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Solvent adhesive for SEBS-based plastic runway bonding and preparation method thereof

A technology based on plastic and track, applied in the direction of adhesives, adhesive types, rubber-derived adhesives, etc., can solve the problems of low strength and slow bonding speed, and achieve high strength, fast bonding speed, and high-strength bonding Effect

Active Publication Date: 2021-03-16
江苏瑞弗橡塑材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the above technical problems, the present invention provides a solvent glue for bonding SEBS-based plastic runways and a preparation method thereof, which can solve the problems of low strength and slow bonding speed in the bonding process of SEBS-based runways.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0038] A kind of preparation method of the solvent glue that is used for SEBS base plastic runway bonding, comprises the following steps:

[0039] Step 1: Weigh 10-30 parts of thermoplastic elastomer TPE, 10-40 parts of tackifying resin, 20-30 parts of mineral spirits, and 10-20 parts of ester solvent in parts by weight, and pour them into the reaction kettle in turn as the bottom Material, control the reaction temperature at 78°C-82°C by reflux to completely dissolve it.

[0040] Step 2: React 100 parts of hydroxyl-terminated polybutadiene, 10-30 parts of isocyanate molecules, and 0.1-1.0 parts of organotin catalyst under nitrogen protection at 60°C for 6 hours to control the relationship between hydroxyl-terminated polybutadiene and isocyanate molecules. The molar ratio is 1:2-1:3 to obtain isocyanate-terminated polybutadiene.

[0041] Step 3: Weigh 20-60 parts of isocyanate-terminated polybutadiene, add it into the mixed system dissolved in Step 1, stir evenly under nitrog...

specific Embodiment 1

[0044] A solvent glue used for SEBS-based plastic runway bonding is prepared by the following steps:

[0045] (1) Weigh 10 parts of SEBS, 20 parts of naphthenic oil 4006, 40 parts of terpene resin, and 20 parts of butyl acetate in parts by weight, and pour them into a heating stainless steel reaction kettle in turn as a base material, through Reflux to control the reaction temperature at 80°C to make it dissolve completely and form a dissolved mixed system.

[0046] (2) Weigh 100 parts of hydroxyl-terminated polybutadiene (M n =2000), 17.4 parts of toluene diisocyanate, 0.2 parts of stannous octoate were reacted for 6 hours at 60°C under nitrogen protection, and the molar ratio of hydroxyl-terminated polybutadiene to isocyanate molecules was controlled to be 1:2 to obtain isocyanate-terminated polybutylene Diene.

[0047] (3) Weigh 30 parts of isocyanate-terminated polybutadiene, add it into the above-mentioned dissolved mixing system, stir evenly under the protection of nit...

specific Embodiment 2

[0050]A solvent glue used for SEBS-based plastic runway bonding is prepared by the following steps:

[0051] (1) Weigh 30 parts of SBS, 30 parts of mineral spirits, 10 parts of C5 petroleum resin, and 10 parts of butyl acetate in parts by weight, and pour them into a heating stainless steel reaction kettle in turn as a base material, controlled by reflux The reaction temperature is 80°C to make it dissolve completely to form a dissolved mixed system.

[0052] (2) Weigh 100 parts of hydroxyl-terminated polybutadiene (M n =2000), 22.2 parts of isophorone diisocyanate, 0.3 parts of stannous octoate were reacted for 6 hours at 60°C under nitrogen protection, and the molar ratio of hydroxyl-terminated polybutadiene to isocyanate molecules was controlled to be 1:2 to obtain isocyanate-blocked terminal polybutadiene.

[0053] (3) Weigh 50 parts of isocyanate-terminated polybutadiene, add it into the above-mentioned dissolved mixing system, stir evenly under the protection of nitrog...

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Abstract

The invention discloses a solvent adhesive for SEBS-based plastic runway bonding and a preparation method thereof. The solvent adhesive is mainly prepared from the following raw materials in parts byweight: 10-30 parts of thermoplastic elastomer TPE, 10-40 parts of tackifying resin, 20-30 parts of solvent oil, 10-20 parts of an ester solvent and 20-60 parts of isocyanate-terminated polybutadiene.The isocyanate-terminated polybutadiene is obtained by reacting 100 parts of hydroxyl-terminated polybutadiene, 10-30 parts of isocyanate molecules and 0.1-1.0 part of an organic tin catalyst. The solvent adhesive realizes rapid initial adhesion with a runway by virtue of the thermoplastic elastomer TPE and the tackifying resin after solvent volatilization within 10 minutes, and the bonding strength is improved by virtue of isocyanate water vapor curing in the later period. The solvent adhesive developed by the invention has the characteristics of fast initial adhesion, strong adhesion, stable properties after curing and the like.

Description

technical field [0001] The invention relates to the field of chemical process solvent glue, in particular to a solvent glue used for bonding SEBS-based plastic runways and a preparation method thereof. Background technique [0002] With the country's vigorous advocacy of national sports, the demand for sports venues, especially plastic tracks, has increased year by year, and higher requirements have been put forward for the durability and construction methods of plastic tracks. The prefabricated SEBS-based plastic runway, as a new type of fully recyclable and environmentally friendly plastic runway, can replace the traditional on-site paved runway and has better stability. It has been popularized and applied in various sports venues. However, how to achieve stable side bonding between prefabricated plastic runways is a problem that the industry needs to solve urgently. [0003] At present, there is no mature solution for the side bonding between prefabricated plastic runway...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J153/02C09J145/00C09J193/04C09J115/00C09J157/02C09J11/08C09J11/00
CPCC09J115/00C09J145/00C09J11/08C09J11/00C08L2205/03C08L2207/04C08L53/025C08L15/00C08L53/02C08L57/02C08L93/04C08L45/00
Inventor 高文通韩冰陈韶郭晓明赵辉黄玉安曹潇周松乐罗彦余保寅张波张奕磊
Owner 江苏瑞弗橡塑材料有限公司
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