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A kind of anti-radiation liquid organic glass

A liquid plexiglass, radiation protection technology, applied in shielding, nuclear engineering, reactors, etc., can solve the problems of environmental pollution, lead toxicity, weak particle absorption ability, etc., and achieve the effect of high-efficiency radiation protection performance

Active Publication Date: 2016-01-27
砀山县纳方包装材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional radiation protection materials generally use concrete, cement, lead plates, iron plates, etc. With the application of radiation in more and more fields, these materials have been difficult to meet the needs of various protective equipment production. In recent years, polymer based As a radiation protection material, composite materials have become a research hotspot. It is made of organic polymer materials as the matrix skeleton material and micro-powder with the function of absorbing rays as the filler. Among them, plexiglass (polymethyl methacrylate) is often used as the matrix material. At present, organic lead glass, organic barium glass, organic cadmium glass and other varieties have appeared, and related products and patents have also been reported
[0003] Lead or lead compounds are the mainstream of application as fillers, but they have two disadvantages: on the one hand, lead radiation-proof materials have good particle absorption ability for rays with energy higher than 88keV and between 13 and 40keV, but for energy Rays between 40 and 88keV have a region with very weak particle absorption ability (that is, "Pb weak absorption region"); on the other hand, lead is toxic and pollutes the environment, so its use is often restricted

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A kind of anti-radiation liquid organic glass, each component is calculated in parts by mass as follows:

[0024] Methyl methacrylate 30g,

[0025] Dibenzoyl peroxide 0.5g,

[0026] Dioctyl phthalate 15g,

[0027] Caprylic acid 7g,

[0028] Propylene glycol 5g,

[0029] n-butanol 0.5g,

[0030] Cyclohexanone 10g,

[0031] Cyclohexane 20g,

[0032] Lead methacrylate 7g,

[0033] Samarium methacrylate 5g.

[0034] The preparation steps include: first dissolving lead methacrylate in cyclohexanone, dissolving samarium methacrylate in octanoic acid and propylene glycol, and then weighing methyl methacrylate, dioctyl phthalate, cyclohexane, For n-butanol, put the above raw materials into a reaction kettle, stir, heat to 78°C, add dibenzoyl peroxide cyclohexanone solution dropwise, and keep the temperature for 1 hour to obtain liquid organic glass.

Embodiment 2

[0036] A kind of anti-radiation liquid organic glass, each component is calculated in parts by mass as follows:

[0037] Methyl methacrylate 40g,

[0038] Dibenzoyl peroxide 0.5g,

[0039] Dioctyl phthalate 10g,

[0040] Caprylic acid 5g,

[0041] Propylene glycol 3g,

[0042] n-butanol 1.5g,

[0043] Cyclohexanone 8g,

[0044] Cyclohexane 10g,

[0045] Lead methacrylate 14g,

[0046] Samarium methacrylate 8g.

[0047] The preparation steps include: first dissolving lead methacrylate in cyclohexanone, dissolving samarium methacrylate in octanoic acid and propylene glycol, and then weighing methyl methacrylate, dioctyl phthalate, cyclohexane, For n-butanol, put the above raw materials into a reaction kettle, stir, heat to 78°C, add dibenzoyl peroxide cyclohexanone solution dropwise, and keep the temperature for 2 hours to obtain liquid organic glass.

Embodiment 3

[0049] A kind of anti-radiation liquid organic glass, each component is calculated in parts by mass as follows:

[0050] Methyl methacrylate 30g,

[0051] Dibenzoyl peroxide 0.5g,

[0052] Dioctyl phthalate 5g,

[0053] Caprylic acid 9g,

[0054] Propylene glycol 5g,

[0055] n-butanol 0.5g,

[0056] Cyclohexanone 5g,

[0057] Cyclohexane 10g,

[0058] Lead methacrylate 20g,

[0059] Samarium methacrylate 15g.

[0060] The preparation steps include: first dissolving lead methacrylate in cyclohexanone, dissolving samarium methacrylate in octanoic acid and propylene glycol, and then weighing methyl methacrylate, dioctyl phthalate, cyclohexane, For n-butanol, put the above raw materials into a reaction kettle, stir, heat to 78°C, add dibenzoyl peroxide cyclohexanone solution dropwise, and keep the temperature for 2 hours to obtain liquid organic glass.

[0061] In order to prove the preparation of the radiation protection performance of the liquid organic glass of the pr...

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PUM

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Abstract

The invention provides a radiation-proof liquid organic glass. Lead methacrylate and samarium methacrylate are used as radiation-proof components to prepare liquid radiation-proof organic glass. First, lead methacrylate is dissolved in cyclohexanone, and formazan Dissolve samarium acrylate in octanoic acid and propylene glycol, then weigh methyl methacrylate, dioctyl phthalate, cyclohexane, and n-butanol, put the above raw materials into the reaction kettle, stir, and heat to 78°C. Add the cyclohexanone solution of dibenzoyl peroxide dropwise and keep the temperature constant for 1-4 hours to obtain liquid organic glass. The plexiglass has the characteristics of excellent radiation protection performance and convenient secondary processing.

Description

technical field [0001] The invention belongs to the field of special organic glass and relates to a radiation-proof liquid organic glass. Background technique [0002] With the continuous development of national defense scientific research, radiation medicine and nuclear technology applications, various radioactive rays are widely used, and the harm of rays to the human body and the damage to the environment are gradually recognized by human beings. The research on various anti-radiation materials to protect these rays has become a very important and urgent topic. Traditional radiation protection materials generally use concrete, cement, lead plates, iron plates, etc. With the application of radiation in more and more fields, these materials have been difficult to meet the needs of various protective equipment production. In recent years, polymer based As a radiation protection material, composite materials have become a research hotspot. It is made of organic polymer mater...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/14C08F220/06C08K5/098G21F1/10
Inventor 李军伟商冬洁
Owner 砀山县纳方包装材料有限公司
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