Special treatment microbial agent for sewage containing alcohol organic substance and treatment method
A technology of organic substances and bacterial agents, which is applied in the field of bioengineering, can solve the problems of inconvenient preparation and use of oxidants, low process operation safety, and increased cost of hazardous waste treatment, so as to save costs, improve removal efficiency, and suppress impact.
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Embodiment 1
[0063] A company produces a coal-based hydrogen wastewater with a COD value of about 16,000mg / L. After analysis, the organic substances mainly include alcohols such as methanol and ethanol.
[0064] Treat this waste water with biochemical method, add facultative anaerobic bacteria Pichia pastoris to the activated sludge system of anaerobic tank, the addition amount is W / V 1‰ (W is the quality of bacterial agent, V is the quality of anaerobic tank Effective pool capacity), outdoor temperature 25°C, stirring 50rpm, after sludge and bacteria exposure for 1 day, let it settle for 1 hour, discard the supernatant, and add nutrient salt-added coal hydrogen wastewater to the activity of the anaerobic pool In the sludge system, make the COD in the anaerobic tank system 4000mg / L, adjust the pH of the system to 7.5 with sodium hydroxide, stir at 50rpm, the dissolved oxygen is <0.5mg / L, measure the COD every day, and check the pH. The concentration of COD in the medium dropped to 2000mg / L...
Embodiment 2
[0071] COD, NH 3 -N, volatile phenol, SS, etc., belong to high-concentration organic sewage.
[0072] Add facultative anaerobic bacteria Lactobacillus subspecies plantarum and Pichia pastoris to the activated sludge system of anaerobic tank, the addition amount is W / V2‰, wherein, the mass ratio of Pichia pastoris and Lactobacillus plantarum subspecies plantarum is 1:1, outdoor temperature 30°C, stirring 50rpm, after the sludge and bacterial agent are stuffy exposed for 1d, let it settle for 1h, discard the supernatant,
[0073] Add the coke oven gas waste water with nutrient salts into the activated sludge system of the above-mentioned anaerobic tank, so that the COD in the anaerobic tank system is 2500 mg / L, adjust the pH of the system to 8.0 with sodium hydroxide, stir at 50 rpm, dissolve oxygen <0.5mg / L, measure its COD every day, check pH, 2d when the COD concentration in the system drops to 1500mg / L, let the sludge settle when it is still for 2.5h, discard the supernatan...
Embodiment 3
[0081] In the industrial production of methanol, the distillation raffinate discharged from the bottom of the rectification tower mainly contains methanol, ethanol, higher alcohols and aldehydes and a small amount of long-chain compounds. Its COD content is relatively high, and it belongs to high-concentration organic wastewater. This embodiment is referred to as methanol wastewater.
[0082] Add facultative anaerobic bacteria Lactobacillus subsp. plantarum and Pichia pastoris to the activated sludge system of the anaerobic tank, and the addition amount is W / V5‰, wherein, the mass ratio of Pichia pastoris and Lactobacillus plantarum subspecies plantarum is 1:0.8, the outdoor temperature is 37°C, stirring 50rpm, after the sludge and bacterial agent are stuffy exposed for 1d, let it settle for 1h, discard the supernatant,
[0083]Add methanol wastewater with nutrient salts into the activated sludge system of the above-mentioned anaerobic tank, so that the COD in the anaerobic tan...
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