Colored curable resin composition
A technology of curable resin and composition, which is applied in nonlinear optics, benzoxanthene dyes, instruments, etc., and can solve the problem of no evaluation of the lightness of color filters, etc.
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[0862] Hereinafter, examples are given to describe the present invention more specifically, but the present invention is of course not limited by the following examples, and of course it can also be implemented with appropriate changes within the range that can be adapted to the purposes described above and below, and they are all included in The technical scope of the present invention.
[0863] (1) Polymethyl compounds
[0864] Polymethyl compound synthesis examples 1-54
[0865] 0.01 mol of indolenine intermediate and 16 g of pyridine or acetonitrile were mixed, 0.012 mol of acetic anhydride was added dropwise, and stirred at room temperature to 50° C. for 1 hour. Add 0.01 mol of active methylene compound and 0.02 mol of triethylamine, and stir at room temperature to 50° C. for 1 to 3 hours. The obtained solid was purified by reflux with methanol, and the solid was dried at 120° C. to obtain the target product. The analysis results are shown in [Table 1] to [Table 6].
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Synthetic example 55
[0878] [Synthesis Example 55 of Polymethyl Compounds] Production of Compound No. 84
[0879] 0.2 g of Compound No. 31 and 20 g of ion-exchanged water were mixed, and an aqueous sodium hydroxide solution was added dropwise to homogenize the solution. An aqueous solution of 0.062 g of barium chloride dihydrate was charged thereinto, and stirred for 30 minutes. The obtained solid was filtered, washed with water, and dried to obtain 0.19 g of the target product (yield: 82.5%).
Synthetic example 56
[0880] [Synthesis Example 56 of Polymethyl Compounds] Production of Compound No. 85
[0881] Except having used copper sulfate pentahydrate instead of barium chloride dihydrate, 0.07 g (yield 33.3%) of the target object was obtained similarly to polymethyl compound synthesis example 55.
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