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Light-cured composite resin based on laminar filler and preparation method of light-cured composite resin

A flake filler and composite resin technology, applied in the field of stomatology materials, can solve the problems of unsatisfactory mechanical properties of composite resin repair materials, insufficient strength and wear resistance, easy formation of secondary caries, etc., so as to reduce the failure of dental caries repair. Fracture, reduce cracking, prolong the effect of penetration path

Inactive Publication Date: 2015-03-25
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the shortcomings of composite resins in long-term clinical application have gradually been exposed, among which the more prominent ones are: first, during the polymerization process, the volume shrinks, resulting in micro-leakage of the edges between the composite resin and the tooth, and then It is easy to form secondary caries; second, the mechanical properties of composite resin restoration materials are not ideal, especially when used as a posterior tooth filling restoration, compared with silver amalgam, its strength and wear resistance are still insufficient
[0003] Studies have shown that the shortcomings of photocurable resin materials may be related to the composition and content of the repair resin itself, especially the type and relative content of the resin matrix and the performance and content of inorganic fillers.

Method used

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  • Light-cured composite resin based on laminar filler and preparation method of light-cured composite resin

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Accurately weigh 5.0g BisGMA and 5.0g TEGDMA in a small beaker, add 0.1g photoinitiator CQ and EDMAB (3:7) to obtain a mixture solution.

[0017] Weigh 50 g of flaky silicon dioxide, stir in an aqueous solution of 1 microliter / ml hydrofluoric acid for 12 hours, centrifuge, and after drying, reflux for 12 hours in a toluene solution of KH570 with a volume concentration of 30%, and suction filter. After drying, weigh 10g of the treated flaky silica and add it to the above mixture solution, stir and grind to make it evenly mixed, and then evacuate and exhaust to obtain a 50% flaky silica filler. Cured composite resin.

[0018] Prepare the resin as a sample conforming to the YY1042-2009 standard, cure it under a 1000-watt blue light for 40 seconds, then test its hardness and water absorption, and test its curing shrinkage with the pycnometer method. The results are as follows:

[0019] Vickers hardness: 90

[0020] Curing shrinkage: 2.1%

[0021] Water absorption rate: 3...

Embodiment 2

[0023] Accurately weigh 4.0g UDMA and 4.0g TEGDMA in a small beaker, add 0.1g photoinitiator CQ and EDMAB (3:7).

[0024] Weigh 50 g of flake aluminum oxide, stir in 7 microliters / ml of hydrochloric acid solution for 12 hours, centrifuge, after drying, reflux for 12 hours in the toluene solution of KH570 with a volume concentration of 30%, suction filtration, and after drying, Weigh 12g of treated flaky alumina and add it to the mixed solution, stir and grind to make it evenly mixed, and then evacuate and exhaust to obtain a photocurable composite resin with 60% flaky alumina filler doping.

[0025] Take a sample of the resin prepared to meet the YY1042-2009 standard, cure it under a 1000-watt blue light for 40 seconds, then test its hardness and water absorption, and test its curing shrinkage by the pycnometer method. The result is as follows:

[0026] Vickers hardness: 110

[0027] Curing shrinkage: 1.8%

[0028] Water absorption: 30 days water absorption 1.23% (wt.%) The...

Embodiment 3

[0030] Accurately weigh 2.0g UDMA and 2.0g TCDMA in a small beaker, add 0.08g photoinitiator CQ and EDMAB (3:7) and mix well.

[0031] Weigh 50g of flaky alumina, stir in 3 microliters / ml of hydrochloric acid solution for 12 hours, centrifuge, after drying, reflux for 12 hours in the toluene solution of KH570 with a volume concentration of 30%, filter with suction, and weigh after drying. Take 16g of treated flaky alumina and add it to the mixed solution, stir and grind to make it evenly mixed, and then evacuate and exhaust to obtain a photocurable composite resin with 80% flaky alumina filler doping.

[0032] Take a sample of the resin prepared to meet the YY1042-2009 standard, cure it under a 1000-watt blue light for 40 seconds, then test its hardness and water absorption, and test its curing shrinkage by the pycnometer method. The result is as follows:

[0033] Vickers hardness: 93

[0034] Curing shrinkage: 1.8%

[0035] Water absorption rate: 30 days water absorption r...

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Abstract

The invention discloses light-cured composite resin based on a laminar filler for oral cavities and a preparation method of the light-cured composite resin, belonging to the field of oral medical materials. According to the light-cured composite resin disclosed by the invention, a common filler in the conventional light-cured composite resin is replaced by the laminar filler subjected to chemical treatment. The orientation and own characteristics of the laminar filler ensure that during light curing of a light-cured resin matrix, the curing shrinkage ratio of the light-cured resin matrix is greatly reduced and the strength and hardness of the light-cured resin matrix are increased. By using the laminar filler, a seepage path of water molecules is greatly increased, the water absorption rate of the composite resin is greatly reduced, the dehiscence between repair resin and a tooth matrix can be significantly reduced, and clinically most common ruptures and secondary caries causing repair failure can be effectively reduced. The light-cured composite resin is of great significance for reducing pains of patients and promoting the development of oral cavity repair materials.

Description

technical field [0001] The invention belongs to the field of stomatological materials, and in particular relates to a light-cured composite resin based on sheet-like fillers and a preparation method thereof. Background technique [0002] In the 1960s, composite resin was introduced into the field of tooth restoration, which became a revolutionary progress in oral material science. Although composite resin materials have been developed for many years, many of their excellent properties have played an important role in clinical treatment. However, the shortcomings of composite resins in long-term clinical application have gradually been exposed, among which the more prominent ones are: first, during the polymerization process, the volume shrinks, resulting in micro-leakage of the edges between the composite resin and the tooth, and then It is easy to form secondary caries; second, the mechanical properties of composite resin restoration materials are not ideal, especially whe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A61K6/083A61K6/027A61K6/02
Inventor 崔占臣张英超朱松宫海环史作森
Owner JILIN UNIV
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