Dielectric material with positive linear capacitance temperature change rate, and preparation method thereof
A technology of capacity temperature change rate and dielectric material, which is applied in the field of functional ceramic materials, can solve the problems of large dielectric loss of ceramics, decrease of capacitor capacity, and influence on circuit performance, and achieve the effect of improving insulation resistivity, reducing dielectric loss, and reducing loss
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Embodiment 1
[0029] (1) Weigh 52.26gBi 2 o 3 , 11.89gNa 2 CO 3 and 35.85gTiO 2 , mixed ball milling, sieving, and calcining at 800°C for 4 hours to synthesize sodium bismuth titanate; the sodium bismuth titanate is mainly Bi 0.5 Na 0.5 TiO 3 , containing a small amount of Bi 0.6 Na 0.4 TiO 3 and Bi 0.4 Na 0.6 TiO 3 . The same goes for other embodiments.
[0030] (2) 92.68g barium titanate and 7.32g bismuth sodium titanate were weighed, mixed by ball milling, dried, crushed through a 40-mesh sieve, and calcined at 1200°C for 3 hours to synthesize a eutectic compound;
[0031] (3) Weigh 79.03gBi 2 o 3 , 20.97gH 3 BO 3 , mixed by ball milling with alcohol as the medium, dried, crushed through a 40-mesh sieve, and calcined at 400°C for 4 hours to synthesize BiBO 3 ;
[0032] (4) Accurately weigh 97.65g of the compound prepared in step (2), 1.682gNb 2 o 5 , 0.426gNd 2 o 3 , 0.242gMnCO 3 、2gBiBO 3 Proceed to the ingredients. Grind for 6 hours with 2 mm zirconium balls, ...
Embodiment 2
[0034] (1) Weigh 52.26gBi 2 o 3 , 11.89gNa 2 CO 3 and 35.85g TiO 2 , mixed ball milling, sieving, and calcining at 900°C for 2 hours to synthesize sodium bismuth titanate;
[0035] (2) Weigh 93.6g of barium titanate and 6.4g of bismuth sodium titanate, mix them by ball milling, dry them, crush them through a 40-mesh sieve, and calcinate at 1140°C for 6 hours to synthesize a eutectic compound;
[0036] (3) Weigh 79.03gBi 2 o 3 , 20.97gH 3 BO 3 , mixed by ball milling with alcohol as the medium, dried, crushed through a 40-mesh sieve, and calcined at 400°C for 4 hours to synthesize BiBO 3 ;
[0037] (4) Accurately weigh the compound prepared by 97.6g step (2), 1.679gNb 2 o 5 , 0.483gEr 2 o 3 , 0.242gMnCO 3 、2.5gBiBO 3 , for batching. Grind for 6 hours with 2mm yttrium stabilized zirconium balls, dry and pass through an 80-mesh standard sieve, add 6-7% paraffin to fry and granulate, and then pass through an 80-mesh standard sieve again. Press the granulated powder ...
Embodiment 3
[0039] (1) Weigh 52.26gBi 2 o 3 , 11.89gNa 2 CO 3 and 35.85gTiO 2 , mixed ball milling, sieving, and calcining at 850°C for 3 hours to synthesize sodium bismuth titanate;
[0040] (2) Weigh 91.76g of barium titanate and 8.24g of bismuth sodium titanate, mix them by ball milling, dry, crush and pass through a 40-mesh sieve, and calcinate at 1140°C for 2 hours to synthesize a eutectic compound;
[0041] (3) Weigh 79.03gBi 2 o 3 , 20.97gH 3 BO 3 , mixed by ball milling with alcohol as the medium, dried, crushed through a 40-mesh sieve, and calcined at 400°C for 4 hours to synthesize BiBO 3 ;
[0042] (4) Accurately weigh 97.48g of the compound prepared in step (2), 2.016gNb 2 o 5 , 0.161gEr 2 o 3 , 0.339gMnCO 3 、2.5gBiBO 3 , for batching. Grind for 6 hours with 2mm yttrium stabilized zirconium balls, dry and pass through an 80-mesh standard sieve, add 6-7% paraffin to fry and granulate, and then pass through an 80-mesh standard sieve again. Press the granulated p...
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