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Modified calcium carbonate for automobile plastic and preparation method thereof

A calcium carbonate, modified technology, applied in chemical instruments and methods, fibrous fillers, inorganic pigment treatment, etc., can solve problems such as poor direct application effect, uneven dispersion of polymers, interface defects, etc., and achieve mechanical strength. High, decorative, and enhanced lubricity

Inactive Publication Date: 2015-11-11
池州青阳县龙酉钙业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improve the reinforcing effect of calcium carbonate and the dispersion performance in composite materials And the physical properties of modified calcium carbonate filled composite materials, it is necessary to use different surface modifiers and treatment methods to modify the surface of calcium carbonate powder, thereby broadening the application field of calcium carbonate

Method used

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Embodiment Construction

[0012] specific implementation plan

[0013] The present invention will be described in detail below through specific examples.

[0014] A modified calcium carbonate for automotive plastics and a preparation method thereof, which is prepared from the following raw materials in parts by weight (kg): calcium carbonate 150, sodium oleate 45, sodium dodecylbenzenesulfonate 0.6, sodium bicarbonate 2 , styrene 7, potassium persulfate 0.04, fumed silica 5, organic bentonite 3, zinc oxide 4, silane coupling agent kh5501, sepiolite powder 3, appropriate amount of deionized water;

[0015] A kind of modified calcium carbonate for automobile plastics of the present invention and preparation method thereof, are made by following specific steps:

[0016] (1) Dissolve sodium oleate and deionized water to make a 1% aqueous solution of sodium oleate, stir electrically for 10 minutes and raise the temperature to 60°C, add calcium carbonate and stir for 1.5 hours, after stirring, let stand for...

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Abstract

The invention discloses modified calcium carbonate for automobile plastic and a preparation method thereof. The modified calcium carbonate is characterized by being composed of the following raw materials in parts by weight: 100 to 150 parts of calcium carbonate, 30 to 50 parts of sodium oleate, 0.3 to 0.7 part of sodium dodecyl benzene sulfonate, 1 to 3 parts of sodium bicarbonate, 4 to 8 parts of styrene, 0.02 to 0.05 part of potassium persulfate, 3 to 5 parts of gas-phase silicon dioxide, 2 to 3 parts of organic bentonite, 2 to 4 parts of zinc oxide, 1 to 2 parts of silane coupling agent kh550, 3 to 4 parts of meerschaum powder, and a proper amount of deionized water. The added zinc oxide and meerschaum powder can be bonded to calcium carbonate under the action of coupling agent, thus the sterilizing performance, thermal insulation property, and anticorrosion performance of calcium carbonate are further enhanced, the modified calcium carbonate can be applied to automobile plastic to prolong the service life of automobile shell, at the same time, anti-aging performance and decorative effect of the automobile plastic are also strengthened, the automobile quality is improved therefore, and the modified calcium carbonate is worthy to promote.

Description

technical field [0001] The invention relates to the field of industrial fillers, in particular to a modified calcium carbonate for automobile plastics and a preparation method thereof. Background technique [0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improve the reinforcing effec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/02C09C3/06C09C3/08C09C3/12C09C3/10C08K13/06C08K9/04C08K9/06C08K9/02C08K3/26
Inventor 李国栋
Owner 池州青阳县龙酉钙业有限公司
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