Silicic acid fertilizer and preparation process thereof
A technology of silicic acid and chemical fertilizers, applied in dicalcium phosphate fertilizers, phosphate fertilizers, silicon oxide, etc., can solve problems such as inability to mix phosphate fertilizers, less than effective utilization, and calcium silicate agglomeration and hardening, etc. The effect of low production cost and moderate solubility
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Embodiment 1
[0028] Example 1 Preparation of silicic acid fertilizer with sodium silicate
[0029] a, take solid sodium silicate (Na 2 Si0 39H 2 0) as the raw material to obtain product A;
[0030] b. Make product A into a sodium silicate solution with a concentration of 25%, add hydrochloric acid for neutralization reaction, so that the pH value of the sodium silicate solution does not exceed 6.5, and the obtained silicic acid colloid solution is used as product B: the chemical reaction formula is : Na 2 Si0 3 +2HC→2NaCl+H 2 Si0 3
[0031] c. Use the heating gelation precipitation method to transfer product B into a sedimentation tank, heat to 80-100°C, and keep the temperature for 3 hours. After the silicic acid in product B is completely precipitated, the obtained product is used as product C;
[0032] d. Send product C to a vacuum filter for filtration, wash the sediment with mixed water to remove soluble salt impurities, and then continue to wash the sediment with 8% dilute am...
Embodiment 2
[0034] Embodiment 2 uses sodium silicate to make various silicic acid fertilizers
[0035] a. Take solid sodium silicate as raw material to obtain product A:
[0036] b. Make product A into a sodium silicate solution with a concentration of 25%, add sulfuric acid to carry out neutralization reaction, so that the pH value of the sodium silicate solution does not exceed 6.5, and the obtained silicic acid colloid solution is used as product B; the chemical reaction formula is : CaSi03+C02+H20→CaC03↓+H2Si03:
[0037] c. Using the animal gel coagulation precipitation method, add sulfuric acid to product B to make the acidity of the silicic acid colloidal solution reach 0-1 mol / liter, then add the animal gelatin solution with a concentration of 2% and a volume of the silicic acid colloidal solution of 10%, and then Heat to 60-800°C and keep the temperature for 1 hour, until the silicic acid in product B is completely precipitated, and the obtained product is product C: animal glue ...
Embodiment 4
[0046] Example 4 Preparation of various silicic acid fertilizers with blocks containing calcium silicate (carbon dioxide neutralization method)
[0047] a, take ironmaking slag (also can be yellow phosphorus slag or ferromanganese slag, also can be the block that burns with limestone and clay) as raw material, get A product;
[0048] b. Crush product A and put it into a reaction container, add water 10 times the weight of product A, and pass in carbon dioxide gas while stirring until the pH value of the solution is ≤ 6.5, stop the ventilation, filter, and the obtained filter residue is silicon-rich Calcium carbonate precipitation of acid, as B slag, the obtained filtrate is a colloidal solution of silicic acid, called B liquid;
[0049] c. Using the gelation precipitation method, heat liquid B to 80-100°C and keep it warm for 3 hours. After the silicic acid in liquid B is completely precipitated, add B slag and stir evenly to make the silicic acid precipitate adsorb on the cal...
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