Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Thermoplastic resin composition, preparation method and one application thereof

A thermoplastic resin and composition technology, which is applied in the field of thermoplastic resin composition and its preparation, can solve the problems of affecting the mechanical properties and heat resistance of styrene resins, reducing the gloss of ABS and ASA systems, increasing the interface, etc., to achieve good The effect of a matte finish

Inactive Publication Date: 2019-12-31
WUHAN JINFA TECH CO LTD +1
View PDF3 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Judging from the existing modified matting technology, inorganic matting agents are relatively seldom used in styrene-based polymers such as ABS and ASA. To achieve the desired matting degree, a large amount of inorganic filler must be added. When the filler is excessive , the interface between the filler and the resin increases, and the interface bonding strength is low, which will easily cause the deterioration of the overall mechanical properties
Non-reactive matting agents often have poor compatibility with ABS and ASA, and form a two-phase incompatible structure after adding them. At the same time, most organic matting agents are also toughening agents. When the amount added is high, it will greatly affect the mechanical properties of styrene resins. and heat resistance
For reactive matting agents, to achieve the ideal matting effect, more reactive matting agents need to be added, which may cause two-phase phase separation or a significant decrease in mechanical properties
In summary, the current four modified matting technologies have certain limitations, and more advanced technologies are still needed to further reduce the gloss of ABS and ASA systems

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Thermoplastic resin composition, preparation method and one application thereof
  • Thermoplastic resin composition, preparation method and one application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0047] The present invention is described in more detail through the following examples, but the present invention is not limited by the following examples.

[0048] The sources of raw materials used in the present invention are as follows:

[0049] Polypropylene: PP 7033N, ExxonMobil Chemical;

[0050] Styrene impact toughening agent:

[0051] ABS-1: The butadiene content is 25%, the average particle size is 3.0 microns, produced by Gaoqiao Petrochemical;

[0052] ABS-2: Butadiene content is 25%, average particle size is 5.0 microns;

[0053] ASA: Acrylate content is 60%, average particle size is 0.6 microns, produced by UMG Corporation;

[0054] MBS: Butadiene content is 60%, average particle size is 0.3 microns, produced by LG Chem;

[0055] Copolymer of vinyl aromatic monomer and ethylenically unsaturated nitrile monomer:

[0056] SAN-1: Acrylonitrile content is 25 wt%, molecular weight is 250,000 Daltons, produced by Kumho Petrochemical;

[0057] SAN -2: Acrylonitrile content is 18 wt%,...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention discloses a thermoplastic resin composition, which comprises, by weight, 30-98 parts of a styrene-based anti-impact toughening agent, 10-80 parts of a copolymer of a vinyl aromatic monomer and an alkene-based unsaturated nitrile monomer, and 0.5-20 parts of boehmite, wherein the average particle size of the boehmite is 0.01-10 [mu]m, the specific surface area of the boehmite is 3.0-150 m<2> / g, and the Ca element content of the boehmite does not exceed 1000 ppm. By controlling the Ca element content of boehmite, a large number of micropores are formed in the surface of boehmite, so that boehmite has good compatibility with rubber particles in a matrix, and by controlling the particle size and the specific surface area of boehmite, boehmite easily achieves light extinction so as to bring light extinction effect.

Description

Technical field [0001] The invention relates to the technical field of polymer materials, in particular to a thermoplastic resin composition, a preparation method thereof, and an application. Background technique [0002] Styrene-acrylonitrile copolymers such as ABS and ASA are the two most important resins in the styrene series. Compared with other resins, ABS and ASA, which are of high quality and low price, and have various excellent characteristics, have become one of the most used types of thermoplastic resins. They are widely used in the automotive industry, household appliances, automation instruments, high-speed rail ships, sports equipment, and outdoor Equipment and construction industries. ABS uses butadiene as the rubber phase, which has better impact performance; while ASA uses acrylic rubber instead of butadiene rubber, which has excellent weather resistance. Both have excellent gloss properties and can meet the needs of high-end home appliances. The gloss can be u...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L51/04C08L25/12C08K7/24C08K3/22
CPCC08K2003/2227C08K2201/003C08L55/02C08L2205/03C08L51/04C08L25/12C08K7/24C08K3/22
Inventor 王琪林荣涛季得运卢朝亮李文龙程文超李欣达孙付宇余朦山缪启龙郭涛杨波罗忠富
Owner WUHAN JINFA TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products