) Add 340 parts of diethylene glycol monovinyl polyoxyethylene ether macromonomer, 3.4 parts of 28% ammonia water and 290 parts of deionized water into the reaction kettle, stir until it dissolves until there are no obvious lumps or flakes solution;

[0039] (2) Measure the temperature in the reactor, control the initial temperature to 22°C, and throw in 3.6 parts of tert-butyl hydroperoxide and 0.006 parts of palladium acetate at one time;

[0040] (3) After 5 minutes, start dropwise adding solution A consisting of 0.9 parts of 2-hydroxyphenyl hydroxymethylsulfinic acid-sodium salt, 1.8 parts of 3-mercaptopropionic acid isooctyl ester and 142 parts of deionized water. 1.2h;

[0041] (4) After another 1min, start to add 16.6 parts of acrylic acid, 34 parts of methacryloxyethylpyrrolidone, 5.8 parts of tet...

Embodiment 3

[0044] A kind of polycarboxylate water reducing agent that effectively resists the influence of flocculant, its preparation method comprises the following steps:

[0045] (1) Add 350 parts of 4-hydroxybutyl vinyl ether polyoxyethylene ether macromonomer, 3.6 parts of 32% sodium hydroxide solution and 300 parts of deionized water into the reaction kettle, stir until it dissolves until there is no obvious lump solution in shape or sheet;

[0046] (2) Measure the temperature in the reactor, control the initial temperature to 16°C, and throw in 3.2 parts of tert-butyl hydroperoxide and 0.008 parts of ruthenium acetate at one time;

[0047] (3) After 5 minutes, start dropwise adding solution A consisting of 0.82 parts of 2-hydroxy-2-sulfinic acid-zinc salt, 1.5 parts of 3-mercaptopropionic acid and 145 parts of deionized water, and the dropping time is 1.2 hours ;

[0048] (4) After another 2 minutes, start to add 13.6 parts of methacrylic acid, 4.2 parts of crotonic acid, 33.6 p...

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Abstract

The invention discloses a polycarboxylate superplasticizer capable of effectively resisting the influence of a flocculating agent and a preparation method of the polycarboxylate superplasticizer. The water reducing agent is prepared from the following components in parts by weight: 330 to 350 parts of unsaturated polyether macromonomer, 3 to 6 parts of alkaline stabilizer, 0.005 to 0.012 part of transition metal salt catalyst, 2.5 to 5.0 parts of oxidizing agent, 0.5 to 1.0 part of reducing agent, 1 to 3 parts of chain transfer agent, 15 to 20 parts of unsaturated carboxylic acid, 25 to 35 parts of methacryloyloxyethyl pyrrolidone monomer, 5 to 8 parts of fluoro functional monomer and 0.5 to 1.0 part of crosslinking slow-release monomer. 10-20 parts of a sodium hydroxide solution; and deionized water. The polycarboxylic acid water reducer can effectively solve the problems that when the residual amount of a flocculating agent in machine-made sand is high, the viscosity of a concrete material is increased, the flowability of the concrete is reduced, the slump loss of the concrete is accelerated, the mixing amount of the water reducer needs to be greatly increased or doubled, the strength of the concrete is reduced and the like in the existing water reducer.

Description

technical field [0001] The invention relates to the technical field of water reducers, in particular to a polycarboxylate water reducer that can effectively resist the influence of flocculants and a preparation method thereof. Background technique [0002] Polycarboxylate superplasticizer is the most widely used concrete admixture at present. It has the advantages of low dosage, high water reducing rate, strong designability of molecular structure, good dispersibility, good slump retention performance, wide applicability, and production It is simple, green and pollution-free, and is widely used in the field of construction engineering. It is a research hotspot in the field of concrete admixtures at this stage. [0003] In recent years, with the rapid development of my country's economy, the amount of concrete has increased dramatically. Sand and gravel are the main raw materials in concrete. The excessive mining and consumption of natural sand has caused adverse effects on ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F220/06C08F220/36C08F220/24C08F222/14C08F222/20C08F220/04C08F222/02C04B24/26C04B103/30
CPCC08F283/065C04B24/2694C04B2103/302C08F220/06C08F220/36C08F220/24C08F222/102C08F220/04C08F222/02Y02W30/91
Inventor 舒学军万甜明舒豆豆何年梁青松赵涛
Owner SICHUAN TONGZHOU CHEM TECH
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