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Manufacturing method of moisture-absorbing and anti-static polypropylene fibers

A technology of polypropylene fiber and manufacturing method, which is applied in the manufacture of conductive/antistatic filaments, single-component polyolefin rayon, rayon, etc., and can solve the problems of airtightness, easy dust absorption, and non-hygroscopicity.

Active Publication Date: 2016-11-16
ZHEJIANG MODERN TEXTILE IND RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It is not suitable for clothing due to its non-hygroscopic, airtight, uncomfortable, poor thermal stability, and easy to absorb dust

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Embodiment 1: a kind of manufacture method of hygroscopic antistatic polypropylene fiber adopts following steps:

[0034] A) According to the number of parts by mass, take 0.8 parts of halloysite nanotubes whose characteristic parameters are 40nm in diameter and 500nm in length, 0.5 parts of laurylamine polyoxyethylene ether, 1.2 parts of nano-scale conductive mica powder, and 1.2 parts of characteristic parameters whose length is 0.5 μm, 0.01μm wide attapulgite rod crystals, 4.0 parts of 30% sodium bicarbonate aqueous solution by mass fraction, 0.2 parts of nanoscale calamine powder mixed, stirred in a superheated steam reactor at 150 °C, steamed for 45 minutes, and heated at 400 °C Vacuum microwave irradiation for 2 hours, then immerse in 80 parts of sulfamic acid solution with a mass fraction of 30% for vacuum moisture absorption treatment, after absorption, heat to 60°C for ultrasonic dispersion for 0.5 hours, then stir and disperse for 3.5 hours to obtain suspended ...

Embodiment 2

[0038] Embodiment 2: a kind of manufacture method of hygroscopic antistatic polypropylene fiber adopts following steps:

[0039] A) According to the number of parts by mass, take 1.0 parts of halloysite nanotubes with a characteristic parameter diameter of 70nm and a length of 1200nm, 0.75 parts of laurylamine polyoxyethylene ether, 1.6 parts of nano-scale conductive mica powder, and 1.4 parts of a characteristic parameter with a length of 2.5 μm, 0.05μm wide attapulgite rod crystal, 5.0 parts by mass fraction of 30% sodium bicarbonate aqueous solution, 0.45 parts of nano-scale calamine powder mixed, stirred in a superheated steam reactor at 160 ° C, steamed for 50 minutes, and then heated at 450 ° C Vacuum microwave irradiation for 3 hours, then immerse in 100 parts of sulfamic acid solution with a mass fraction of 30% for vacuum moisture absorption treatment, after absorption, heat to 75°C for ultrasonic dispersion for 1 hour, then stir and disperse for 4 hours to obtain susp...

Embodiment 3

[0043] Embodiment 3: a kind of manufacture method of hygroscopic antistatic polypropylene fiber, adopts following steps:

[0044] A) According to the number of parts by mass, take 1.2 parts of halloysite nanotubes whose characteristic parameters are 100nm in diameter and 2000nm in length, 1.0 parts of laurylamine polyoxyethylene ether, 2.0 parts of nano-scale conductive mica powder, and 1.6 parts of characteristic parameters whose length is 5 μm , with a width of 0.10 μm attapulgite rod crystals, 6.0 parts by mass fraction of 30% sodium bicarbonate aqueous solution, and 0.7 parts of nano-scale calamine powder are mixed, stirred in a superheated steam reactor at 170 ° C, and after steaming for 60 minutes, vacuum at 500 ° C Microwave irradiated for 4 hours, then immersed in 120 parts of sulfamic acid solution with a mass fraction of 30% for vacuum moisture absorption treatment, heated to 95°C for 1.5 hours with ultrasonic dispersion after absorption, and then stirred and disperse...

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Abstract

The invention relates to a manufacturing method of moisture-absorbing and anti-static polypropylene fibers, and belongs to the technical field of polymeric fiber manufacturing. The method comprises the steps that halloysite nanotubes, conductive mica powder, attapulgite crystals, an aqueous sodium bicarbonate solution and calamine powder are mixed, subjected to a steaming reaction and vacuum-microwave radiation and then soaked in a sulfamic acid solution to thoroughly absorb the solution, ultrasonic dispersion is conducted, suspended matter is subjected to microwave plasma etching treatment and ultrasonic treatment, supernatant suspended matter is taken to be filtered, washed and dried, an obtained material is stirred in a mixer together with kieselguhr, aluminum-doped zinc oxide nanometer powder, sodium bentonite, a PP-g-MAH compatibilizer and a silane coupling agent alcoholic solution, isotactic polypropylene powder is added after the mixture is dried, and then stirring and drying are conducted. According to the method, the polypropylene fibers are prepared by blending and mixing isotactic polypropylene through the super-high adsorptive property of the halloysite nanotubes and kieselguhr and the synergistic effect of sodium bentonite and the conductive material, and therefore the polypropylene fibers have the moisture-absorbing, comfortable, dyeable and anti-static characteristics and the like.

Description

technical field [0001] The invention relates to a method for manufacturing hygroscopic and antistatic polypropylene fibers, which belongs to the technical field of polymer fiber manufacturing. Background technique [0002] Polypropylene fiber, also known as PP fiber or polypropylene fiber, is a fiber spun from isotactic polypropylene. Its biggest advantage is light weight and a density of 0.91 / cm 3 , 20-30% lighter than ordinary chemical fibers, is the smallest specific gravity of all textile fibers and has high strength, large elongation, high initial modulus, and excellent elasticity. The abrasion resistance of polypropylene fiber is only second to that of polyamide fiber, and it has good corrosion resistance, especially for inorganic acid and alkali stability, no mildew, no rot, no fear of insects, etc., but polypropylene fiber does not absorb water and is difficult to dye , the static electricity is very large, and the volume resistivity at room temperature is as high a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/46D01F1/10D01F1/09
CPCD01F1/09D01F1/10D01F6/46
Inventor 范艳苹陶仁中李琪樊健美张芳胡克勤
Owner ZHEJIANG MODERN TEXTILE IND RES INST
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