Preparation method of lead-acid storage battery gel electrolyte

A colloidal electrolyte, lead-acid battery technology, applied in lead-acid batteries and other directions, can solve the problems of short gelation time, poor gel stability, poor gel strength, etc., to avoid hydration stratification, and to achieve good thixotropy , the effect of prolonging life

Active Publication Date: 2018-07-06
TIANNENG GRP HENAN ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to solve the problems of short gelation time, poor gel strength, poor thixotropy, poor gel stability, serious hydration and stratification of colloidal electrolyte, large resistance and short life in the prior art. And proposed a kind of preparation method of colloidal electrolyte of lead-acid battery

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  • Preparation method of lead-acid storage battery gel electrolyte
  • Preparation method of lead-acid storage battery gel electrolyte
  • Preparation method of lead-acid storage battery gel electrolyte

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Embodiment 1

[0018] A kind of preparation method of lead-acid storage battery colloidal electrolyte that the present invention proposes comprises the following steps:

[0019] S1. Prepare the raw materials for the preparation of lead-acid battery colloidal electrolyte, including 8% nano silicon dioxide, 0.06% methyltrimethoxysilane, 3% dimethicone, 0.9% sulfate, nano Boron oxide 0.5%, 1-allyl-3-methylimidazolium chloride 0.7%, grease 0.15%, fatty alcohol polyoxyethylene ether sodium sulfate 0.5%, stabilizer 0.3%, sulfuric acid 44%, the rest is distilled water , where the density of sulfuric acid solution is 1.56g / cm 3 , sulfate is the composite agent of lead sulfate, cobalt sulfate, sodium sulfate, tin sulfate and aluminum sulfate that mass ratio is 1.8:1.2:3:0.7:2.5; Stabilizer is polyacrylamide and polyacrylamide that mass ratio is 1:30 Compositions of carboxymethylcellulose;

[0020] S2. Add nano-silica to the ultrasonic disperser, add distilled water until the mass fraction of nano-s...

Embodiment 2

[0025] A kind of preparation method of lead-acid storage battery colloidal electrolyte that the present invention proposes comprises the following steps:

[0026] S1. Raw materials for preparation of colloidal electrolyte for lead-acid battery, including 6% nano silicon dioxide, 0.04% methyltrimethoxysilane, 2% dimethyl polysiloxane, 0.7% sulfate, nano Boron oxide 0.35%, 1-allyl-3-methylimidazolium chloride 0.5%, grease 0.12%, fatty alcohol polyoxyethylene ether sodium sulfate 0.3%, stabilizer 0.2%, sulfuric acid 40%, the rest is distilled water , where the density of sulfuric acid solution is 1.52g / cm 3 , sulfate is the composite agent of lead sulfate, cobalt sulfate, sodium sulfate, tin sulfate and aluminum sulfate that mass ratio is 1.4:0.8:2.5:0.5:2; Stabilizer is polyacrylamide and polyacrylamide that mass ratio is 1:1 Compositions of carboxymethylcellulose;

[0027] S2. Add nano-silica to the ultrasonic disperser, add distilled water until the mass fraction of nano-sil...

Embodiment 3

[0032]A kind of preparation method of lead-acid storage battery colloidal electrolyte that the present invention proposes comprises the following steps:

[0033] S1. Raw materials for preparation of colloidal electrolyte for lead-acid battery, including 3% nano silicon dioxide, 0.02% methyltrimethoxysilane, 1% dimethyl polysiloxane, 0.5% sulfate, nano Boron oxide 0.2%, 1-allyl-3-methylimidazolium chloride 0.3%, grease 0.08%, fatty alcohol polyoxyethylene ether sodium sulfate 0.1%, stabilizer 0.1%, sulfuric acid 35%, the rest is distilled water , where the density of sulfuric acid solution is 1.48g / cm 3 , sulfate is the composite agent of lead sulfate, cobalt sulfate, sodium sulfate, tin sulfate and aluminum sulfate that mass ratio is 1:0.5:2:0.3:1.5; Stabilizer is polyacrylamide and polyacrylamide that mass ratio is 30:1 Compositions of carboxymethylcellulose;

[0034] S2. Add nano-silica to the ultrasonic disperser, add distilled water until the mass fraction of nano-silica...

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Abstract

The invention belongs to the technical field of lead-acid storage batteries and in particular relates to a preparation method of lead-acid storage battery gel electrolyte, aiming at solving the problems in the prior art that gel electrolyte has a serious hydration and layering phenomenon, great resistance and short service life. The preparation method comprises the following steps: after mixing nano silicon dioxide and distilled water, dispersing; then adding methyltrimethoxysilane, and raising the temperature and reacting to obtain a mixed solution A; stirring and mixing sulfate, nano boron oxide, 1-allyl-3-methylimidazole chloride, sodium alcohol ether sulphate and the residual distilled water to obtain a solution B; adding dimethicone, lubricating grease and sulfuric acid into the mixedsolution B and mixing to obtain a mixed solution C; after mixing the mixed solution A and the mixed solution C, adding a stabilizing agent and uniformly mixing to obtain the lead-acid storage batterygel electrolyte. The preparation method provided by the invention has the advantages of simplicity, moderate preparation conditions and low cost; the prepared gel electrolyte has good thixotropic behaviors, small inner resistance, no acid leakage, no smoke, slow water loss speed and long service life and is worthy of being popularized.

Description

technical field [0001] The invention relates to the technical field of lead-acid batteries, in particular to a method for preparing colloidal electrolyte of lead-acid batteries. Background technique [0002] In storage batteries, lead-acid batteries have the advantages of mature technology, cheap price, good charging and discharging performance, and safe use. As the most important stable power supply and DC power supply, they are widely used in aviation, railways, automobiles, ships, communications, and finance In various industries such as military and national defense, it has become an indispensable energy product in social production and human life. Lead-acid battery refers to a battery whose electrodes are mainly made of lead and its oxides, and the electrolyte is a sulfuric acid solution. In the discharge state of the lead-acid battery, the main component of the positive electrode is lead dioxide, and the main component of the negative electrode is lead; in the chargin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/08
CPCH01M10/08Y02E60/10
Inventor 韩峰欧阳万忠赵兴强周桂华程可红
Owner TIANNENG GRP HENAN ENERGY TECH
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