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High fluidity modified calcium carbonate for plastics and preparation method thereof

A high fluidity, calcium carbonate technology, used in chemical instruments and methods, fibrous fillers, inorganic pigment treatment, etc., can solve problems such as poor direct application effect, uneven dispersion of polymers, interface defects, etc. Convenient source, simple preparation method, and the effect of enhancing self-lubrication and fluidity

Inactive Publication Date: 2015-12-16
池州青阳县龙酉钙业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improve the reinforcing effect of calcium carbonate and the dispersion performance in composite materials And the physical properties of modified calcium carbonate filled composite materials, it is necessary to use different surface modifiers and treatment methods to modify the surface of calcium carbonate powder, thereby broadening the application field of calcium carbonate

Method used

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Embodiment Construction

[0013] specific implementation plan

[0014] The present invention will be described in detail below through specific examples.

[0015] A high-fluidity modified calcium carbonate for plastics and a preparation method thereof, which is prepared from the following raw materials in parts by weight (kg): calcium carbonate 150, sodium oleate 46, sodium dodecylbenzenesulfonate 0.6, bicarbonate Sodium 3, styrene 6, potassium persulfate 0.04, fumed silica 4, organic bentonite 3, dioctyl phthalate 0.6, pregelatinized starch 1, zinc stearate 2, appropriate amount of deionized water;

[0016] A kind of high fluidity modified calcium carbonate for plastics of the present invention and preparation method thereof, are made by following specific steps:

[0017] (1) Dissolve sodium oleate and deionized water to make a 1% aqueous solution of sodium oleate, stir electrically for 10 minutes and raise the temperature to 60°C, add calcium carbonate and stir for 1.5 hours, after stirring, let sta...

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PUM

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Abstract

The invention discloses a high fluidity modified calcium carbonate for plastics and a preparation method thereof. The high fluidity modified calcium carbonate is characterized by being prepared from the following raw materials by weight part: 100-150 of calcium carbonate, 30-50 of sodium oleate, 0.3-0.7 of sodium dodecyl benzene sulfonate, 1-3 of sodium bicarbonate, 4-8 of styrene, 0.02-0.05 of potassium persulfate, 3-5 of fumed silica, 2-3 of organic bentonite, 0.4-1 of dioctyl phthalate, 1-2 of pregelatinized starch, 1-3 of zinc stearate, and a proper amount of deionized water. The dioctyl phthalate, pregelatinized starch and zinc stearate added in the invention can enhance the self-lubrication and fluidity of calcium carbonate, can reduce material loss during processing, also can enhance the toughness and hardness of plastics, and improve the quality of plastic parts. The high fluidity modified calcium carbonate for plastics provided by the invention has the advantages of simple preparation method, convenient raw material sources, and low cost, and has the effect of reinforcing all performance of products as an industrial filler, thus being worth popularizing.

Description

technical field [0001] The invention relates to the field of industrial fillers, in particular to a high-fluidity modified calcium carbonate for plastics and a preparation method thereof. Background technique [0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improve the reinforcing ef...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/02C09C3/08C09C3/06C09C3/10C08K9/10C08K9/04C08K3/26
Inventor 李国栋
Owner 池州青阳县龙酉钙业有限公司
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