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Electrostatic-screening graphene anticorrosion coating and preparation method thereof

A technology of electrostatic shielding and anti-corrosion coatings, applied in anti-corrosion coatings, conductive coatings, polyether coatings, etc., can solve problems such as mechanical properties, anti-corrosion performance degradation, graphene easy to re-overlap and gather, destroy uniformity, and compactness, etc., to achieve Improve stability, improve electrostatic shielding effect and stability, and prevent agglomeration

Active Publication Date: 2018-05-18
HEBEI CHENYANG INDAL & TRADE GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The composite coating provided by the present invention has both hydrophobicity and antistatic properties, does not contain any fluorine-containing substances, is environmentally friendly, and has excellent durability. However, graphene will agglomerate itself, destroying the uniformity and compactness of its dispersion. Agglomeration occurs when it is applied to coatings, and stress concentration occurs inside the coating film, resulting in a decrease in mechanical properties and anti-corrosion properties
At present, the application of graphene in anti-corrosion coatings has the defect that it is difficult to disperse, and the layers of graphene are easy to overlap and gather again.

Method used

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  • Electrostatic-screening graphene anticorrosion coating and preparation method thereof

Examples

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Embodiment 1

[0025] An electrostatic shielding graphene anticorrosive coating, comprising the following parts by weight: 65 parts by weight of polyvinylidene fluoride-tetrafluoroethylene-perfluoromethyl vinyl ether emulsion, 15 parts by weight of electrostatic shielding agent, and 15 parts by weight of gold nanowires , 5 parts by weight of sodium tripolyphosphate, 8 parts by weight of aminopropyltriethoxysilane, 2 parts by weight of polyoxypropylene glycerol ether, 3 parts by weight of BYK 354.

[0026] The preparation method of the electrostatic shielding graphene anticorrosive coating includes the following steps:

[0027] Place the porous carbon microspheres and the surfactant stearic acid in the dispersion of graphene oxide, ultrasonically disperse for 10-30 minutes, and then dry, and then spray the polyacetylene on the surface of the porous microspheres with a spray dryer. After drying, Get electrostatic shielding agent;

[0028] Mix the polyvinylidene fluoride-tetrafluoroethylene-perfluoro...

Embodiment 2

[0032] An electrostatic shielding graphene anticorrosive coating, comprising the following parts by weight: 75 parts by weight of polyvinylidene fluoride emulsion, 20 parts by weight of electrostatic shielding agent, 10 parts by weight of carbon black, 8 parts by weight of sodium tripolyphosphate, and diethylene triamino acid 3 parts by weight of propyltrimethoxysilane, 3 parts by weight of polyoxypropylene glyceryl ether, and 9 parts by weight of BYK 348.

[0033] The preparation method of the electrostatic shielding graphene anticorrosive coating includes the following steps:

[0034] Place the porous polystyrene microspheres and the surfactant fatty alcohol sodium sulfate in the dispersion of graphene oxide, ultrasonically disperse for 10-30 minutes, and then dry, then spray the polyacetylene on the surface of the porous microspheres with a spray dryer, and dry Then, the electrostatic shielding agent is obtained; the amount of sodium sulfate of fatty alcohol is 5% of the mass of...

Embodiment 3

[0039] An electrostatic shielding graphene anticorrosive coating, comprising the following parts by weight: 80 parts by weight of polyurethane emulsion, 25 parts by weight of electrostatic shielding agent, 5 parts by weight of silver nanoparticles, 8 parts by weight of polyacrylamide, and aminopropyl triethoxy 3 parts by weight of silane, 5 parts by weight of polyoxyethylene polyoxypropanolamine ether, 3 parts by weight of BYK 346;

[0040] The preparation method of the electrostatic shielding graphene anticorrosive coating includes the following steps:

[0041] Place the porous ceramic microspheres and fluorocarbon surfactant in the dispersion of graphene oxide, ultrasonically disperse for 10-30 minutes, and then dry, and then spray the polyacetylene on the surface of the porous microspheres with a spray dryer. After drying, the result is Electrostatic shielding agent;

[0042] Mix polyurethane emulsion, silver nanoparticles, polyacrylamide, aminopropyltriethoxysilane, polyoxyethyl...

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Abstract

The invention relates to the field of coatings, in particular to an electrostatic-screening graphene anticorrosion coating and a preparation method thereof. The electrostatic-screening graphene anticorrosion coating comprises, by weight, 60-80 parts of organic polymer emulsion, 10-25 parts of an electrostatic screening agent, 5-20 parts of a conductive filler, 5-8 parts of a dispersant, 3-8 partsof a coupling agent, 1-5 parts of a defoaming agent, and 3-9 parts of a leveling agent, wherein the electrostatic screening agent comprises porous microspheres, graphene film and polyacetylene film sequentially from inside to outside and allows graphite to be evenly distributed on the surface of the porous microspheres, the porous microspheres are sealed with the polyacetylene film, and aggregation of the graphene film is prevented accordingly. By adding the electrostatic screening agent into the coating, the electrostatic screening action and stability of the coating can be significantly improved, aggregation of graphene in the coating can be prevented, graphene stability can be improved, and coating stability can be improved accordingly.

Description

Technical field [0001] The invention relates to the field of coatings, in particular to an electrostatic shielding graphene anticorrosive coating and a preparation method thereof. Background technique [0002] Electrostatic discharge is a common phenomenon in daily life. In a dry environment, sometimes the human body will feel electricity when touching metal objects and occasionally see electric sparks. This is the phenomenon of electrostatic discharge, which is also the phenomenon of ESD. . Due to the friction between objects, static electricity is easy to accumulate, causing static electricity hazards, interfering with the normal operation of electronic computers and precision instruments, and even causing explosions and fires in severe cases. Electrostatic discharge will produce a short discharge current and a strong discharge magnetic field. It can cause malfunction of electronic equipment in operation, and even damage to internal components, resulting in loss of function o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D127/16C09D175/04C09D171/02C09D5/08C09D5/24C09D7/62C09D7/65
CPCC08K2201/011C08L2201/04C08L2205/025C08L2205/03C09D5/08C09D5/24C09D127/16C09D171/02C09D175/04C08L71/02C08K13/06C08K9/10C08K7/24C08L25/06C08L33/26C08K7/28
Inventor 陈庆昝航
Owner HEBEI CHENYANG INDAL & TRADE GROUP CO LTD
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