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A kind of alcoholysis-resistant PPA composite material and processing method thereof for automobile

A composite material and alcoholysis-resistant technology, which is applied in the field of alcoholysis-resistant PPA composite materials for automobiles and its processing, and achieves the effects of no change in the surface of the sample, high heat resistance, and good surface of the sample

Inactive Publication Date: 2017-08-22
FOSHAN GAOMING DISTRICT MINGCHENG TOWN NEW ENERGYNEW MATERIAL IND TECH INNOVATION CENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to overcome the deficiencies of the prior art, the present invention provides a PPA composite material with excellent long-term alcoholysis resistance, which solves the problem of the prior art that requires the addition of alcoholysis-resistant agents or anti-alcoholysis agents to meet the requirements of alcoholysis-resistant properties Problem: The PPA composite material does not need to add alcoholysis-resistant agent, not only maintains the original physical properties, but also meets the technical requirements of TL-VW774 in the alcoholysis-resistant chemical properties, that is, placed in 100% ethylene glycol solution at a constant temperature of 135°C After 48 hours, the surface of the product is good without change, without cracking, and has excellent mechanical properties

Method used

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  • A kind of alcoholysis-resistant PPA composite material and processing method thereof for automobile
  • A kind of alcoholysis-resistant PPA composite material and processing method thereof for automobile

Examples

Experimental program
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Effect test

Embodiment 1

[0028] An alcoholysis-resistant PPA composite material for automobiles is composed of the following components by weight percentage: 58% of PPA, 40% of pretreated glass fiber, 0.5% of nucleating agent, 1.1% of auxiliary agent, and 0.4% of heat stabilizer.

[0029] The processing method of described automobile with alcoholysis resistant PPA composite material, comprises the steps:

[0030] (1) Glass fiber is pretreated, including the following steps:

[0031] a. First, mix the silane coupling agent, water and ethanol to prepare a mixed solution. The volume ratio of ethanol, water and silane coupling agent is ethanol: water: silane coupling agent = 30:8:0.8, in which silane coupling agent The joint agent is 3-aminopropyltriethoxysilane;

[0032] b. Immerse the ordinary continuous glass fiber in the mixed solution, ultrasonically treat it for 20 minutes, the frequency is 70KHz, and let it stand for 50 minutes; then mechanically vibrate for 40 minutes, the frequency is 600Hz and ...

Embodiment 2

[0040] An alcoholysis-resistant PPA composite material for automobiles is composed of the following components by weight percentage: 58.1% of PPA, 40% of pretreated glass fiber, 0.4% of nucleating agent, 1% of auxiliary agent, and 0.5% of heat stabilizer.

[0041] The processing method of described automobile with alcoholysis resistant PPA composite material, comprises the steps:

[0042] (1) Glass fiber is pretreated, including the following steps:

[0043] a. First, mix silane coupling agent, water and ethanol to prepare a mixed solution. The volume ratio of ethanol, water and silane coupling agent is ethanol: water: silane coupling agent = 35: 10: 0.5, of which silane coupling agent The joint agent is N-2-aminoethyl-3-aminopropyltrimethoxysilane;

[0044]b. Immerse the ordinary continuous glass fiber in the mixed solution, ultrasonically treat it for 18 minutes, the frequency is 75KHz, and let it stand for 60 minutes; then mechanically vibrate for 50 minutes, the frequency...

Embodiment 3

[0052] An alcoholysis-resistant PPA composite material for automobiles consists of the following components by weight percentage: 58% PPA, 40% pretreated glass fiber, 0.6% nucleating agent, 1% auxiliary agent, and 0.4% heat stabilizer.

[0053] The processing method of described automobile with alcoholysis resistant PPA composite material, comprises the steps:

[0054] (1) Glass fiber is pretreated, including the following steps:

[0055] a. First mix the silane coupling agent, water and ethanol to prepare a mixed solution. The volume ratio of ethanol, water and silane coupling agent is ethanol: water: silane coupling agent = 40:5:1, in which silane coupling agent The coupling agent is diethylenetriaminopropyltrimethoxysilane;

[0056] b. Immerse the ordinary continuous glass fiber in the mixed solution, ultrasonically treat it for 15min, the frequency is 80KHz, and let it stand for 55min; then mechanically vibrate for 60min, the frequency is 550Hz and the amplitude is 1mm; t...

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Abstract

The present invention discloses an automobile alcoholysis-resistant PPA composite material comprising the following components by weight: 58-63.1% of PPA resin, 35-40% of pretreated glass fiber, 0.4-0.6% of a nucleating agent, 1-1.1% of an additive and 0.4-0.5% of a heat stabilizer, and by successive combination of ultrasonic vibration and mechanical vibration, a silane coupling agent and a PPE melt are used for impregnation pretreatment of the glass fiber. The present invention also discloses a processing method of the automobile alcoholysis-resistant PPA composite material, the alcoholysis resistance of the automobile alcoholysis-resistant PPA composite material can be improved under the premise of no reduction of physical properties of the automobile alcoholysis-resistant PPA composite material without addition of an alcoholysis-resistant agent, the automobile alcoholysis-resistant PPA composite material has excellent alcoholysis resistance, the alcoholysis resistance can reach TL-VW774 testing requirements, the sample surface is good, and does not change and crack, and the problem of need of addition of the alcoholysis-resistant agent or an anti-alcoholysis agent for achieving alcoholysis-resistant performance requirements in the prior art and the problem of significant decrease of mechanical performances of a matrix material by addition of PPE in the prior art can be solved.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to an alcoholysis-resistant PPA composite material for automobiles and a processing method thereof. Background technique [0002] With the rapid development of the automobile industry, replacing steel with plastic has become the trend and direction of the development of automobile materials. Glass fiber reinforced PPA materials are widely used in water chamber parts of automobiles, such as thermostats, for their excellent heat resistance and mechanical properties. Shells, water tank joints, etc. These parts not only require the material to have excellent mechanical properties, but also require the material to have good hydrolysis resistance and alcoholysis resistance, and can be used for a long time in hot water and antifreeze ethylene glycol mixed solution without performance degradation. [0003] The materials used for automotive water chamber parts are required to be resistant t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/10C08L23/16C08K13/06C08K9/06C08K7/14C08K5/524C08K5/17C08K5/103C08K5/13C08K5/098
CPCC08L77/10C08L2201/08C08L23/16C08K13/06C08K9/06C08K7/14C08K5/524C08K5/17C08K5/103C08K5/13C08K5/098
Inventor 严梅霞
Owner FOSHAN GAOMING DISTRICT MINGCHENG TOWN NEW ENERGYNEW MATERIAL IND TECH INNOVATION CENT
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