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Resin microsphere plugging agent and preparation method therefor

A technology of resin microspheres and plugging agents, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of water-flooding wave volume and recovery rate reduction, formation pores and fractures becoming larger, and crude oil production impact. , to achieve the effect of geological improvement, oil production increase and good transparency

Active Publication Date: 2018-12-04
HENAN ZHENGJIA ENERGY ENVIRONMENTAL PROTECTION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the initial stage of the development of oil recovery technology in my country, water injection was mostly used for development. As the production time of oil wells increased, most of the oil wells became high water-cut oil wells, and the oil wells were affected by long-term water injection, which changed the physical properties of underground oil reservoirs and formation pores. , Under the water injection pressure, the formation pores and fractures between the production well and the water injection well become larger, and the permeability increases, so the water flooding swept volume and recovery factor are greatly reduced, and the crude oil production is significantly affected
Traditional polymer, gel and other types of plugging agents have defects such as high injection pressure, low plugging rate, fast degradation speed, and excessive viscosity when implementing profile control and water plugging operations for low-permeability formations

Method used

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  • Resin microsphere plugging agent and preparation method therefor
  • Resin microsphere plugging agent and preparation method therefor
  • Resin microsphere plugging agent and preparation method therefor

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preparation example Construction

[0060] The preparation method of above-mentioned resin microsphere plugging agent, comprises the following steps:

[0061] A. Add organic dispersant and inorganic dispersant to deionized water, raise the temperature, control the stirring temperature to 60-70°C, and stir for 1 hour;

[0062] B. adding the oil-soluble initiator to the mixture of vinyl monomers, ester monomers and functional monomers to dissolve the oil-soluble initiator;

[0063] C. Add the mixture obtained in step B to the mixture obtained in step A, control the stirring speed to 120-300r / min, and carry out the polymerization reaction at 70-95°C for 6 hours to obtain dispersions with different particle sizes;

[0064] D. Stir the dispersions of different particle sizes obtained in step C to room temperature to obtain the resin microsphere plugging agent.

Embodiment 1

[0066]The preparation method of the resin microsphere blocking agent of this embodiment is: add 1 part of polyvinyl alcohol 1788 and 0.5 part of sodium hexametaphosphate into 80 parts of deionized water, stir at a speed of 120 r / min, heat up, and control the temperature to 60 ° C , and stirred for 1 h to obtain solution A. Add 0.6 parts of initiator azobisisobutyronitrile into a mixture containing 40 parts of styrene, 5 parts of glycidyl methacrylate and 5 parts of methyl methacrylate and 5 parts of diallyl phthalate to make the initiator The agent dissolves. The mixture of various monomers was added to the solution A, the stirring speed was controlled at 300r / min, and the temperature was 70°C to carry out the polymerization reaction for 6h. The obtained emulsion was cooled down to room temperature by stirring to obtain a dispersion of resin microspheres with a particle size of 200 μm.

Embodiment 2

[0068] The preparation method of the resin microsphere plugging agent of this embodiment is: add 0.5 parts of polyethylene glycol 400 and 0.3 parts of sodium pyrophosphate to 90 parts of deionized water, stir at a speed of 120 r / min, heat up, and control the temperature to 60 ° C , and stirred for 1 h to obtain solution A. 0.7 parts of initiator azobisisobutyronitrile was added to a mixture containing 30 parts of styrene, 6 parts of butyl acrylate and 10 parts of diallyl phthalate to dissolve the initiator. The mixture of various monomers was added to the solution A, the stirring speed was controlled at 280r / min, and the temperature was 80°C to carry out the polymerization reaction for 6h. The obtained emulsion was cooled down to room temperature by stirring to obtain a microsphere dispersion with a particle size of 50 nm.

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Abstract

The invention relates to a resin microsphere plugging agent and a preparation method therefor. The resin microsphere plugging agent is prepared from the following ingredients in parts by mass: 30-60 parts of alkene monomer, 5-40 parts of ester monomer, 5-10 parts of functional monomer, 0.1-1 part of organic dispersant, 0.3-0.5 part of inorganic dispersant, 0.6-1 part of oil-soluble initiator and 80-120 parts of distilled water. The resin microsphere plugging agent is obtained through adding the organic dispersant and the inorganic dispersant into deionized water, carrying out heating, stirringand mixing, adding the oil-soluble initiator into a mixture of the alkene monomer, the ester monomer and the functional monomer, dissolving the oil-soluble initiator, mixing all the ingredients, carrying out a polymerization reaction so as to obtain a dispersion solution of different particle sizes, and carrying out stirring to cool the dispersion solution to room temperature. According to the resin microsphere plugging agent and the preparation method therefor, the technological operations are simple, and prepared resin microspheres have the advantages of uniform particle size, easy-controlled reaction temperature, high yield, good stability, good flexibility, good transparency, good heat resistance and difficulty in degradation.

Description

technical field [0001] The invention belongs to the field of oil field chemistry, and in particular relates to a resin microsphere plugging agent and a preparation method thereof. Background technique [0002] In the initial stage of the development of oil recovery technology in my country, water injection was mostly used for development. As the production time of oil wells increased, most of the oil wells became high water-cut oil wells, and the oil wells were affected by long-term water injection, which changed the physical properties of underground oil reservoirs and formation pores. , Under the water injection pressure, the formation pores and fractures between the production well and the water injection well become larger, and the permeability increases, so that the water flooding swept volume and recovery factor are greatly reduced, and the crude oil production is significantly affected. Traditional polymer, gel and other types of plugging agents have defects such as hi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/512C08F212/08C08F220/38C08F220/14C08F218/18C08F220/18C08F220/20
CPCC09K8/5083C09K8/5086C09K8/512C08F212/08C08F220/1804C08F218/18C08F220/20C08F220/38C08F220/14
Inventor 赖小娟刘佳慧王磊张引引石浪浪
Owner HENAN ZHENGJIA ENERGY ENVIRONMENTAL PROTECTION CO LTD
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