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High-density refractory ceramic fiber and preparation method thereof

A refractory ceramic fiber and density technology, which is applied in the field of refractory materials, can solve the problems of affecting product strength, reducing the density of ceramic fibers, and using more binders to achieve high strength, increase density, and reduce usage.

Active Publication Date: 2018-07-03
长兴正发热电耐火材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the amount of binder used in the raw material of the above-mentioned patented ceramic fiber is relatively large (2-6%). Even if the binder has high temperature resistance, it still partially decomposes in a high temperature environment, thereby leaving pores inside the ceramic fiber, resulting in The density of ceramic fibers is reduced, which ultimately affects the strength of the product

Method used

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  • High-density refractory ceramic fiber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A high-density refractory ceramic fiber is prepared by mixing ceramic slurry A and ceramic slurry B at a weight ratio of 1:1.

[0033] Wherein, the A ceramic slurry includes the following raw materials in parts by weight: 70 parts of fused chromium oxide, 15 parts of zirconia, 10 parts of alumina micropowder, 1 part of yttrium oxide micropowder, 1 part of lanthanum and lanthanide metal oxide micropowder, 1 part of fine metal yttrium powder, 2 parts of tetradecyltrimethylammonium bromide, 60 parts of ethanol, and 40 parts of water.

[0034] The B ceramic slurry includes the following raw materials in parts by weight: 70 parts of fused chromium oxide, 15 parts of zirconia, 10 parts of alumina micropowder, 1 part of yttrium oxide micropowder, 1 part of lanthanum and lanthanide metal oxide micropowder, metal yttrium 1 part of fine powder, 1 part of sodium dodecylbenzenesulfonate, 1 part of binder (polyethylene oxide: aluminum dihydrogen phosphate: sodium lignosulfonate = 1:...

Embodiment 2

[0044] A high-density refractory ceramic fiber is prepared by mixing ceramic slurry A and ceramic slurry B with a weight ratio of 0.8:1.2.

[0045] Wherein, the A ceramic slurry includes the following raw materials in parts by weight: 60 parts of fused chromium oxide, 20 parts of zirconia, 15 parts of alumina micropowder, 0.5 part of yttrium oxide micropowder, 1.5 parts of lanthanum and lanthanide metal oxide micropowder, 0.5 parts of fine metal yttrium powder, 3 parts of tetradecyltrimethylammonium bromide, 50 parts of ethanol, and 50 parts of water.

[0046] The B ceramic slurry includes the following raw materials in parts by weight: 60 parts of fused chromium oxide, 20 parts of zirconia, 15 parts of alumina micropowder, 0.5 part of yttrium oxide micropowder, 1.5 parts of lanthanum and lanthanide metal oxide micropowder, metal yttrium 0.5 parts of fine powder, 1.5 parts of sodium dodecylbenzenesulfonate, 1.5 parts of binder (acrylate: aluminum dihydrogen phosphate: sodium l...

Embodiment 3

[0056] A high-density refractory ceramic fiber is prepared by mixing ceramic slurry A and ceramic slurry B with a weight ratio of 1.2:0.8.

[0057] Wherein, the A ceramic slurry includes the following raw materials in parts by weight: 80 parts of fused chromium oxide, 10 parts of zirconia, 5 parts of alumina micropowder, 1.5 parts of yttrium oxide micropowder, 0.5 part of lanthanum and lanthanide metal oxide micropowder, 1.5 parts of fine metal yttrium powder, 1 part of tetradecyltrimethylammonium bromide, 70 parts of ethanol, and 30 parts of water.

[0058] The B ceramic slurry includes the following raw materials in parts by weight: 80 parts of fused chromium oxide, 10 parts of zirconia, 5 parts of alumina micropowder, 1.5 parts of yttrium oxide micropowder, 0.5 part of lanthanum and lanthanide metal oxide micropowder, metal yttrium 1.5 parts of fine powder, 0.5 parts of sodium dodecylbenzenesulfonate, 0.5 parts of binder (epoxy resin: aluminum dihydrogen phosphate: sodium l...

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Abstract

The invention relates to the field of refractory materials, and discloses a high-density refractory ceramic fiber and a preparation method thereof. The ceramic fiber is prepared by mixing an A ceramicslurry and a B ceramic slurry, wherein the A ceramic slurry comprises electrofused chromium oxide, zirconia, alumina micro powder, yttrium oxide micro powder, lanthanum and / or lanthanide metal oxidemicro powder, metal yttrium micro powder, tetradecyl trimethyl ammonium bromide, ethanol and water; and the B ceramic slurry comprises electrofused chromium oxide, zirconia, alumina micro powder, yttrium oxide micro powder, lanthanum and / or lanthanide metal oxide micro powder, metal yttrium micro powder, sodium dodecyl benzene sulfonate, binding agent, ethanol and water. According to the high-density refractory ceramic fiber, the using amount of the binding agent is greatly reduced, and the density of the ceramic fiber is effectively increased, therefore, the ceramic fiber has a higher strength.

Description

technical field [0001] The invention relates to the field of refractory materials, in particular to a high-density refractory ceramic fiber and a preparation method thereof. Background technique [0002] Ceramic fiber is a kind of fibrous lightweight refractory material, which has the advantages of light weight, high temperature resistance, good thermal stability, low thermal conductivity, small specific heat and mechanical vibration resistance, so it is widely used in machinery, metallurgy, chemical industry, petroleum, ceramics, Glass, electronics and other industries have been widely used. [0003] At present, the widely used high-temperature insulation fiber materials mainly include aluminum silicate-based ceramic fibers, alumina-based and zirconia-based ceramic fibers. However, aluminum silicate refractory fiber products are considered carcinogenic and banned. Although zirconia-based ceramic fibers can withstand high temperatures of 2000°C, they will expand in volume, ...

Claims

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Application Information

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IPC IPC(8): C04B35/66C04B35/12D01F9/08
CPCC04B35/12C04B35/62231C04B35/66C04B2235/3217C04B2235/3224C04B2235/3225C04B2235/3227C04B2235/3244C04B2235/40C04B2235/447C04B2235/77C04B2235/95C04B2235/96
Inventor 周成周益城周成平
Owner 长兴正发热电耐火材料有限公司
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