High-anti-slippery abrasion-resistant material for shoes and preparation method thereof

A wear-resistant material and anti-slip technology, which is applied in the field of shoes, can solve problems such as increasing the difficulty of production, and achieve the effects of enhancing mechanical properties, improving wear resistance and anti-wet skid performance

Active Publication Date: 2016-07-20
QUANZHOU JIYOU SHOES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN103483634 discloses a kind of non-slip rubber sole material, adding TDI modified nano SiO 2 and other additives, improve the coefficient of friction, but due to SiO 2 Additional modification process preparation is required, which increases the difficulty of production, so a high anti-slip and wear-resistant rubber sole material is urgently needed

Method used

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  • High-anti-slippery abrasion-resistant material for shoes and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 30 parts of natural rubber, 20 parts of styrene-butadiene rubber, 25 parts of cis-butadiene rubber and 25 parts by weight of brominated butyl rubber are sent into an open mill to carry out open milling. Mixed rubber material after milling and 8 parts by weight of zinc oxide, 1 part by weight of tetramethylthiuram monosulfide, 1 part by weight of N-phenyl-1-naphthylamine, 15 parts by weight of rubber oil, 0.5 parts by weight of stearin Acid, 13 parts by weight of white carbon black and 27 parts by weight of nano-calcium carbonate are put into a banbury mixer for banbury mixing together, the temperature of the banbury mixer is 125°C, and the material is discharged after banbury mixing for 4 minutes; the above-mentioned mixed glue is discharged into a designated mold and cooled for 24 Hours; After cooling, add 1 part by weight of sulfur, 4.5 parts by weight of silicon carbide and 4 parts by weight of silicone peroxide coupling agent, and send it into a vulcanizing machine f...

Embodiment 2

[0024] First 40 parts of natural rubber, 25 parts of styrene-butadiene rubber, 20 parts of cis-butadiene rubber and 23 parts by weight of chlorinated butyl rubber are prepared and sent into the mill for milling. The roller distance of the mill is 1mm, and the thin pass is 10 times; Finally, the mixed rubber material after milling is mixed with 4 parts by weight of zinc carbonate, 3 parts by weight of dibenzothiazole disulfide, 3 parts by weight of N-phenyl-N'-isopropyl-p-phenylenediamine, 20 parts by weight of rubber oil , 1 part by weight of stearic acid, 17 parts by weight of white carbon black and 23 parts by weight of nanometer calcium carbonate are put into banbury mixer banbury together, and banbury mixer temperature is 110 ℃, discharge after banbury mixing 4 minutes; Above-mentioned mixed glue is discharged into In the designated mold, cool for 24 hours; after cooling, add 2 parts by weight of sulfur, 3.5 parts by weight of silicon carbide and 3 parts by weight of α-func...

Embodiment 3

[0026] 30 parts of natural rubber, 40 parts of styrene-butadiene rubber, 25 parts of cis-butadiene rubber and 15 parts by weight of iodized butyl rubber are sent into an open mill to carry out open milling. Finally, mix the mixed rubber material after milling with 3 parts by weight of titanium dioxide, 2 parts by weight of N, N'-bicyclohexyl-2-benzothiazole sulfenamide, 2 parts by weight of 2-mercaptobenzimidazole, 15 parts by weight Part rubber oil, 1.5 parts by weight of stearic acid, 20 parts by weight of white carbon black and 20 parts by weight of nano-calcium carbonate are dropped into banbury mixer banbury together, and banbury mixer temperature is 100 ℃, discharge after banbury mixing 5 minutes; Above-mentioned mixing The rubber is discharged into the designated mold and cooled for 24 hours; after cooling, add 2 parts by weight of sulfur, 3 parts by weight of silicon carbide and 2 parts by weight of long-chain alkylsilane coupling agent, and send it to a vulcanizer for ...

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Abstract

The invention discloses a high-anti-slippery abrasion-resistant material for shoes and a preparation method thereof.The high-anti-slippery abrasion-resistant material is prepared from, by weight, 20-40 parts of natural rubber, 20-40 parts of styrene-butadiene rubber, 20-40 parts of butadiene rubber, 15-25 parts of halogenated butyl rubber, 20-30 parts of nanometer calcium carbonate, 10-20 parts of rubber oil, 10-20 parts of white carbon black, 3-8 parts of an activator, 3-5 parts of silicon carbide, 2-4 parts of organic siloxane, 1-5 parts of an accelerant, 1-3 parts of an antiager, 1-3 parts of sulfur and 0.5-1.5 parts of stearic acid.The raw materials required by the prepared high-anti-slippery abrasion-resistant material for the shoes are low in price and easy to obtain, the preparation process is simple, the strength is high, the anti-slippery performance is good, the abrasion-resistant performance and processing performance are excellent, the friction coefficient is 1.4-1.6, the friction volume is 304-315 / mm<3>, and the material can be used for production of high-anti-slippery abrasion-resistant shoe soles and other auxiliary materials.

Description

technical field [0001] The invention belongs to the field of shoes, and in particular relates to a high anti-slip and wear-resistant material for shoes and a preparation method thereof. Background technique [0002] Generally, the anti-slip (dry) effect of rubber materials under normal conditions is mostly good, but some industries require higher anti-slip effects to meet the needs of operations under harsh working conditions, such as used in wet ground environments (working with water or kitchen) work shoes, etc. At present, the manufacturing process of high anti-skid shoes on the market is complicated, and the material is expensive. Its price is often ten times or even dozens of times that of ordinary footwear, and the applicable environmental conditions are relatively limited. [0003] According to the current research status of the footwear industry, injection-molded shoe soles such as sneakers and injection-molded shoes are heavy and hard, which affects wearing comfort...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L9/06C08L9/00C08L23/28C08K13/02C08K3/34C08K3/26C08K5/09C08K3/36C08K3/22A43B13/04
CPCA43B13/04C08K2201/011C08L7/00C08L9/00C08L9/06C08L2205/02C08L2205/035C08L23/283C08K13/02C08K3/34C08K2003/2296C08K5/09C08K3/36C08K2003/265
Inventor 王勇丁功成
Owner QUANZHOU JIYOU SHOES CO LTD
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