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Method for treating wastewater generated after preparing alcohol from cassavas as raw material

A waste water treatment and alcohol technology, applied in water/sewage multi-stage treatment, water/sludge/sewage treatment, chemical instruments and methods, etc., can solve problems such as excessive foam, deep color, polluted environment, etc., and achieve less foam , the effect of light chroma

Inactive Publication Date: 2015-05-06
GUANGXI COFCO BIO ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process of using cassava as raw material to produce alcohol has become mature, and the residue after alcohol production has also been further utilized, but the waste liquid produced after alcohol production has not been effectively treated and directly discharged outside, which has a serious impact on the environment. The waste liquid has become the chief culprit of polluting the environment
If the alcohol waste liquid is not treated, there will be hidden dangers of damaging the environment. This problem has attracted the attention of alcohol manufacturers, and corresponding measures have been taken. These measures are to directly contact the waste liquid with activated sludge. The organic matter in the waste liquid is degraded through the aerobic respiration of activated sludge. However, the concentration of TCOD and TSS (suspended solids) in the waste liquid after only such activated sludge treatment is still high and the color is deep. There is a lot of foam, it is difficult to use traditional advanced treatment processes such as membrane treatment and ion exchange treatment, and the cost is high, and it is not very good to ensure that the discharge is up to standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The following is carried out by continuous treatment, and the water flow is kept at 200m 3 / h, specifically, send the aerobic effluent (COD value 1200mg / L, SS value 800mg / L) obtained from the waste water of cassava to alcohol after activated sludge treatment into the sedimentation tank and add 2.8kg Polyferric chloride per ton of wastewater (purchased from Guangxi Pingguo Fenghua Technology Co., Ltd.) and anionic polyacrylamide of 4g / ton of wastewater (viscosity average molecular weight is 14 million, purchased from Nanning Zhonglong Environmental Protection Technology Co., Ltd. A130MHW model, the same below) and contact and settle at normal temperature; send the settled supernatant into the Fenton oxidation tower, and add Fenton’s reagent (containing 27% by weight of hydrogen peroxide and 10% by weight of sulfurous acid The aqueous solution of iron) makes the content of hydrogen peroxide in this supernatant be 1.2kg / ton waste water mg / L and the content of ferrous ion b...

Embodiment 2

[0029] The following is carried out by continuous treatment, and the water flow is kept at 200m 3 / h, specifically, send the aerobic effluent obtained from the waste water of cassava to alcohol after activated sludge treatment (value 1230mg / L, SS value 900mg / L) into the sedimentation tank, add 2.5kg / Polyferric chloride (purchased from Guangxi Pingguo Fenghua Technology Co., Ltd.) and anionic polyacrylamide of 3g / ton of waste water were contacted and settled at normal temperature; the settled supernatant was sent to Fen In the Oxidation tower, add Fenton's reagent (being the aqueous solution that contains the hydrogen peroxide of 27% by weight and the ferrous chloride of 10% by weight) so that the content of hydrogen peroxide in the supernatant is 1kg / ton waste water and ferrous The content of ions is 1.2kg / ton of wastewater, and it reacts at normal temperature; the wastewater with a pH value of 5 after the reaction is sent to another reaction tank, and after the pH value is a...

Embodiment 3

[0031] The following is carried out by continuous treatment, and the water flow is kept at 200m 3 / h, specifically, send the aerobic effluent obtained from the waste water of cassava to alcohol after activated sludge treatment (value 1600mg / L, SS value 1200mg / L) into the sedimentation tank, add 3kg / ton The polyferric chloride of wastewater (purchased from Guangxi Pingguo Fenghua Technology Co., Ltd.) and the anionic polyacrylamide of 5g / ton of wastewater are contacted and settled at room temperature; the supernatant after sedimentation is sent to Fenton In the oxidation tower, add Fenton's reagent (for the aqueous solution containing 27% by weight of hydrogen peroxide and 10% by weight of ferrous sulfate) so that the content of hydrogen peroxide in the supernatant is 1.3kg / ton of waste water and ferrous ions The content of the waste water is 1.8kg / ton, and it reacts at normal temperature; the waste water with a pH value of 4 after the reaction is sent to another reaction tank, ...

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Abstract

The invention discloses a method for treating wastewater generated after preparing alcohol from cassavas as a raw material. The method comprises the following steps: (1) adding a primary flocculant according to an amount of 2-5kg / ton of wastewater into aerobic effluent which is discharged by virtue of active sludge treatment after preparation of alcohol, stirring uniformly, and standing for 10-40 minutes to obtain a sludge deposit and a supernatant; (2) adding a Fenton reagent into the supernatant, wherein the used amount of hydrogen peroxide is 0.8-2kg / ton of wastewater, the used amount of a ferrous salt is 0.6-3kg / ton of wastewater, and hydrogen peroxide is subjected to oxidative degradation reaction with substances in the supernatant; (3) adding an acid-alkali regulator to adjust the pH value to 6-9, and performing aeration treatment; and (4) adding a secondary flocculant into the waste solution after the aeration treatment according to a used amount of 2-10g / ton of wastewater to perform secondary sedimentation so as to ensure that residual impurities are deposited. After the wastewater is treated by the method disclosed by the invention, the COD (chemical oxygen demand) and SS (suspended substances) in discharged water are reduced to a very low level, the COD value is less than 300mg / L, the SS value is lower than 150mg / L, the color of the discharged water is light, and the foam in the discharged water is less, so that the wastewater reaches a standard of direct discharge.

Description

technical field [0001] The invention relates to a method for treating waste water after ethanol is prepared by using cassava as a raw material, and belongs to the technical field of waste water treatment after ethanol is prepared. Background technique [0002] Cassava is one of the three largest tuber crops in the world. It is rich in starch and is an important raw material for alcohol production. The process of using cassava as raw material to produce alcohol has become mature, and the residue after alcohol production has also been further utilized, but the waste liquid produced after alcohol production has not been effectively treated and directly discharged outside, which has a serious impact on the environment. The waste liquid has become the chief culprit of polluting the environment. If the alcohol waste liquid is not treated, there will be hidden dangers of damaging the environment. This problem has attracted the attention of alcohol manufacturers, and corresponding ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04
Inventor 岳国君柳树海孙振江黄加军李涛李保华时强
Owner GUANGXI COFCO BIO ENERGY
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