Conductive anticorrosive coating
A conductive anti-corrosion and coating technology, used in anti-corrosion coatings, conductive coatings, epoxy resin coatings, etc., can solve the problems of high cost, difficult processing, unstable conductivity, etc., and achieve good alkali resistance and improve salt spray resistance. Effect
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Embodiment 1
[0028] The preparation method of modified graphene comprises the following steps:
[0029] 1) Calculated according to parts by weight, weigh 30 parts of graphene, 8 parts of citric acid, 4 parts of chitosan, 8 parts of conductive carbon black, 1 part of tin chloride and 3 parts of phosphorus oxychloride;
[0030] 2) dissolving citric acid in water to prepare an aqueous solution of citric acid, then adding graphene, and then adding tin chloride for stirring and dispersing to obtain a dispersion;
[0031] 3) Add chitosan and conductive carbon black to the dispersion in step 2), stir and disperse, heat up to 40° C., add phosphorus oxychloride and keep it warm for 60 minutes, then filter and dry the filtrate.
Embodiment 2
[0033] The preparation method of modified graphene comprises the following steps:
[0034] 1) Calculated according to parts by weight, weigh 40 parts of graphene, 16 parts of citric acid, 2 parts of chitosan, 4 parts of conductive carbon black, 3 parts of tin chloride and 6 parts of phosphorus oxychloride;
[0035] 2) dissolving citric acid in water to prepare an aqueous solution of citric acid, then adding graphene, and then adding tin chloride for stirring and dispersing to obtain a dispersion;
[0036] 3) Add chitosan and conductive carbon black to the dispersion in step 2), stir and disperse, then raise the temperature to 60° C., add phosphorus oxychloride and keep it warm for 30 minutes, then filter and dry the filtrate.
Embodiment 3
[0038] A conductive anticorrosion coating, calculated in parts by weight, comprising the following components:
[0039] 70 parts of hydroxyl acrylic resin, 20 parts of epoxy resin, 2 parts of modified graphene of embodiment 1, 6 parts of carbon nanotubes, 1.6 parts of octadecyl dimethyl hydroxyethyl ammonium nitrate, 3 parts of 2-methylimidazole 0.3 parts of preservatives, 0.6 parts of polyether defoamers and 120 parts of acetone. The preservative is a mixture of isothiazolinone and aluminum tripolyphosphate, and the mass ratio of isothiazolinone to aluminum tripolyphosphate is 5:1.
[0040] The preparation method of conductive anticorrosion coating:
[0041] 1) First mix part of the hydroxyl acrylic resin, carbon nanotubes and all the modified graphene evenly, and then use a ball mill to perform ball milling to obtain a dispersion;
[0042] 2) Mix the remaining hydroxyl acrylic resin, epoxy resin, octadecyl dimethyl hydroxyethyl ammonium nitrate and part of acetone, and the...
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