High-temperature-resistant nitrification inhibitor as well as preparation method and application thereof
A technology of nitrification inhibitor and high temperature resistance, which is applied in application, agricultural gas emission reduction, fertilizer mixture, etc. It can solve the problems of unusable, low environmental pollution, and high temperature resistance, and achieve low cost, low environmental pollution, and stability Good results
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Embodiment 1
[0035] A high temperature resistant nitrification inhibitor, the steps are as follows:
[0036] Step 1: Add 200g distilled water, 20g calcium silicate and 27g mass concentration of 98% hydrochloric acid aqueous solution to the reaction kettle with temperature sensor and stirrer, mix and disperse evenly, and heat it from Room temperature rises to 80°C;
[0037] Step 2: Add 60g of acrylic acid and 45g of 3,4-dimethylpyrazole to the system of Step 1, mix and disperse evenly;
[0038] Step 3: slowly add 9g composite initiator (ammonium persulfate / ammonium bicarbonate / tert-butyl peroxybenzoate, ammonium persulfate, ammonium bicarbonate and tert-butyl peroxybenzoate) in step (two) system The molar ratio is 1:1:1); then react at 80°C for 2h, and finally cool down to collect the product. The above reactions do not require additional introduction of protective gas.
[0039] The nitrification inhibitor prepared in this example was tested by gel permeation chromatography, and its numb...
Embodiment 2
[0043] A high-temperature-resistant nitrification inhibitor, as described in Example 1, the difference is: the heating rate in step 1 is 1°C / min, and the heating temperature is 40°C, and other steps and conditions are the same as in Example 1.
Embodiment 3
[0045] A high temperature resistant nitrification inhibitor, as described in Example 1, the difference is: the quality of the composite initiator, calcium silicate, hydrochloric acid, 3,4-dimethylpyrazole, acrylic acid, distilled water is respectively 11g, 44g, 35g, 63g, 76g and 400g; other steps and conditions are the same as in Example 1.
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