High-ductility cement-based composite material and preparation method thereof
A composite material, cement-based technology, used in fiber types, textiles and papermaking, ultrasonic/sonic fiber processing, etc., can solve problems such as poor fracture toughness, prone to cracking, building damage, etc., to achieve the effect of improving strength and toughness
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[0037] Preparation Examples of Raw Materials and Intermediates
[0038] raw material
[0039] The cement is PO5 2.5 cement;
[0040] Fly ash is a first-class fly ash;
[0041] Mineral powder is S105 mineral powder;
[0042] The water reducer is a high-efficiency polycarboxylate water reducer;
[0043] Starch ether is potato starch ether;
[0044] Polyoxyethylene polyoxypropylene block copolymer, CAS No. 9003-11-6, molecular weight 102.132;
[0045] Fatty alcohol polyoxyethylene ether phosphate potassium salt, model MOA3PK;
[0046] The higher carbon alcohol phosphate is cetostearyl phosphate;
[0047] The emulsifier is fatty alcohol polyoxyethylene ether, the model is AE09.
preparation example 1
[0050] The preparation method of modified polyvinyl alcohol fiber:
[0051] A1. 10kg polyoxyethylene polyoxypropylene block copolymer, 10kg fatty alcohol polyoxyethylene ether phosphate potassium salt, 10kg higher carbon alcohol phosphate ester salt are mixed homogeneously, then add 2000kg emulsifier and mix homogeneously, make dispersant;
[0052] A2. Soak the polyvinyl alcohol fiber in acetone solution, heat and reflux for 5 hours, take out the polyvinyl alcohol fiber, wash it twice with water, and then dry it to constant weight at 100°C;
[0053] A3. Mix the polyvinyl alcohol fibers treated in A2 with the dispersant obtained in A1. The solid-to-liquid ratio is 1:200. Shake at room temperature for 0.5h at a speed of 135r / min, then take out the sample and dry it to constant weight at 100°C , to obtain modified polyvinyl alcohol fiber
preparation example 2
[0055] The preparation method of modified polyoxymethylene fiber:
[0056] B1. Wash the polyoxymethylene fiber with absolute ethanol, and then vacuum-dry the polyoxymethylene fiber at 90°C for 2 hours;
[0057] B2. Treat the polyoxymethylene fibers cleaned by B1 in a plasma processor for 60s. The processing parameters of the plasma processor are: air atmosphere, 400W power, and 3mm distance between two electrodes;
[0058] B3. The polyoxymethylene fiber treated by B2 is immediately immersed in nano-SiO with a mass concentration of 3%. 2 In aqueous solution, and at 60°C, oscillate for 3 hours at a speed of 135r / min, then take out the polyoxymethylene fiber, wash it with water three times, and dry it at 90°C until constant weight to obtain the modified polyoxymethylene fiber.
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