Pressure sensitive adhesion bonding agent compound, pressure sensitive adhesion bonding agent, pressure sensitive adhesion bonding sheet and display body
A pressure-sensitive adhesive and adhesive technology, applied in the direction of adhesive types, pressure-sensitive films/sheets, ester copolymer adhesives, etc., can solve problems such as durability conditions, bubbles, peeling, etc., to achieve Excellent step followability and excellent anti-foaming effect
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[0099] (2) Preparation of pressure-sensitive adhesive adhesive composition
[0100] The pressure-sensitive adhesive composition P can be obtained by mixing a radical polymerizable component (A), an ion polymerizable component (B), a visible light-activated radical polymerization initiator (C), and an ultraviolet-ray activated ion polymerization initiator ( D) at the same time, according to the need to add additives and prepare.
[0101] Here, when a (meth)acryloyl group-containing monomer or a vinyl group-containing monomer is used as the radically polymerizable component (A), since its molecular weight is relatively small and its viscosity is low, it can be used without a solvent. Mix the ingredients. This pressure-sensitive adhesive composition P can be used as a coating liquid as it is, as a solventless pressure-sensitive adhesive composition.
[0102] [Pressure Sensitive Adhesive Adhesives]
[0103] The pressure-sensitive adhesive of the present embodiment is obtained b...
Embodiment 1
[0157] 1. Preparation of urethane acrylate oligomers
[0158] 1 mole of polypropylene glycol (PPG) with a weight-average molecular weight of 9,200, 2 moles of isophorone diisocyanate (IPDI), and 2 moles of 2-hydroxyethyl acrylate (HEA) were polymerized to obtain urethane acrylate oligomers Polyether urethane acrylate with a weight average molecular weight of 9,900.
[0159] In addition, the weight-average molecular weights of polypropylene glycol and polyether urethane acrylate are values converted to standard polystyrene measured under the following conditions by gel permeation chromatography (GPC).
[0160] ・GPC measuring device: HLC-8020 manufactured by Tosoh Co., Ltd.
[0161] ・GPC column: manufactured by Tosoh Co., Ltd. (hereinafter, described in order of passage)
[0162] TSK guard column HXL-H
[0163] TSK ge1 GMHXL (×2)
[0164] TSK ge1 G2000HXL
[0165] ·Determination solvent: tetrahydrofuran
[0166] ·Measurement temperature: 40℃
[0167] 2. Preparation of P...
Embodiment 2
[0181] Except having changed the compounding quantity of the ionically polymerizable component (B) into 5 mass parts, it carried out similarly to Example 1, and produced the pressure-sensitive adhesive adhesive sheet.
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