Colored photosensitive resin composition color filter and image display device produced using the same
A technology of photosensitive resin and composition, which is applied in the direction of photosensitive materials, optics and instruments used in optomechanical equipment, and can solve problems such as uneven brightness, reduced aperture ratio, flatness, etc., and achieve excellent brightness and close adhesion The effect of excellent performance and excellent sensitivity
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Synthetic example 1
[0226] Synthesis Example 1: Production of Alkali-Soluble Resin
[0227] 100 g of propylene glycol monomethyl ether acetate and 100 g of propylene glycol monomethyl ether were charged into a flask equipped with a stirrer, a thermometer, a reflux cooling pipe, a dropping funnel, and a nitrogen introduction pipe, and the atmosphere in the flask was replaced with air. After adding nitrogen, 8.2 g of azobisisobutyronitrile, 3.1 g of monomethacrylate (manufactured by Hitachi Chemical Co., Ltd., FA-513M) with a tricyclodecane skeleton, 55.2 g of 2-ethylhexyl acrylate, 4 - 5.9 g of methylstyrene, 85.2 g of glycidyl methacrylate, and 6.0 g of n-dodecyl mercaptan. Then, stirring was performed to raise the temperature of the reaction liquid to 80° C., and the reaction was carried out for 4 hours.
[0228] The temperature of the reaction solution was lowered to normal temperature, and the atmosphere of the flask was replaced with air from nitrogen, and then 0.2 g of triethylamine, 0.1 ...
Synthetic example 2
[0230] Synthesis Example 2: Production of Alkali-Soluble Resin
[0231] 100 g of propylene glycol monomethyl ether acetate and 100 g of propylene glycol monomethyl ether were charged into a flask equipped with a stirrer, a thermometer, a reflux condenser, a dropping funnel, and a nitrogen introduction pipe, and the atmosphere in the flask was replaced with air. After nitrogen, 8.2 g of azobisisobutyronitrile, 3.1 g of monomethacrylate (manufactured by Hitachi Chemical Co., Ltd., FA-513M) of tricyclodecane skeleton, 38.4 g of n-butyl acrylate, 4-methyl 5.9 g of styrene, 85.2 g of glycidyl methacrylate, and 6.0 g of n-dodecyl mercaptan. Then, stirring was performed to raise the temperature of the reaction liquid to 80° C., and the reaction was carried out for 4 hours.
[0232] The temperature of the reaction liquid was lowered to normal temperature, and the atmosphere of the flask was replaced with air from nitrogen, then 0.2 g of triethylamine, 0.1 g of 4-methoxyphenol, 43.2...
Synthetic example 3
[0234] Synthesis Example 3: Production of Alkali-Soluble Resin
[0235] 182 g of propylene glycol monomethyl ether acetate was charged into a flask equipped with a stirrer, a thermometer, a reflux condenser, a dropping funnel, and a nitrogen introduction tube, and after replacing the atmosphere in the flask with nitrogen from air, the temperature was raised to 100°C.
[0236] Then, in the above-mentioned flask, 70.5 g of benzyl methacrylate, 43.0 g of methacrylic acid, 22.0 g of monomethacrylate with a tricyclodecane skeleton (manufactured by Hitachi Chemical Co., Ltd., FA-513M), 22.0 g of propylene glycol mono A mixed solution of 136 g of methyl ether acetate and 3.6 g of azobisisobutyronitrile was dropped into the flask from the dropping funnel over 2 hours, and stirred at 100° C. for 5 hours.
[0237] Next, the atmosphere in the flask was replaced from nitrogen to air, 35.5 g of glycidyl methacrylate, 0.9 g of tris(dimethylaminomethyl)phenol, and 0.145 g of hydroquinone w...
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