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Anticorrosion abrasive-resistant material with Ni-Cu-P-TiN composite coating and preparation method of material

A ni-cu-p-tin, anti-wear material technology, applied in chemical instruments and methods, metal material coating processes, coatings, etc. Falling off, reducing the bonding strength of the coating and the substrate, etc.

Inactive Publication Date: 2015-02-11
CENT SOUTH UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the prior art, the coating of the anti-corrosion and anti-wear ink scraper with coating is usually a single-layer Ni-P coating, but it is difficult for the single-layer Ni-P coating to meet the increasingly complex construction conditions due to its anti-corrosion and anti-wear properties, so people try to The Ni-P coating introduces a new phase, which is expected to achieve the purpose of improving the overall performance of the material. In the research, it was found that when copper is added to the Ni-P coating, the bonding strength between the coating and the substrate will be reduced; when directly applied to the Ni-P coating When the second phase particles are introduced into the coating, due to the insufficient embedding strength of the second phase particles, the coating is easy to fall off in a corrosive and abrasive environment

Method used

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  • Anticorrosion abrasive-resistant material with Ni-Cu-P-TiN composite coating and preparation method of material
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Examples

Experimental program
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Effect test

Embodiment 1

[0048] First dissolve 30g nickel sulfate, 30g sodium hypophosphite, 8g citric acid, 25g trisodium citrate and 20mg potassium iodate with a small amount of deionized water respectively to obtain an aqueous solution of components such as nickel sulfate and sodium hypophosphite; , 20ml lactic acid, 15ml glacial acetic acid and citric acid solution were mixed and stirred for 5min to obtain a ternary complex complexing agent solution; the complex complexing agent solution was mixed with nickel sulfate solution and stirred for 5min to obtain solution A; then, lemon Trisodium acid solution, sodium hypophosphite solution and potassium iodate solution were added to solution A respectively, and stirred for 5 minutes each time to fully mix the components. Finally, use a pH meter to adjust the pH of the solution to 4.8, and set the volume to 1 L. The regulator is dilute ammonia water. At this time, the preparation of electroless plating solution A is completed; repeat the above operations ...

Embodiment 2

[0055] First dissolve 32g nickel sulfate, 32g sodium hypophosphite, 9g citric acid, 30g trisodium citrate and 22mg potassium iodate respectively with a small amount of deionized water to obtain an aqueous solution of components such as nickel sulfate and sodium hypophosphite; , 22ml lactic acid, 17ml glacial acetic acid and citric acid solution were mixed and stirred for 5min to obtain a ternary complex complexing agent solution; the complex complexing agent solution was mixed with nickel sulfate solution and stirred for 5min to obtain solution A; then, lemon Trisodium acid solution, sodium hypophosphite solution and potassium iodate solution were added to solution A respectively, and stirred for 5 minutes each time to fully mix the components. Finally, use a pH meter to adjust the pH of the solution to 5.0, and set the volume to 1 L. The regulator is dilute ammonia water. At this time, the preparation of the electroless plating solution A is completed; repeat the above operati...

Embodiment 3

[0062] First dissolve 35g nickel sulfate, 35g sodium hypophosphite, 10g citric acid, 35g trisodium citrate and 25mg potassium iodate respectively with a small amount of deionized water to obtain an aqueous solution of components such as nickel sulfate and sodium hypophosphite; , 25ml lactic acid, 20ml glacial acetic acid and citric acid solution were mixed and stirred for 5min to obtain a ternary complex complexing agent solution; the complex complexing agent solution was mixed with nickel sulfate solution and stirred for 5min to obtain solution A; then, lemon Trisodium acid solution, sodium hypophosphite solution and potassium iodate solution were added to solution A respectively, and stirred for 5 minutes each time to fully mix the components. Finally, use a pH meter to adjust the pH of the solution to 5.1, and set the volume to 1 L. The regulator is dilute ammonia water. At this time, the preparation of the electroless plating solution A is completed; repeat the above operat...

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Abstract

The invention discloses an anticorrosion abrasive-resistant material which sequentially comprises a base material, a Ni-P coating, a Ni-Cu-P coating and a Ni-Cu-P-TiN coating from inward to outward. According to the invention, flexible metal Cu and TiN nano particles are added into the Ni-P coating via a prior precipitation mechanism and a co-deposition mechanism, so that the Cu metal and the TiN particles have complementary performance advantages; meanwhile, in order to improve the wettability of the TiN particles and a Ni-P alloy, the TiN particles are subjected to Ni coating modification treatment, and the bonding intensity of the TiN particles and the coating is increased; on the other hand, by the multi-layer structural design of Ni-P / Ni-Cu-P / (Ni-Cu-P-TiN), the problem of poor bonding intensity of the coatings caused by the prior precipitation mechanism of Cu is solved. The method is simple in technology, and equipment is low in price; a subsequent technology is combined, a coating scraper with good corrosion resistance and tribology performance can be prepared, and the service life of the scraper can be multiplied.

Description

technical field [0001] The invention relates to an anti-corrosion and anti-wear material with Ni-Cu-P-TiN composite coating and a preparation method thereof, belonging to the technical field of anti-corrosion and anti-wear material preparation. Background technique [0002] In the prior art, the coating of the anti-corrosion and anti-wear ink scraper with coating is usually a single-layer Ni-P coating, but it is difficult for the single-layer Ni-P coating to meet the increasingly complex construction conditions due to its anti-corrosion and anti-wear properties, so people try to The Ni-P coating introduces a new phase, which is expected to achieve the purpose of improving the overall performance of the material. In the research, it was found that when copper is added to the Ni-P coating, the bonding strength between the coating and the substrate will be reduced; when directly applied to the Ni-P coating When the second phase particles are introduced into the coating, due to ...

Claims

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Application Information

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IPC IPC(8): B32B15/01C23C18/48
CPCC23C18/50
Inventor 周宏明高志成贾洋夏庆路
Owner CENT SOUTH UNIV
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