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A kind of graphene modified carbon fiber pre-fabric and preparation method thereof

A graphene modification, carbon fiber technology, applied in the direction of carbon fiber, liquid repellent fiber, fiber treatment, etc., can solve the problems affecting power stability and life, low bonding strength, easy delamination, etc., to achieve a wide range of applications Value, the effect of increasing strength

Active Publication Date: 2022-08-02
QINGDAO GRAPHENE CARBON NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the application of carbon fiber materials, its surface active functional groups are less and inert. In the production of carbon fiber composite resin materials, the wettability and adhesion between the carbon fiber reinforced matrix and the reinforced resin are poor, resulting in low bonding strength between the carbon fiber reinforced matrix and the resin reinforced composite interface. The difference in bending strength and impact strength is easy to delaminate, which affects the structural performance of carbon fiber composite materials, and affects the power stability and life of carbon fiber composite materials for conductive heating applications. Therefore, the activity of carbon fiber bodies and the strength and toughness of epoxy resin are improved. Carbon fiber The most effective method for the performance of composite materials, which is mainly used in aviation and military fields, sports and leisure industries, automobile manufacturing industries and other industrial fields, so the application market prospect of carbon fiber composite materials is very broad

Method used

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  • A kind of graphene modified carbon fiber pre-fabric and preparation method thereof
  • A kind of graphene modified carbon fiber pre-fabric and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Example 1. Preparation of ordinary carbon fiber prepreg

[0023] The preparation method of common carbon fiber pre-fabrication comprises the following steps:

[0024] 1. Preparation of modified resin prepreg

[0025] (1) prepare resin acetone solution; choose 100 parts of resin, melt and stir the resin under 70 ℃ heating state for 50min to obtain resin liquid;

[0026] (2) Coating the resin liquid on the release paper with a film coater to obtain a resin composite release paper.

[0027] 2. Preparation of conductive prepreg

[0028] (1) Use a hot-pressing roller to clamp the carbon fibers in the clockwise direction between two layers of resin composite release papers in step 2, and carry out multi-pass hot rolling and yarn-spreading compounding;

[0029] (2) Peel off the upper single-sided release paper;

[0030] (3) Composite PE film, and roll up to complete ordinary carbon fiber prepreg.

Embodiment 2

[0031] Example 2. Preparation of modified carbon fiber pre-fabricated fabric

[0032] The preparation method of the graphene-modified carbon fiber prefabricated cloth of the present invention comprises the following steps:

[0033] 1. Preparation of modified carbon fiber

[0034] (1) select 1 part of graphene conductive paste of 5% concentration, and fully mix 30 parts of acetone liquid with ultrasonic mixer to obtain graphene conductive paste;

[0035] (2) Instantaneous high-temperature carbonization of carbon fiber at a temperature of 550 °C with a high-temperature electric heating tube;

[0036] (3) Continuous immersion through the graphene conductive slurry tank;

[0037] (4) Continuously soaking through the hydrogen peroxide water tank to clean and oxidize the carbon fibers;

[0038] (5) continuous drying treatment through a high-temperature electric heating tube at 200° C. to obtain graphene-modified carbon fibers.

[0039] 2. Preparation of modified resin prepreg

...

Embodiment 3

[0048] Embodiment 3; Preparation of graphene modified prepreg

[0049] The preparation method of the graphene-modified carbon fiber prefabricated cloth of the present invention comprises the following steps:

[0050] 1. Preparation of modified carbon fiber

[0051] (1) select 3 parts of graphene conductive paste of 5% concentration, and fully mix 30 parts of acetone liquid with ultrasonic mixer to obtain graphene conductive paste;

[0052] (2) Instantaneous high-temperature carbonization of carbon fiber at a temperature of 550 °C with a high-temperature electric heating tube;

[0053] (3) Continuous immersion through the graphene conductive slurry tank;

[0054] (4) Continuously soaking through the hydrogen peroxide water tank to clean and oxidize the carbon fibers;

[0055] (5) continuous drying treatment through a high-temperature electric heating tube at 200° C. to obtain graphene-modified carbon fibers.

[0056] 2. Preparation of modified resin prepreg;

[0057] (1) p...

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Abstract

The invention discloses a graphene-modified carbon fiber prepreg and a preparation method thereof. The preparation raw materials of the graphene-modified carbon fiber prepreg include carbon fiber, resin, graphene, oxidant, diluent, release paper, PE film, carbon fiber is prepared into graphene modified conductive carbon fiber prepreg through carbonization, graphene impregnation, cleaning and drying, hot rolling and yarn spreading composite resin release paper, film coating, winding, etc. The present invention makes the surface of carbon fiber introduce Oxygen-containing groups such as carbonyl and carboxyl groups can change the surface inertness, change the adsorption capacity and composite ability of carbon fibers to active substances, and at the same time improve the strength, toughness, conductivity, etc. of carbon fiber materials, which can be used as conductive heating prepregs. It has unique properties such as ultra-thinness, toughness, water resistance, and attenuation resistance. It can also improve strength, toughness and other properties in special applications of carbon fiber composite materials such as military industry, aerospace, and new energy. It has a very wide range of properties. Modified materials of application value.

Description

technical field [0001] The invention belongs to the technical fields of carbon fiber manufacturing and carbon fiber application, and in particular relates to a graphene-modified carbon fiber pre-fabrication cloth and a preparation method thereof. Background technique [0002] Graphene is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice composed of carbon atoms with sp2 hybrid orbitals. It is the thinnest and smallest nanoscale material known. It has extraordinary strength, electrical conductivity and thermal conductivity at room temperature. It has important application prospects in materials science, energy, biomedicine, and drug delivery, and is considered to be a revolutionary material in the future. [0003] Carbon fiber is "soft on the outside and rigid on the inside", which is lighter than metal aluminum, but stronger than steel, and has the characteristics of corrosion resistance and high modulus. It is an important material in national defense...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M11/74D06M101/40
CPCD06M11/74D06M2101/40D06M2200/12
Inventor 金银金俊一
Owner QINGDAO GRAPHENE CARBON NEW MATERIAL TECH CO LTD
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