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Preparation method of environment-friendly high-temperature-resistant water-based drilling fluid plugging anti-collapse agent

A water-based drilling fluid, plugging and anti-slump technology, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of unreachable sulfonated material properties, poor plugging performance, etc., and achieve good plugging , Effective blocking, softening effect of wide window

Active Publication Date: 2020-05-12
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Conventional materials, including polymeric materials, cannot achieve the performance of the above-mentioned sulfonated materials
For example, Chinese patent document CN108728057A discloses a nano-resin emulsion plugging agent for drilling fluid. The raw materials include acrylic acid, butyl acrylate, styrene and emulsifiers. The plugging agent prepared by this invention can plug micro-fractures during drilling. , can also play a certain role in bearing pressure and preventing collapse on the well wall, but the plugging performance is not good, and the plugging effect on high-temperature formations has not been involved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A preparation method of an environment-friendly anti-high temperature water-based drilling fluid plugging and anti-collapse agent, comprising the steps of:

[0037] a. Preparation of pre-polyemulsion:

[0038] (1) 32g styrene and 8g methyl methacrylate are mixed to obtain a mixed monomer;

[0039] (2) Dissolve 3.2g of emulsifier MS-1 in 160mL of deionized water to prepare an aqueous solution of emulsifier MS-1 with a concentration of 2wt%, add the mixed monomers obtained in the above step (1), and use a shear emulsifier emulsified to form a stable pre-polyemulsion.

[0040] b. Preparation of post-polymerization emulsion:

[0041] (3) 20g AM (acrylamide), 5g AMPS (2-acrylamido-2-methylpropanesulfonic acid), 1g DMDAAC (dimethyl diallyl ammonium chloride) and 2g emulsifier MS-1 Fully dissolve in 100ml of water to obtain an emulsion, and use 30wt% sodium hydroxide aqueous solution to adjust the pH to 7 to obtain a dispersion;

[0042] (4) 12g styrene and 3g methyl methacr...

Embodiment 2

[0048] A preparation method of an environment-friendly anti-high temperature water-based drilling fluid plugging and anti-collapse agent, comprising the steps of:

[0049] a. Preparation of pre-polyemulsion:

[0050] (1) 28g styrene and 12g methyl methacrylate are mixed to obtain mixed monomers;

[0051] (2) Dissolve 3.2g of emulsifier MS-1 in 160mL of deionized water to prepare an aqueous solution of emulsifier MS-1 with a concentration of 2wt%, add the mixed monomers obtained in the above step (1), and use a shear emulsifier emulsified to form a stable pre-polyemulsion.

[0052] b. Preparation of post-polymerization emulsion:

[0053] (3) 25g AM (acrylamide), 1g AMPS (2-acrylamido-2-methylpropanesulfonic acid), 1g DMDAAC (dimethyl diallyl ammonium chloride) and 2g emulsifier MS-1 Fully dissolve in 100ml of water to obtain an emulsion, and use 30wt% sodium hydroxide aqueous solution to adjust the pH to 7 to obtain a dispersion;

[0054] (4) 10.5g styrene and 4.5g methyl m...

Embodiment 3

[0060] A preparation method of an environment-friendly anti-high temperature water-based drilling fluid plugging and anti-collapse agent, comprising the steps of:

[0061] a. Preparation of pre-polyemulsion:

[0062] (1) 32g styrene and 8g methyl methacrylate are mixed to obtain a mixed monomer;

[0063] (2) Dissolve 3.2g of emulsifier MS-1 in 160mL of deionized water to prepare an aqueous solution of emulsifier MS-1 with a concentration of 2wt%, add the mixed monomers obtained in the above step (1), and use a shear emulsifier emulsified to form a stable pre-polyemulsion.

[0064] b. Preparation of post-polymerization emulsion:

[0065] (3) 15g AM (acrylamide), 10g AMPS (2-acrylamido-2-methylpropanesulfonic acid), 2g DMDAAC (dimethyl diallyl ammonium chloride) and 2g emulsifier MS-1 Fully dissolve in 100ml of water to obtain an emulsion, and use 30wt% sodium hydroxide aqueous solution to adjust the pH to 7 to obtain a dispersion;

[0066] (4) 10.5g styrene and 4.5g methyl ...

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PUM

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Abstract

The invention provides a preparation method of an environment-friendly high-temperature-resistant water-based drilling fluid plugging anti-collapse agent. The preparation method comprises the following steps: mixing and emulsifying a styrene monomer, an acrylic monomer and an emulsifier MS-1 aqueous solution to prepare a pre-polymerized emulsion; dispersing a hydrophilic monomer, a cationic monomer and an emulsifier MS-1 in water, adjusting the pH value to 6.5-8.5, then adding a mixed monomer of a styrene monomer and an acrylic monomer, and mixing and emulsifying to prepare a post-polymerization emulsion; adding a cross-linking agent 1 and an initiator 1 into the pre-polymerization emulsion, uniformly dispersing, and carrying out a reaction; adding the post-polymerization emulsion in a dropwise manner, adding a cross-linking agent 2 and an initiator 2, uniformly dispersing, continuously carrying out a reaction, drying, and crushing to obtain the plugging anti-collapse agent. The plugging anti-collapse agent prepared by the method is of a core-shell structure, is non-toxic and good in environmental protection performance, has excellent filtrate loss reduction, plugging and collapseprevention performances, has good temperature resistance, and can realize effective plugging and collapse prevention of a high-temperature stratum.

Description

technical field [0001] The invention relates to a preparation method of an environment-friendly anti-high temperature water-based drilling fluid plugging and anti-slumping agent, which belongs to the field of oilfield chemistry in the petroleum industry. [0002] technical background [0003] Drilling fluid is called the "blood" of drilling. Water-based drilling fluid is a complex colloid-suspension multi-level dispersion system formed by clay particles and various chemical agents in water. It is an indispensable core engineering technology in oil and gas exploration and development. It directly affects the safety and efficiency of drilling and is the key to ensure the success of drilling. [0004] Drilling fluid sulfonated materials mainly include sulfonated asphalt, sulfonated lignite, sulfonated phenolic resin, sulfonated tannin, sulfonated tannin, etc., which have strong temperature resistance and play an important role in the drilling process of deep wells, ultra-deep we...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F257/02C08F220/56C08F220/58C08F226/02C08F212/08C08F220/14C08F222/38C09K8/035
CPCC08F257/02C08F212/08C09K8/035C09K2208/04C08F220/56C08F226/02C08F220/14C08F222/385C09K8/24C09K8/426C09K8/44C08F285/00C09K8/512C09K8/516C08F220/585C08F226/04C08F257/00
Inventor 黄贤斌孙金声吕开河刘敬平白英睿王金堂金家锋
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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