Comb type structure amphiprotic ionic polymer filtrate reducer and preparation method thereof
A zwitterion and fluid loss additive technology, applied in drilling compositions, chemical instruments and methods, etc., can solve the problem that fluid loss additives cannot have both fluid loss control performance and temperature and salt resistance performance, and achieve Easy for large-scale industrial production, guaranteed fluid loss performance, and good production stability
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Embodiment 1
[0025] The comb-shaped structure zwitterionic polymer fluid loss reducer of this embodiment is formed by copolymerization of the following monomers in parts by weight: 40 parts of 2-acrylamide-2-methylpropanesulfonic acid, polyethylene glycol monomethyl ether acrylic acid 20 parts of ester, 30 parts of N,N-dimethylacrylamide, 10 parts of dimethyl diallyl ammonium chloride; the preparation process is as follows:
[0026] 1) Add 40 parts of 2-acrylamide-2-methylpropanesulfonic acid and 300 parts of distilled water into the reactor, stir until fully dissolved; then add 20 parts of polyethylene glycol monomethyl ether acrylate, stir well, add Sodium hydroxide solution with a mass concentration of 20%, adjust the pH of the system to 6; then add 30 parts of N,N-dimethylacrylamide and 10 parts of dimethyl diallyl ammonium chloride, and stir evenly at 40°C , to obtain a monomer solution in which the sum of the mass concentrations of each monomer is 25%;
[0027] 2) Nitrogen protectio...
Embodiment 2
[0030] The comb-shaped structure zwitterionic polymer fluid loss reducer of this embodiment is formed by copolymerization of the following monomers in parts by weight: 30 parts of 2-acrylamide-2-methylpropanesulfonic acid, polyethylene glycol monomethyl ether acrylic acid 10 parts of ester, 50 parts of N,N-dimethylacrylamide, 10 parts of dimethyl diallyl ammonium chloride; the preparation process is as follows:
[0031] 1) Add 30 parts of 2-acrylamide-2-methylpropanesulfonic acid and 400 parts of distilled water into the reactor, stir until fully dissolved; then add 10 parts of polyethylene glycol monomethyl ether acrylate, stir well, add Sodium hydroxide solution with a mass concentration of 20%, adjust the pH of the system to 7; then add 50 parts of N,N-dimethylacrylamide and 10 parts of dimethyl diallyl ammonium chloride, and stir evenly at 35°C , to obtain a monomer solution in which the sum of the mass concentrations of each monomer is 20%;
[0032] 2) Nitrogen protectio...
Embodiment 3
[0035] The comb-shaped structure zwitterionic polymer fluid loss reducer of this embodiment is formed by copolymerization of the following monomers in parts by weight: 30 parts of 2-acrylamide-2-methylpropanesulfonic acid, polyethylene glycol monomethyl ether acrylic acid 5 parts of ester, 60 parts of N,N-dimethylacrylamide, 5 parts of dimethyl diallyl ammonium chloride; the preparation process is as follows:
[0036] 1) Add 30 parts of 2-acrylamide-2-methylpropanesulfonic acid and 300 parts of distilled water into the reactor, stir until fully dissolved; then add 5 parts of polyethylene glycol monomethyl ether acrylate, stir well, add Sodium hydroxide solution with a mass concentration of 20%, adjust the pH of the system to 8; then add 60 parts of N,N-dimethylacrylamide and 5 parts of dimethyl diallyl ammonium chloride, and stir evenly at 50°C , to obtain a monomer solution in which the sum of the mass concentrations of each monomer is 25%;
[0037] 2) Nitrogen protection fo...
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