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A kind of organic montmorillonite and its application

An organic montmorillonite and montmorillonite technology, applied in the treatment of dyed low molecular organic compounds, monocarboxylic acid ester copolymer adhesives, adhesive types, etc., can solve the problem of environmental pollution, corrosive smoke, Toxic and other problems, to achieve the effect of low cost, fast initial adhesion and high adhesion strength

Active Publication Date: 2017-08-15
顶立新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the flame-retardant materials of halogenated flame retardants, a large amount of toxic and corrosive smoke will be produced when burning, which will pollute the environment

Method used

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  • A kind of organic montmorillonite and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) Preparation of organic montmorillonite:

[0028] (1.1) Put 20 kg of natural montmorillonite in a device that has been added with 100 kg of water, stir for about 2.5 hours, let it stand for 5 hours, and then remove the lower layer of coarse sand larger than 200 mesh.

[0029] (1.2) Add 3 kilograms of sodium hexametaphosphate again, add 0.6 kilograms of concentration and be 33wt% hydrochloric acid solution, make the pH value of system be 5-6, after stirring, further divide and be greater than 400 order detritus minerals (feldspar, carbonate Wait);

[0030] (1.3) Repeat step 1.2 for 2 times to obtain the montmorillonite slurry or suspension, that is, the montmorillonite after purification and sodiumization;

[0031] (1.4) Organicization: Add 2.0 kg of cocamidopropyl betaine to the above-mentioned purified sodium montmorillonite solution while stirring, heat and stir in a water bath at 80°C for 2.0 hours, filter and dry, pass through 600 mesh after grinding Sieve, the...

Embodiment 2

[0037] (1) Preparation of organic montmorillonite:

[0038] (1.1) Put 25 kg of natural montmorillonite in a device that has been added with 110 kg of water, stir for about 2.8 hours, let stand for 5.5 hours, and then remove the lower layer of coarse sand greater than 200 mesh.

[0039] (1.2) Add 3.5 kilograms of sodium hexametaphosphate again, add 0.7 kilograms of concentration and be 33% hydrochloric acid solution, make the pH value of the system 5-6, after stirring, further divide and be greater than 400 order detritus minerals (feldspar, carbonate Wait);

[0040] (1.3) Repeat step 1.2 for 2 times to obtain the montmorillonite slurry or suspension, that is, the montmorillonite after purification and sodiumization;

[0041] (1.4) Organicization: Add 2.1 kg of octadecamidopropyl betaine to the above-mentioned purified sodium montmorillonite solution while stirring, heat and stir in a water bath at 81°C for 2.3 hours, filter and dry, and pass through 600°C after grinding. Mesh ...

Embodiment 3

[0047] (1) Preparation of organic montmorillonite:

[0048] (1.1) Put 30 kg of natural montmorillonite in a device that has been added with 120 kg of water, stir for about 3.0 hours, let stand for 6.0 hours, and then remove the lower layer of coarse sand greater than 200 mesh.

[0049] (1.2) Add 4 kilograms of sodium hexametaphosphate again, add 0.8 kilograms of concentration and be 33% hydrochloric acid solution, make the pH value of the system 5-6, after stirring, further divide and be greater than 400 mesh clastic minerals (feldspar, carbonate Wait);

[0050] (1.3) Repeat step 1.2 for 3 times to obtain the montmorillonite slurry or suspension, that is, the montmorillonite after purification and sodiumization;

[0051] (1.4) Organicization: Add 1 kg of octadecamidopropyl betaine and 1.2 kg of cocamidopropyl betaine to the above-mentioned purified sodium montmorillonite solution while stirring, heat and stir in a water bath at 82°C for 2.5 After one hour, filter and dry, pa...

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Abstract

The invention discloses an organic montmorillonite and an application thereof. The invention firstly modifies the montmorillonite to obtain the organic montmorillonite, thereby preparing an adhesive. Among them, organic montmorillonite plays the role of protective colloid and emulsification in the process of vinyl acetate copolymerization. The layered montmorillonite is dispersed in the polymer matrix and has the characteristics of good storage stability, uniform dispersion and strong interfacial binding force. At the same time, montmorillonite is an inorganic flame retardant, which has the advantages of excellent mechanical properties, gas barrier and flame retardant effect, low cost, and convenient processing. It not only improves the mechanical properties of polymers, but also opens up a new way for polymer flame retardants. .

Description

technical field [0001] The invention relates to an adhesive preparation technology, in particular to an organic montmorillonite and its application. Background technique [0002] Water-based polyvinyl acetate adhesive is currently one of the most widely used and used environmentally friendly adhesives. It is obtained by emulsion polymerization with water as the dispersion medium, and is a water-based environmentally friendly adhesive. It is widely used in wood, furniture, decoration, printing, textiles, etc. , leather, paper and other industries, is a very environmentally friendly adhesive. Fast drying, good initial tack, good workability; strong adhesion, high compressive strength; strong heat resistance. Widely used in semi-outdoor and outdoor particleboard, plywood, laminated wood and wood cold-setting finger joints. These plywood boards are widely used in the manufacturing process of wooden doors and other furniture. The boards have large format, many varieties, good...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J131/04C09J11/04C08F218/08C08F220/06C08F220/28C09C1/28C09C3/08
Inventor 刘维均罗平牟海燕宋志强徐建
Owner 顶立新材料科技股份有限公司
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