Polyacid Ag(I) coordination polymer as well as preparation method and application thereof

Abstract

The invention relates to a polyacid Ag(I) coordination polymer as well as a preparation method and an application thereof. The chemical formula of the polyacid Ag(I) coordination polymer is [Ag3(btp)2(PMo12O40).1.5H2O]n, btp is 2,6-bis(1,2,4-triazole-1-yl)pyridine, and the crystal of the polyacid Ag(I) coordination polymer belongs to the monoclinic system and P21 / n space group. The preparation method comprises the steps as follows: AgNO3, H3PMo12O40, btp and distilled water are mixed to be placed in a reactor and stirred to be uniformly mixed, the pH of the solution is adjusted to 1.7-2.6 withan HCl solution during stirring, the solution is heated at 140-160 DEG C for 4-6 days and then cooled to the room temperature, and washing, filtration and drying are performed to obtain the polyacidAg(I) coordination polymer. The polyacid Ag(I) coordination polymer can be used as an electrolytic material.

Description

technical field [0001] The invention belongs to the technical field of electrochemical catalysis, and in particular relates to a polyacid-based Ag(I) coordination polymer and a preparation method and application thereof. Background technique [0002] Coordination polymers have achieved remarkable results in the fields of gas storage and separation, heterogeneous catalysis, magnetism, and sensing. However, the functional design and development of such materials is far from enough, such as in Electrocatalysis technology field. Hydrogen peroxide aqueous solution, commonly known as hydrogen peroxide, is a widely used traditional inorganic chemical product. It is often used for disinfection of medical wounds and food disinfection. However, due to its slow decomposition, the vapor or mist inhaled from this product is strongly irritating to the respiratory tract and eyes. Direct contact with liquids can cause irreversible damage and even blindness. There are many methods for cata...

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Problems solved by technology

[0003] Among the polyacid-based Ag(I) coordination polymers reported so far, no reports related to 2,6-bis(1,2,4-triazol-1-yl)pyridine ligands have been found, and the H 2 o 2 The electrocatalytic activity of reduction has been less studied (Zhang Z.F., Ma H.Y., PangH.J., Zhang C.J., Yu T.T., Li S.B., Zhao C.Y., Inorg.Chem.Commun., 2016, 72, 91–95; C.J.Wang , T.T.Wang, Q.Lan, S.Yao, H.L.Wu, Y.Y.Zhou, Z.M.Zhang, E.B.Wang, RSC Adv., 2016, 6, 15513–15517; L.P.Cui, J.H.Lv, K.Yu, X.Y.Ma, W.T. Dai, B.B. Zhou, Inorg. Chem. Commun., 2018, 98, 87–91; X.L. Wang, R. Zhang, X. Wang, H.Y. Lin, G.C. Liu, H.X. Zhang, Polyhedron, 2017, 135, 180–188; X. Li, Y.L.Wang, K.F.Zhou, Y.L.Wang, T.Han, J.Q.Sha, J.Coord.Chem., 2018, 71, 1–21.)

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