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Thermo-oxidative aging-resistant low-precipitation MCA flame-retardant PA66 composite material and application thereof

A technology of PA66 and composite materials, which is applied in the field of heat-resistant oxygen aging and low-precipitation MCA flame-retardant PA66 composite materials. Effect of Flame Retardant Stability

Active Publication Date: 2020-01-17
合诚技术股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the effect of temperature and humidity, the added small molecule carboxylic acid has a large tendency to precipitate and is easy to precipitate during the placement process, causing appearance defects of the product or affecting subsequent processing (such as silk screen printing)

Method used

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  • Thermo-oxidative aging-resistant low-precipitation MCA flame-retardant PA66 composite material and application thereof
  • Thermo-oxidative aging-resistant low-precipitation MCA flame-retardant PA66 composite material and application thereof
  • Thermo-oxidative aging-resistant low-precipitation MCA flame-retardant PA66 composite material and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0041] Example 1 Preparation of heat-resistant oxygen aging low-precipitation MCA flame-retardant PA66 composite material

[0042] Weigh the raw materials of Groups 1 to 6 according to Table 1 below, and extrude and granulate them through a twin-screw extruder. Among them, the premixed PA66 resin, MCA flame retardant, antioxidant, flame retardant stabilizer and boric acid The zinc mixture is added from the main feeding port of the twin-screw extruder, and the hollow glass microspheres are added from the side feeding port of the extruder. Adjust the processing technology so that the hollow glass microspheres are evenly dispersed and less broken during processing; the mixture is melted, blended and extruded by a twin-screw extruder, then cooled, air-dried, and pelletized to obtain heat-resistant, oxygen-aging and low-precipitation MCA flame-retardant PA66 composite material.

[0043] Table 1: Raw material components and dosage (unit: kg) used to prepare the MCA flame-retardant ...

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Abstract

The invention discloses a thermo-oxidative aging-resistant low-precipitation MCA flame-retardant PA66 composite material and application of the thermo-oxidative aging-resistant low-precipitation MCA flame-retardant PA66 composite material. The composite material comprises the following components in parts by weight: 85-91 parts of PA66 resin, 8-12 parts of an MCA flame retardant, 0.6-1.0 part of hollow glass beads, 0.3-0.6 part of an antioxidant, 0.2-0.3 part of a flame retardant stabilizer and 0.3-0.6 part of zinc borate. According to the invention, PA66 is used as a resin matrix, a common MCA flame retardant in the market is adopted, and the hollow glass beads, anhydrous zinc borate and stearate are combined as flame retardant stabilizers, so that the composite material reaches the UL94V0 grade and is less separated out, and the printing effect of a final product is effectively improved; by adding an efficient compound antioxidant system, the performance retention rate of the material in a high-temperature environment is improved, and the material is widely applied to the fields of electronic appliances and connectors, especially the field of wiring terminals.

Description

technical field [0001] The invention belongs to the technical field of polyamide 66 resin modification, and in particular relates to a heat-resistant oxygen-aging low-precipitation MCA flame-retardant PA66 composite material and an application thereof. Background technique [0002] Polyamide 66 (PA66) resin has excellent mechanical and physical properties, and is widely used in machinery manufacturing, electric tools, electronic appliances, transportation and other fields. However, because PA66 resin can only reach the V-2 flame retardant grade, and the molten droplets during the combustion process are likely to cause secondary ignition and cause a larger fire, which greatly limits its application fields, especially in industrial / automotive electronic appliances In the field, these products are in direct or indirect contact with the electricity environment, and leakage, short circuit, arc, etc. in the circuit are likely to cause fire. Therefore, in practical applications, m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08K13/04C08K7/28C08K5/3492C08K3/38C08K5/098
CPCC08K13/04C08K7/28C08K5/34928C08K3/38C08K5/098C08K2003/387C08K2201/011C08L77/06
Inventor 张宇诸泉蒋文真
Owner 合诚技术股份有限公司
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