Fireproof coating for self-repairing type steel structure and preparation method thereof
A fire-retardant coating and self-repairing technology, applied in fire-resistant coatings, anti-corrosion coatings, polyurea/polyurethane coatings, etc., can solve the problems of poor durability, cracking, and poor fire performance, and achieve increased durability, reduced dosage, Guaranteed self-healing effect
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[0034] The preparation method of described epoxy resin microcapsules is: add 10g urea and 27g 37% formaldehyde aqueous solution in the flask, make urea dissolve completely by magnetic stirring action; After the obtained solution is mixed evenly, adjust the pH value of the solution with triethylamine 8-9, keep a constant temperature of 70°C, react for 1-1.5h, and obtain a viscous milky white wall material; dilute 33g of epoxy resin E44 with 3g of diluent 692 in advance, and add sodium dodecylsulfonate aqueous solution (0.4 g sodium dodecylsulfonate and 10mL deionized water), stirred at 1000r / min for 20 minutes to obtain the core material; under stirring, the gained milky white wall material was added to the core material, and then 1g of resorcinol was added Phenol was stirred, and 0.1g of defoamer n-octanol was added dropwise, and the pH value of the system was adjusted to 3-4 after stirring evenly, and reacted at 60°C for 3 hours; the obtained product was washed with distilled ...
Embodiment 1
[0037] A self-repairing steel structure fireproof coating, the components and their mass percentages are: epoxy modified water-based polyurethane emulsion 20%, melamine formaldehyde resin microencapsulated ammonium polyphosphate 35%, polyurethane microencapsulated inorganic particles 15%, self-healing microcapsules 15%, hydroxyethyl cellulose 0.5%, dispersant 0.5%, defoamer 0.5%, antifungal agent 1%, n-octanol 0.5%, and the rest is water (deionized water); The preparation method of the self-repairing steel structure fireproof coating comprises the following steps:
[0038] 1) weighing each component according to the mass percentage of each component, grinding melamine microencapsulated ammonium polyphosphate and polyurethane microencapsulated inorganic particles into powder, adding deionized water, and fully grinding;
[0039] 2) Add hydroxyethyl cellulose, defoamer, dispersant and antifungal agent, and fully grind;
[0040] 3) adding epoxy-modified water-based polyurethane e...
Embodiment 2
[0042] A self-repairing steel structure fireproof coating, the components and their mass percentages are: epoxy modified water-based polyurethane emulsion 25%, melamine formaldehyde resin microencapsulated ammonium polyphosphate 30%, polyurethane microencapsulated inorganic particles 20%, self-healing microcapsules 10%, hydroxyethyl cellulose 1%, dispersant 0.5%, defoamer 0.5%, antifungal agent 1%, n-octanol 1%, and the rest is water (deionized water). Its preparation method is identical with embodiment 1.
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