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High-performance light-storing noctilucent master batch for polyolefin plastic and preparation method thereof

A high-performance, polyolefin technology, applied in the field of plastic product coloring, can solve the problems of low concentration of luminous powder, easy darkening of masterbatch color, unsatisfactory dispersion performance, etc., to achieve good luminous effect, pure color and dispersibility Good results

Inactive Publication Date: 2014-09-24
CHANGZHOU HONGMEI PLASTIC MASTERBATCH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the luminous masterbatches provided on the market generally have the following disadvantages: 1. Masterbatches with high luminous powder content in the masterbatch have unsatisfactory dispersion performance, and most of them can only be used for thick-walled plastic products; 2. Good dispersion performance High-quality luminous masterbatch often has a low concentration of luminous powder, and it is added in a large proportion in thin-walled plastic products (especially plastic films); 3. The color of the masterbatch is easy to darken, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] LLDPE (melt flow rate is 15-25g / 10min; particle size is 30-60 mesh) 15%; LDPE (melt flow rate is 5-10g / 10min; particle size is 50-100 mesh) 21.5%; one (or Various) luminous pigment 60%; polyethylene wax (molecular weight 3000-4000) 3.0%; bisethylene stearamide 1.5%. Put 60% of the total amount of the above-mentioned luminous pigments into a plastic or ceramic mixer and mix evenly with other components, and use a twin-screw extruder for melt blending. The temperature is controlled at 140-180 ° C, and the remaining 40 % of the luminous pigment is evenly metered into the barrel of the extruder through side feeding, mixed and extruded together with the main material, and then granulated by water-cooled cutting of the strands or air-cooled cutting of the die surface. , and finally dried to obtain the masterbatch of the present invention, the degree of dispersion is 2.

Embodiment 2

[0012] LLDPE (melt flow rate is 15-25g / 10min; particle size is 30-60 mesh) 10%; LDPE (melt flow rate is 5-10g / 10min; particle size is 50-100 mesh) 27.5%; one (or Various) luminous pigment 60%; polyethylene wax (molecular weight 3000-4000) 2%; bisethylene stearamide 0.5%. Put 60% of the total amount of the above-mentioned luminous pigments into a plastic or ceramic mixer and mix evenly with other components, and use a twin-screw extruder for melt blending. The temperature is controlled at 140-180 ° C, and the remaining 40 % of the luminous pigment is evenly metered into the barrel of the extruder through side feeding, mixed and extruded together with the main material, and then granulated by water-cooled cutting of the strands or air-cooled cutting of the die surface. , and finally dried to obtain the masterbatch of the present invention, the degree of dispersion is 3.

Embodiment 3

[0014] LLDPE (melt flow rate is 15-25g / 10min, particle size is 30-60 mesh) 15.5%; LDPE (melt flow rate is 5-10g / 10min; particle size is 50-100 mesh) 20%; one (or more) species) luminous pigment 62%; polyethylene wax (molecular weight 3000-4000) 2%; bisethylene stearamide 0.5%. Put 60% of the total amount of the above-mentioned luminous pigments into a plastic or ceramic mixer and mix evenly with other components, and use a twin-screw extruder for melt blending. The temperature is controlled at 140-180 ° C, and the remaining 40 % of the luminous pigment is evenly metered into the barrel of the extruder through side feeding, mixed and extruded together with the main material, and then granulated by water-cooled cutting of the strands or air-cooled cutting of the die surface. , and finally dried to obtain the masterbatch of the present invention, the degree of dispersion is 3.

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Abstract

The invention relates to a high-performance light-storing noctilucent master batch for polyolefin plastic and a preparation method thereof. The high-performance noctilucent master batch for polyolefin plastic comprises: 10-15.5% of LLDPE (the melt flow rate is 15-25g / 10min, and the particle size is 30-60 meshes), 27.5-5% of LDPE (the melt flow rate is 5-10g / 10min, an the particle size is 50-100 meshes), 60-75% of one (or multiple) noctilucent pigment, 2.0-3.0% of polyethylene wax (the molecular weight is 3000-4000) and 0.5-1.5% of ethylene bis stearamide. The preparation method comprises the following steps: putting 60% of the noctilucent pigment and the other components into a mixer, uniformly mixing, and performing melt blending through a double screw extruder, wherein the temperature is controlled at 140-180 DEG C; meanwhile, feeding the residual 40% of the noctilucent pigment into a machine barrel of the extruder through lateral charging in a uniform metering manner, and mixing and extruding together with the main materials; then granulating and molding in a brace water-cooling cutting and drawing manner or a mold surface air-cooling cutting and drawing manner; and finally, drying to obtain the master batch provided by the invention. The master batch can be used for coloring of plastic products in plastic processing industry.

Description

technical field [0001] The invention relates to a high-performance light-storing luminous masterbatch for polyolefin plastics and a preparation method thereof, which can be applied to the coloring of plastic products in the plastic processing industry. technical background [0002] At present, the luminous masterbatches provided on the market generally have the following disadvantages: 1. Masterbatches with high luminous powder content in the masterbatch have unsatisfactory dispersion performance, and most of them can only be used for thick-walled plastic products; 2. Good dispersion performance High-quality luminous masterbatches often have a low concentration of luminous powder, and are added in a large proportion in thin-walled plastic products (especially plastic films); 3. The color of the masterbatch tends to darken. Contents of the invention [0003] Aiming at the problems in the prior art, the object of the present invention is to provide a high-performance light-s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08K5/20C08J3/22
CPCC08L23/0815C08L23/06C08L2203/16C08L2205/025C08L2205/03C08L2207/066
Inventor 楚强姚宇平
Owner CHANGZHOU HONGMEI PLASTIC MASTERBATCH
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