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Smelting furnace and smelting method for recovering electrolyte from aluminum electrolysis carbon residues

An electrolyte and smelting furnace technology, applied in the field of aluminum electrolysis, can solve the problems of low production efficiency, long roasting time, harsh working environment, etc., and achieve the effects of improving processing efficiency, increasing reaction area, and convenient process control

Inactive Publication Date: 2020-08-18
中铝郑州有色金属研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Disadvantages of carbon slag flotation method: low electrolyte recovery rate; high carbon content (about 5%) in recovered electrolyte, which is not conducive to returning to aluminum electrolysis production; flotation wastewater contains fluoride ions, and wastewater treatment is required
Disadvantages of charcoal slag roasting method: long roasting time, low production efficiency, which is not conducive to large-scale treatment of charcoal slag; labor intensity is high, and the working environment is harsh

Method used

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  • Smelting furnace and smelting method for recovering electrolyte from aluminum electrolysis carbon residues
  • Smelting furnace and smelting method for recovering electrolyte from aluminum electrolysis carbon residues

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Effect test

Embodiment 1

[0023] A smelting furnace for recovering electrolyte from aluminum electrolytic carbon slag according to the present invention is adopted. The smelting furnace is a vertical smelting furnace, which includes a feed inlet 1 at the top, a flue gas outlet 2, a furnace body 3 at the middle, and a Combustion aid inlet 5 near the bottom, fuel inlet 6, electrolyte overflow outlet 7 and electrolyte collection pool 8 at the bottom, the furnace body 3 includes: cryolite layer, corrosion-resistant layer, refractory material layer, heat preservation Material layers and steel plates. The corrosion-resistant layer is made of carbon material with a thickness of 10mm; the refractory material layer has a heat resistance of 1250°C and a thickness of 300mm; the thermal conductivity of the thermal insulation material used in the insulating material layer is 0.45W / (m K) at 25°C, and the thickness is 300mm; the thickness of the steel plate is 3mm.

[0024] Use the carbon contained in the carbon slag...

Embodiment 2

[0031] A smelting furnace for recovering electrolyte from aluminum electrolytic carbon slag according to the present invention is adopted. The smelting furnace is a vertical smelting furnace, which includes a feed inlet 1 at the top, a flue gas outlet 2, a furnace body 3 at the middle, and a Combustion aid inlet 5 near the bottom, fuel inlet 6, electrolyte overflow outlet 7 and electrolyte collection pool 8 at the bottom, the furnace body 3 includes: cryolite layer, corrosion-resistant layer, refractory material layer, heat preservation Material layers and steel plates. The corrosion-resistant layer is made of silicon nitride material with a thickness of 50mm; the refractory material layer has a heat resistance of 1300°C and a thickness of 240mm; the heat-insulating material used for the heat-insulating material layer has a thermal conductivity of 0.35W / (m K) at 25°C and a thickness of 230mm; the thickness of the steel plate 7mm.

[0032] Utilize the carbon contained in the c...

Embodiment 3

[0039]A smelting furnace for recovering electrolyte from aluminum electrolytic carbon slag according to the present invention is adopted. The smelting furnace is a vertical smelting furnace, which includes a feed inlet 1 at the top, a flue gas outlet 2, a furnace body 3 at the middle, and a Combustion aid inlet 5 near the bottom, fuel inlet 6, electrolyte overflow outlet 7 and electrolyte collection pool 8 at the bottom, the furnace body 3 includes: cryolite layer, corrosion-resistant layer, refractory material layer, heat preservation Material layers and steel plates. The corrosion-resistant layer is made of silicon nitride combined with silicon carbide material, with a thickness of 80mm; the refractory material layer has a heat resistance of 1400°C and a thickness of 180mm; the heat-insulating material used for the heat-insulating material layer has a thermal conductivity of 0.3W / (m K) at 25°C and a thickness of 160mm ; Steel plate thickness 12mm.

[0040] Use the carbon co...

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Abstract

The invention discloses a smelting furnace for recovering electrolyte from aluminum electrolysis carbon residues. The smelting furnace is a vertical smelting furnace and comprises a feed port, a fluegas outlet, a furnace body, a combustion improver adding port, a fuel adding port, an electrolyte overflow port and an electrolyte collecting tank at the bottom, wherein the feed port and the flue gasoutlet are located at the top position, the furnace body is located at the middle position, and the combustion improver adding port, the fuel adding port and the electrolyte overflow port are locatednear the bottom; and the furnace body comprises a cryolite layer, a corrosion-resistant layer, a refractory material layer, a thermal insulation material layer and a steel plate from inside to outside. According to the smelting furnace for recovering the electrolyte from the aluminum electrolysis carbon residues, the carbon residues and hot gas flow make reverse contact in the smelting furnace, so that the reaction area is increased, and the processing efficiency is improved; the electrolyte contained in the carbon residues is melted by utilizing the calorific value of the carbon residues, and meanwhile, process parameters can be adjusted according to different components of the carbon residues, so that process control is convenient; and the high-melting-point cryolite protective layer isformed on the inner wall of the smelting furnace in the operation process, so that corrosion of reaction materials to a furnace body lining is reduced, and the service life of the smelting furnace isguaranteed.

Description

technical field [0001] The invention belongs to the technical field of aluminum electrolysis, and relates to a melting furnace and a melting method for recovering electrolyte from aluminum electrolysis carbon slag. Background technique [0002] The existing aluminum electrolysis technology uses alumina as a raw material, molten cryolite as a solvent, and carbon body as an anode, and electrolyzes in an electrolytic cell to obtain metal aluminum liquid. In the process of aluminum electrolysis, due to the influence of uneven combustion of carbon anode, selective oxidation, erosion and erosion of aluminum liquid and electrolyte, some carbon particles fall off from the anode and enter the molten salt electrolyte, forming carbon slag. [0003] The generation of carbon slag in the electrolytic cell has a great impact on the aluminum electrolysis process. In order to ensure the normal progress of the aluminum electrolytic production process, the carbon slag in the aluminum electroly...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F27B14/08F27B14/14C25C3/06
CPCF27B14/08F27B14/14C25C3/06F27B2014/0843F27M2003/13
Inventor 李昌林周云峰汪艳芳王俊青罗丽芬王俊伟张芳芳侯光辉柴登鹏
Owner 中铝郑州有色金属研究院有限公司
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