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Preparation method and application of cobalt disulfide and carbon nano fiber composite material

A carbon nanofiber, composite material technology, applied in the directions of carbon fiber, fiber treatment, fiber chemical characteristics, etc., can solve the problems of long charge-discharge cycle, low capacity density, low power density, etc., and achieves fewer synthesis steps, simple operation methods, The effect of increasing the surface area

Active Publication Date: 2017-09-26
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Solar energy and wind energy are efficient, green, environmentally friendly and renewable, but they are not stable. For example, solar energy cannot be generated at night, and wind energy is also uncertain. Solar energy and electric energy cannot be stored like fossil energy, so it is necessary to design a storage Energy systems store and utilize energy
At present, the more common energy storage systems are batteries and electrostatic capacitors. Batteries have high energy density and large storage capacity, but the charge and discharge cycle is long and the power density is low; electrostatic capacitors have fast charge and discharge speeds and high power density, but low capacity density. small amount

Method used

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  • Preparation method and application of cobalt disulfide and carbon nano fiber composite material
  • Preparation method and application of cobalt disulfide and carbon nano fiber composite material
  • Preparation method and application of cobalt disulfide and carbon nano fiber composite material

Examples

Experimental program
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Embodiment 1

[0033] Embodiment 1 (best embodiment)

[0034] A preparation method of a cobalt disulfide and carbon nanofiber composite material that can be used as an electrode material for a supercapacitor, the specific steps are as follows:

[0035] (1) The spinning solution is a polyacrylonitrile (PAN, Mw=150,000) solution with a concentration of 10%, using N-N dimethylformamide (DMF) as a solvent, stirring for 12 hours, sucking the mixed PAN solution into a syringe, and electrospinning The wire conditions are: voltage 12.5kv, flow rate 0.5mL / h, inner diameter of the needle tube 0.8mm, distance from the needle to the aluminum foil, that is, the receiving distance is 10cm. The spinning time was 10 hours. Cut the white film obtained after spinning into 2*15cm long strips and place them in a tube furnace for pre-carbonization. The conditions are: in an air atmosphere at room temperature 1 °C / min rise to 270 °C, keep warm for 2 hours, and cool to room temperature. Then carry out the carbo...

Embodiment 2

[0043] Embodiment 2 (comparative example)

[0044] A preparation method of a cobalt disulfide and carbon nanofiber composite material that can be used as an electrode material for a supercapacitor, the specific steps are as follows:

[0045] (1): This step is exactly the same as Example 1.

[0046] (2) Hydrothermal process: Weigh 20 mg of carbonized carbon fiber, activate it with concentrated nitric acid for 12 hours, add 0.1 g of cobalt nitrate hexahydrate and 0.05 g of thioacetamide into 20 mL of deionized water, dissolve it with ultrasonic waves, and activate After washing the carbon fiber with water, add it to 20mL solution, transfer the solution to a 35mL reaction kettle, put it in an oven, Reaction at 140℃ for 1h, 3h, 5h . After the reaction, after the reactor was cooled, the carbon fiber was taken out, washed several times with distilled water and ethanol respectively, and vacuum-dried at 60° C. to obtain a composite material.

[0047] The SEM photos of cobalt disul...

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PUM

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Abstract

The invention relates to a preparation method and application of a cobalt disulfide and carbon nano fiber composite material. The preparation method comprises the following steps: firstly, preparing carbon nano fiber by using an electrostatic spinning method; by taking N-N dimethyl formamide (DMF) as a solvent, preparing a polyacrylonitrile spinning solution, uniformly stirring, sucking into an injector, and performing electrostatic spinning; cutting a white film obtained after spinning into long strips, and performing thermal treatment in a tubular furnace so as to obtain a black carbon fiber film; activating with concentrated nitric acid, adding cobalt nitrate hexahydrate and thioacetamide so as to obtain a solution, performing ultrasonic treatment, further transferring the solution into a reaction kettle, and performing hydrothermal reaction; after the reaction kettle is cooled after reaction, taking out the carbon fiber, respectively washing the carbon fiber with distilled water and ethanol for multiple times, and performing vacuum drying, thereby obtaining the cobalt disulfide and carbon nano fiber composite material. The cobalt disulfide and carbon nano fiber composite material is used as an electrode material of a supercapacitor, and properties of the supercapacitor can be tested.

Description

technical field [0001] The invention belongs to the technical field of inorganic nanometer materials, and in particular relates to a preparation method and application of a cobalt disulfide and carbon nanofiber composite material. Background technique [0002] In recent years, the average global temperature has risen and fossil fuels have been increasingly depleted. Solving the problem of energy shortage has attracted widespread attention. Scholars have begun to look for alternative new energy sources. Solar energy and wind energy are efficient, green, environmentally friendly and renewable, but they are not stable. For example, solar energy cannot be generated at night, and wind energy is also uncertain. Solar energy and electric energy cannot be stored like fossil energy, so it is necessary to design a storage The energy system uses the stored energy. At present, the more common energy storage systems are batteries and electrostatic capacitors. Batteries have high energy...

Claims

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Application Information

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IPC IPC(8): D01F9/22D06M11/53H01G11/30H01G11/36D06M101/40
CPCD01F9/225D06M11/53D06M2101/40H01G11/30H01G11/36Y02E60/13
Inventor 吴庆生程玉培
Owner TONGJI UNIV
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