Technology for preparing melamine resin essence microcapsule
A fragrance microcapsule and melamine resin technology, which is applied in the field of textile finishing, can solve the problems of low fragrance wrapping rate, short fragrance retention time, bad hand feeling, etc., and achieve the effect of simplifying the finishing process and good effect
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[0036] (3) Preparation of melamine resin prepolymer
[0037] Put 5-10 parts of melamine and 10-20 parts of 37% formaldehyde solution into a four-necked bottle in parts by weight, heat up to 60-80°C under stirring conditions, and add 0.1-1 part of triethanolamine after the melamine is completely dissolved, Adjust the pH to 7-10, and react for 10-30 minutes to obtain a transparent and viscous melamine resin prepolymer;
[0038] (4) Preparation of self-adhesive double-wall essence microcapsules
[0039] By weight, 10-30 parts of essence, 2-5 parts of methyl methacrylate, 2-5 parts of acrylonitrile, 1-3 parts of butyl acrylate, 1-3 parts of isooctyl acrylate, 0.2-0.5 parts of methyl Acrylic acid, 0.2-0.5 parts of hydroxyethyl acrylate, 0.1-0.3 parts of diacetone acrylamide, 0.1-0.3 parts of adipic acid dihydrazide, and 0.02-0.05 parts of azobisisobutyronitrile are placed in a beaker at a temperature of 30 Stir and mix at -50°C to form a homogeneous oil solution;
[0040]Mix the...
Embodiment 1
[0044] (1) Preparation of styrene-maleic anhydride copolymer powder
[0045] A, maleic anhydride and benzoyl peroxide are added to dissolve in the toluene of 90ml;
[0046] B. Dissolve styrene in 70ml-90ml toluene, heat to 80°C while stirring;
[0047] C. Mix dodecyl mercaptan with 30ml-50ml toluene, heat to 80°C while stirring;
[0048] D. When the solution obtained in step A is heated to ℃, while adding the solution obtained in step B dropwise, add the solution obtained in step C dropwise. After the dropwise addition, heat to 90 ℃ and keep it warm, and stir for 3 hours to obtain low molecular weight styrene-malay Anhydride polymer dispersion system;
[0049] E, suction filtration, 80 ℃ of vacuum dryings, obtain low molecular weight-maleic anhydride copolymer, and the number-average molecular weight of copolymer is 10000;
[0050] Described reaction system comprises two kinds of monomer maleic anhydride and styrene, initiator, solvent and polymerization inhibitor, the tota...
Embodiment 2
[0061] (1) Preparation of styrene-maleic anhydride copolymer powder
[0062] A, maleic anhydride and lauryl peroxide are added to dissolve in the chlorobenzene of 70ml;
[0063] B. Dissolve styrene in 70mlml chlorobenzene, heat to 65°C while stirring;
[0064] C. Mix propanethiol with 30mlml chlorobenzene, stir while heating to 65°C and keep warm;
[0065] D. When the solution obtained in step A is heated to 65°C, while adding the solution obtained in step B dropwise, add the solution obtained in step C dropwise. After the dropwise addition, heat to 75°C and keep it warm, and stir for 1.8 hours to obtain low molecular weight styrene- Maleic anhydride polymer dispersion system;
[0066] E, suction filtration, 60 ℃ of vacuum dryings, obtain low molecular weight-maleic anhydride copolymer, and the number-average molecular weight of copolymer is 5000;
[0067] Described reaction system comprises two kinds of monomer maleic anhydride and styrene, initiator, solvent and polymeriz...
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