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Waterborne polyurethane dispersion body and preparation method thereof

A water-based polyurethane and dispersion technology, applied in polyurea/polyurethane coatings, polyurea/polyurethane adhesives, non-polymer adhesive additives, etc., can solve problems such as poor bonding ability of low surface energy materials, and achieve Wide substrate applicability, low cost effect

Inactive Publication Date: 2018-09-04
肇庆市华莱特复合新型材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is that existing water-based polyurethane dispersions have poor bonding ability for low surface energy materials, need to use curing agent in combination to enhance thermal stability during use, and need to be treated in order to improve the bonding effect before use. Problems with surface pretreatment of target materials

Method used

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  • Waterborne polyurethane dispersion body and preparation method thereof

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specific Embodiment 1

[0033] Polyester polyol, 100 parts; Diisocyanate, 45 parts; Dimethylolpropionic acid, 2 parts; 1,4-Butanediol, 0.5 parts; Trimethylolpropane, 2 parts; Carbodiimide hydrochloride, 1 part; dopamine hydrochloride, 2 parts; triethylamine, 1.2 parts; deionized water, 144.3 parts.

specific Embodiment 2

[0034] Polyester polyol, 100 parts; Diisocyanate, 20 parts; Dimethylolpropionic acid, 6 parts; 1,4-Butanediol, 3 parts; Trimethylolpropane, 4 parts; Methylethylketoxime, 10 parts; Carbodiimide hydrochloride, 2 parts; dopamine hydrochloride, 4 parts; triethylamine, 1.8 parts; deionized water, 149.2 parts.

specific Embodiment 3

[0035] Polyester polyol, 100 parts; Diisocyanate, 32.5 parts; Dimethylolpropionic acid, 4 parts; 1,4-Butanediol, 1.75 parts; Trimethylolpropane, 3 parts; Carbodiimide hydrochloride, 1.5 parts; dopamine hydrochloride, 3 parts; triethylamine, 1.5 parts; deionized water, 145.25 parts.

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Abstract

The invention discloses a waterborne polyurethane dispersion body and a preparation method thereof, wherein the waterborne polyurethane dispersion body is prepared from the following ingredients and raw materials in proportion: 100 parts of polyester polyol, 20 to 45 parts of diisocyanate, 2 to 6 parts of dimethylolpropionic acid, 0.5 to 3 parts of 1,4-butanediol, 2 to 4 parts of trimethylolpropane, 2 to 10 parts of methyl ethyl ketoxime, 1 to 2 parts of carbodiimide hydrochloride, 2 to 4 parts of 3-hydroxytyramine hydrochloride, 1.2 to 1.8 parts of triethylamine and 110 to 160 parts of deionized water. An adhesion unit containing catechol groups and polyurethane containing sealed isocyanate functional groups are combined; an adhesion material with high heat resistance, low cost and wide substrate applicability is obtained through preparation.

Description

technical field [0001] The invention relates to the technical field of coatings and shoe adhesives, in particular to an aqueous polyurethane dispersion and a preparation method thereof. Background technique [0002] At present, the common water-based polyurethane dispersions on the market need to be pre-treated with a treatment agent on the surface of the coated target material to achieve a good adhesion effect, and it is always necessary to add a curing agent to the water-based polyurethane dispersion before use during use. way to improve heat resistance. [0003] For example, the Chinese invention patent CN102617824A discloses a water-based polyurethane curing agent and a water-based polyurethane dispersion used in conjunction with the water-based polyurethane curing agent. The raw material formula of the water-based polyurethane consists of 70-73% isophorone Diisocyanate, 8-9% polyethylene glycol monobutyl ether, 0.1-0.5% 2,4,6-tris(dimethylaminomethyl)phenol and 18-21% ...

Claims

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Application Information

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IPC IPC(8): C08G18/66C08G18/42C08G18/32C08G18/34C08K5/18C09J175/06C09J11/06C09D175/06C09D7/63
CPCC08G18/3206C08G18/348C08G18/42C09D175/06C09J11/06C09J175/06C09D7/63C08K5/18
Inventor 陈应华曾广福
Owner 肇庆市华莱特复合新型材料有限公司
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