Treatment method of nickel cobalt lithium manganate positive electrode material
A technology of nickel-cobalt-lithium-manganese-manganate and cathode materials, applied in chemical instruments and methods, nickel compounds, lithium carbonate;/acid carbonate, etc., can solve the waste of useful components in nickel-cobalt lithium-manganese-oxide batteries , Low resource utilization rate, low recovery rate and other issues, to reduce the loss of nickel and cobalt, realize environmental protection production, and improve the effect of recycling
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Embodiment 1
[0033] A treatment method for nickel-cobalt lithium manganese oxide cathode material, specifically comprising the following steps:
[0034] (1) calcining the nickel-cobalt-manganese positive electrode material at 300° C., and the calcining residence time is 5 minutes to obtain the calcined nickel-cobalt-manganese positive electrode material;
[0035] (2) Configure 200g / L dilute sulfuric acid solution, add it to the nickel-cobalt-manganese cathode material calcined in step (1) and heat up to 90°C for 2 hours, the solid-to-liquid ratio of the nickel-cobalt-manganese cathode material to the dilute sulfuric acid solution is 100: 1. Obtain low manganese liquid and leaching residue;
[0036] (3) The low-manganese solution is treated with a low-manganese wire, and the leaching residue is treated with a high-manganese wire.
[0037] The low manganese wire processing method specifically comprises the following steps:
[0038] S1: Raise the temperature of the low-manganese liquid to 6...
Embodiment 2
[0048] A treatment method for nickel-cobalt lithium manganese oxide cathode material, specifically comprising the following steps:
[0049] (1) calcining the nickel-cobalt-manganese positive electrode material at 600° C., and the calcining residence time is 10 minutes to obtain the calcined nickel-cobalt-manganese positive electrode material;
[0050] (2) Configure 250g / L dilute sulfuric acid solution, add it to the nickel-cobalt-manganese cathode material calcined in step (1) and heat up to 100°C for 2 hours, the solid-to-liquid ratio of the nickel-cobalt-manganese cathode material to the dilute sulfuric acid solution is 200: 1. Obtain low manganese liquid and leaching residue;
[0051] (3) The low-manganese solution is treated with a low-manganese wire, and the leaching residue is treated with a high-manganese wire.
[0052]The low manganese wire processing method specifically comprises the following steps:
[0053] S1: Raise the temperature of the low-manganese liquid to ...
Embodiment 3
[0063] A treatment method for nickel-cobalt lithium manganese oxide cathode material, specifically comprising the following steps:
[0064] (1) Calcining the nickel-cobalt-manganese positive electrode material at 400° C., with a residence time of 7 minutes to obtain the calcined nickel-cobalt-manganese positive electrode material;
[0065] (2) Configure 230g / L dilute sulfuric acid solution, add it to the nickel-cobalt-manganese cathode material calcined in step (1) and heat up to 95°C for 2 hours, the solid-to-liquid ratio of the nickel-cobalt-manganese cathode material to the dilute sulfuric acid solution is 150: 1. Obtain low manganese liquid and leaching residue;
[0066] (3) The low-manganese solution is treated with a low-manganese wire, and the leaching residue is treated with a high-manganese wire.
[0067] The low manganese wire processing method specifically comprises the following steps:
[0068] S1: Raise the temperature of the low-manganese liquid to 75°C, slowly...
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