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Dielectric material with positive linear capacitance temperature change rate, and preparation method thereof

A technology of capacity temperature change rate and dielectric material, which is applied in the field of functional ceramic materials, can solve the problems of large dielectric loss of ceramics, decrease of capacitor capacity, and influence on circuit performance, and achieve the effect of improving insulation resistivity, reducing dielectric loss, and reducing loss

Active Publication Date: 2016-01-20
FUJIAN TORCH ELECTRON TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the second type of ceramic capacitors are commonly used in circuit design. Due to the large dielectric loss of the selected ceramics, and the capacitance-temperature curve within the operating temperature range is nonlinear, especially when the capacitance-temperature curve of the selected ceramic capacitor has a negative temperature change. , with the continuous exchange of charges in the circuit, the capacitor itself will generate heat, causing the temperature of the capacitor itself to rise, thereby causing the capacity of the capacitor to decrease
When selecting capacitors normally, the capacitance value at room temperature is generally used as the design basis. If the capacitance value of the capacitor decreases in the high temperature stage, it will inevitably affect the performance of the circuit.

Method used

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  • Dielectric material with positive linear capacitance temperature change rate, and preparation method thereof
  • Dielectric material with positive linear capacitance temperature change rate, and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0029] (1) Weigh 52.26gBi 2 o 3 , 11.89gNa 2 CO 3 and 35.85gTiO 2 , mixed ball milling, sieving, and calcining at 800°C for 4 hours to synthesize sodium bismuth titanate; the sodium bismuth titanate is mainly Bi 0.5 Na 0.5 TiO 3 , containing a small amount of Bi 0.6 Na 0.4 TiO 3 and Bi 0.4 Na 0.6 TiO 3 . The same goes for other embodiments.

[0030] (2) 92.68g barium titanate and 7.32g bismuth sodium titanate were weighed, mixed by ball milling, dried, crushed through a 40-mesh sieve, and calcined at 1200°C for 3 hours to synthesize a eutectic compound;

[0031] (3) Weigh 79.03gBi 2 o 3 , 20.97gH 3 BO 3 , mixed by ball milling with alcohol as the medium, dried, crushed through a 40-mesh sieve, and calcined at 400°C for 4 hours to synthesize BiBO 3 ;

[0032] (4) Accurately weigh 97.65g of the compound prepared in step (2), 1.682gNb 2 o 5 , 0.426gNd 2 o 3 , 0.242gMnCO 3 、2gBiBO 3 Proceed to the ingredients. Grind for 6 hours with 2 mm zirconium balls, ...

Embodiment 2

[0034] (1) Weigh 52.26gBi 2 o 3 , 11.89gNa 2 CO 3 and 35.85g TiO 2 , mixed ball milling, sieving, and calcining at 900°C for 2 hours to synthesize sodium bismuth titanate;

[0035] (2) Weigh 93.6g of barium titanate and 6.4g of bismuth sodium titanate, mix them by ball milling, dry them, crush them through a 40-mesh sieve, and calcinate at 1140°C for 6 hours to synthesize a eutectic compound;

[0036] (3) Weigh 79.03gBi 2 o 3 , 20.97gH 3 BO 3 , mixed by ball milling with alcohol as the medium, dried, crushed through a 40-mesh sieve, and calcined at 400°C for 4 hours to synthesize BiBO 3 ;

[0037] (4) Accurately weigh the compound prepared by 97.6g step (2), 1.679gNb 2 o 5 , 0.483gEr 2 o 3 , 0.242gMnCO 3 、2.5gBiBO 3 , for batching. Grind for 6 hours with 2mm yttrium stabilized zirconium balls, dry and pass through an 80-mesh standard sieve, add 6-7% paraffin to fry and granulate, and then pass through an 80-mesh standard sieve again. Press the granulated powder ...

Embodiment 3

[0039] (1) Weigh 52.26gBi 2 o 3 , 11.89gNa 2 CO 3 and 35.85gTiO 2 , mixed ball milling, sieving, and calcining at 850°C for 3 hours to synthesize sodium bismuth titanate;

[0040] (2) Weigh 91.76g of barium titanate and 8.24g of bismuth sodium titanate, mix them by ball milling, dry, crush and pass through a 40-mesh sieve, and calcinate at 1140°C for 2 hours to synthesize a eutectic compound;

[0041] (3) Weigh 79.03gBi 2 o 3 , 20.97gH 3 BO 3 , mixed by ball milling with alcohol as the medium, dried, crushed through a 40-mesh sieve, and calcined at 400°C for 4 hours to synthesize BiBO 3 ;

[0042] (4) Accurately weigh 97.48g of the compound prepared in step (2), 2.016gNb 2 o 5 , 0.161gEr 2 o 3 , 0.339gMnCO 3 、2.5gBiBO 3 , for batching. Grind for 6 hours with 2mm yttrium stabilized zirconium balls, dry and pass through an 80-mesh standard sieve, add 6-7% paraffin to fry and granulate, and then pass through an 80-mesh standard sieve again. Press the granulated p...

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Abstract

The invention discloses a dielectric material with a positive linear capacitance temperature change rate, and a preparation method thereof. According to the preparation method, [(1-x)BaTiO3-xBiyNazTiO3] is taken as a base material, and Nb2O5, RE2O3, MnCO3, and BiBO3 are added, wherein x=0.05-0.15, y=0.4=0.6, z=0.4-0.6, molar ratio of BaTiO3 to BiyNazTiO3 is (1-x):x, and RE is used for representing one or a plurality of elements selected from Sm, Er, or Ce. The dielectric material is suitable for preparing multilayer ceramic capacitors with a positive linear capacitance temperature change rate, and is low in dielectric loss; working temperature ranges from -55 to 150 DEG C, temperature stability is excellent (-15%<=delta C / C<=15%), and temperature changing accords with positive linear changing in the working temperature range. In the temperature range ranging from -55 to 150 DEG C, capacitance temperature compensating capacitors can be prepared from the dielectric material, compensating of negative effects caused by capacitor temperature increasing in functional circuits is realized, balancing of charge capacity in the whole temperature section is realized, and circuit stability and reliability are improved. The dielectric material possesses a promising industrialization prospect, and extremely high industrial application value.

Description

technical field [0001] The invention relates to the technical field of functional ceramic materials, in particular to a positive linear capacity temperature change rate dielectric material and a preparation method thereof. Background technique [0002] At present, the second type of ceramic capacitors are commonly used in circuit design. Due to the large dielectric loss of the selected ceramics, and the capacity-temperature curve within the operating temperature range is nonlinear, especially when the capacity-temperature curve of the selected ceramic capacitor has a negative temperature change , with the continuous exchange of charges in the circuit, the capacitor itself will generate heat, causing the temperature of the capacitor itself to rise, thereby causing the capacity of the capacitor to decrease. When selecting a capacitor normally, the capacitance value at room temperature is generally used as the design basis. If the capacitance value of the capacitor decreases in...

Claims

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Application Information

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IPC IPC(8): C04B35/468C04B35/622
Inventor 陈永虹林志盛宋运雄黄祥贤谢显斌吴金剑许金飘
Owner FUJIAN TORCH ELECTRON TECH CO LTD
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