Halogen-free flame-retardant polypropylene material for automotive interiors and preparation method thereof

A technology for flame-retardant polypropylene and automotive interiors, applied in the field of polymer material modification, can solve problems such as poor odor, low toughness, and precipitation of flame retardants, and achieve increased compatibility, good flame retardancy, and improved toughness. performance effect

Pending Publication Date: 2022-02-08
江苏尚艾新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the prior art, although polypropylene has a good flame retardant effect, the problems of low toughness, flame retardant precipitation, and bad smell cannot be solved at the same time.

Method used

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  • Halogen-free flame-retardant polypropylene material for automotive interiors and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A halogen-free flame-retardant polypropylene material for automotive interiors, comprising the following raw materials in parts by weight: 55 parts of polypropylene, 12.5 parts of coated ammonium polyphosphate, 6.25 parts of piperazine pyrophosphate, and 6.25 parts of synergistic flame retardant , 0.5 parts of coupling agent, 5 parts of inorganic filler, 15 parts of toughening agent, 0.5 part of deodorant, 0.6 part of stabilizer;

[0029] Among them, the preparation method of coated ammonium polyphosphate is: add 50g APP to 200mL of absolute ethanol, ultrasonically disperse for 0.5h, disperse evenly, adjust PH≈6 with 15% hydrochloric acid, slowly raise the temperature to 85°C, first add an appropriate amount of For melamine-formaldehyde prepolymer, keep the temperature at 85°C, keep stirring for 2 hours, then add the same amount of epoxy resin, and add a curing agent to react for 0.5 hours to cure the epoxy resin (EP) and make melamine-formaldehyde resin (MF) ) and epox...

Embodiment 2

[0035] A halogen-free flame-retardant polypropylene material for automotive interiors, comprising the following raw materials in parts by weight: 52 parts of polypropylene, 14 parts of coated ammonium polyphosphate, 7 parts of piperazine pyrophosphate, and 7 parts of synergistic flame retardant , 0.8 parts of coupling agent, 5 parts of inorganic filler, 15 parts of toughening agent, 0.5 part of deodorant, 0.3 part of stabilizer;

[0036]Among them, the preparation method of coated ammonium polyphosphate is: add 50g APP to 200mL of absolute ethanol, ultrasonically disperse for 0.5h, disperse evenly, adjust PH≈6 with 15% hydrochloric acid, slowly raise the temperature to 85°C, first add an appropriate amount of For melamine-formaldehyde prepolymer, keep the temperature at 85°C, keep stirring for 2 hours, then add the same amount of epoxy resin, and add a curing agent to react for 0.5 hours to cure the epoxy resin (EP) and make melamine-formaldehyde resin (MF) ) and epoxy resin d...

Embodiment 3

[0042] A halogen-free flame-retardant polypropylene material for automotive interiors, comprising the following raw materials in parts by weight: 50 parts of polypropylene, 15 parts of coated ammonium polyphosphate, 7.5 parts of piperazine pyrophosphate, and 7.5 parts of synergistic flame retardant , 1.5 parts of coupling agent, 5 parts of inorganic filler, 15 parts of toughening agent, 0.5 part of deodorant, 0.6 part of stabilizer;

[0043] Among them, the preparation method of coated ammonium polyphosphate is: add 50g APP to 200mL of absolute ethanol, ultrasonically disperse for 0.5h, disperse evenly, adjust PH≈6 with 15% hydrochloric acid, slowly raise the temperature to 85°C, first add an appropriate amount of For melamine-formaldehyde prepolymer, keep the temperature at 85°C, keep stirring for 2 hours, then add the same amount of epoxy resin, and add a curing agent to react for 0.5 hours to cure the epoxy resin (EP) and make melamine-formaldehyde resin (MF) ) and epoxy re...

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Abstract

The invention discloses a halogen-free flame-retardant polypropylene material for automotive interiors, which is prepared from the following raw materials in parts by weight: 40-70 parts of polypropylene, 10-20 parts of coated ammonium polyphosphate, 5-10 parts of piperazine pyrophosphate, 5-10 parts of a synergistic flame retardant, 0.5-2 parts of a compatilizer, 0-10 parts of an inorganic filler, 10-20 parts of a flexibilizer, 0.2-1 part of a deodorant and 0.3-1.5 parts of a stabilizer, wherein the coated ammonium polyphosphate is prepared by carrying out surface coating modification on high-polymer ammonium polyphosphate by using melamine formaldehyde and epoxy resin. The polypropylene material provided by the invention not only meets the requirement for flame retardant property, but also has the characteristics of excellent rigid-tough balance, precipitation resistance and low odor, is suitable for being applied to automobile industry interiors, and is particularly suitable for passenger car interiors.

Description

technical field [0001] The invention relates to the technical field of polymer material modification, in particular to a halogen-free flame-retardant polypropylene material for automobile interior decoration and a preparation method thereof. Background technique [0002] With the improvement of people's awareness of safety and environmental protection, especially the frequent occurrence of bus fire accidents in recent years, the society has paid great attention to the combustion safety performance of bus materials. The latest national standard "GB38262-2019 Combustion Characteristics of Passenger Car Interior Materials" will be officially implemented on July 1, 2020. The new national standard puts forward stricter requirements for horizontal combustion, vertical combustion, oxygen index, and smoke density. In addition, people have higher and higher requirements for the air quality in the car, and major domestic and foreign automobile manufacturers have made clear requirement...

Claims

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Application Information

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IPC IPC(8): C08L53/00C08L23/12C08L23/08C08K9/10C08K9/06C08K3/32C08K5/3462C08K7/26C08K7/10
CPCC08L53/00C08L23/12C08L2201/02C08L2201/22C08K2003/323C08L23/0815C08K9/10C08K9/06C08K3/32C08K5/3462C08K7/26C08K7/10
Inventor 李青松康兴宾张朕豪辛文博
Owner 江苏尚艾新材料科技有限公司
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